File name: Pandora211s1_Agam_20221125_L2Fit_fout2c6d20220913p1-8.txt File generation date: 20260325T064237.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Ednofri Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 211 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora211_OF_v4d20211214.txt Instrument calibration file used: Pandora211s1_CF_v6d20220913.txt Level 1 file used: Pandora211s1_Agam_20221125_L1_smca1c6d20220913p1-8.txt.bz2 Full location name: Agam Space and Atmosphere Observatory (Balai Pengamatan Antariksa dan Atmosfer/B Short location name: Agam Country of location: Indonesia Location latitude [deg]: -0.2046 Location longitude [deg]: 100.3195 Location altitude [m]: 865 Local noon date: 20221125 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 230 372 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1758 305.3167 305.4576 305.5985 305.7394 305.8803 306.0211 306.1620 306.3028 306.4437 306.5845 306.7253 306.8661 307.0069 307.1477 307.2884 307.4292 307.5699 307.7107 307.8514 307.9921 308.1328 308.2735 308.4142 308.5548 308.6955 308.8361 308.9768 309.1174 309.2580 309.3986 309.5392 309.6798 309.8203 309.9609 310.1014 310.2420 310.3825 310.5230 310.6635 310.8040 310.9445 311.0849 311.2254 311.3658 311.5063 311.6467 311.7871 311.9275 312.0679 312.2083 312.3486 312.4890 312.6293 312.7697 312.9100 313.0503 313.1906 313.3309 313.4711 313.6114 313.7517 313.8919 314.0321 314.1723 314.3126 314.4527 314.5929 314.7331 314.8733 315.0134 315.1536 315.2937 315.4338 315.5739 315.7140 315.8541 315.9941 316.1342 316.2743 316.4143 316.5543 316.6943 316.8343 316.9743 317.1143 317.2543 317.3942 317.5342 317.6741 317.8140 317.9539 318.0938 318.2337 318.3736 318.5135 318.6533 318.7932 318.9330 319.0728 319.2126 319.3524 319.4922 319.6320 319.7717 319.9115 320.0512 320.1909 320.3307 320.4704 320.6101 320.7497 320.8894 321.0291 321.1687 321.3083 321.4480 321.5876 321.7272 321.8668 322.0063 322.1459 322.2855 322.4250 322.5645 322.7041 322.8436 322.9831 323.1226 323.2620 323.4015 323.5409 323.6804 323.8198 323.9592 324.0986 324.2380 324.3774 324.5168 324.6561 324.7955 324.9348 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221125T021336.9Z 8364.092788 269 1 44.75 2 46.74 118.84 63.40 119.41 0.00 1 0.00 1 0 25 2.923e-02 1.541e-02 1.339e-02 6.597e-03 1.950621e-01 3.550797e-03 1.944900e-03 -6.000000e+00 1.801393e-02 226.89 -2.00 3.05 -2.00 316.21 0.00e+00 1.486842e-03 4.077555e-04 8.325422e-05 -6.000000e+00 8.180166e-04 289.30 -2.00 20.00 -2.00 315.42 0.00e+00 1.457 0.000 302.00 328.00 3 7.6464e+00 9.1888e-03 1.5602e-02 -6.0000e+00 4.4482e-02 1.3175e-01 1.0275e-02 8.6749e-03 -6.0000e+00 4.8121e-02 -1.4909e-02 5.9049e-03 4.1322e-03 -6.0000e+00 2.8845e-02 -2.5613e-03 2.6628e-03 1.5920e-03 -6.0000e+00 1.2086e-02 5.2749e-05 8.8289e-05 2.2428e-04 1.9167e-05 -6.0000e+00 9.6339e-04 1.4719e-03 1.3321e-04 12 8 8 10 0 0 63.32 18.78 3.50 0.00147 0.00214 12 4 1 5 0 3728.900 21.58 15.00 18.78 28.06 12.0 927.11 541 -1604 -4260 6038 -1295 3650 -8523 -11089 3067 -12752 -4791 -2696 808 12 10650 2542 4017 3414 -2381 8871 3530 8681 6862 919 483 2876 800 -1968 -193 804 -4671 1486 2543 -4133 -4812 -653 -2950 1021 -606 2377 -1714 -1677 -2272 -1763 -777 619 -1839 -1117 -3821 417 -1652 -1008 3118 1306 -1984 2275 3249 833 469 3343 2540 746 -128 613 -768 -1780 -1067 -2108 593 -369 1355 -402 6 215 -338 -1197 -2037 -2340 -200 -2373 -294 -2414 -1831 170 1198 569 -826 2768 3092 2640 2047 122 -1483 -229 -1585 256 -65 635 -79 6 1575 -1584 -2963 -1499 263 -1777 149 -172 452 1629 -194 532 2305 921 -1567 -1366 -981 1321 -231 1141 657 267 -674 -1194 1193 -1233 -18 -543 -1901 -836 -116 -2561 -367 -165 799 506 644 -861 826 1724 -150 -538 528 107 -351 -974 1187 -251 630 -1680 -2414 628 -3193 -1115 -624 194 3 2870 805 1313 1155 -877 2986 1271 2967 2500 350 191 1137 319 -805 -73 292 -1817 572 1017 -1796 -2047 -262 -1277 481 -325 1413 -1162 -1196 -1675 -1305 -568 443 -1319 -771 -2637 273 -1135 -721 2248 996 -1605 1792 2554 668 373 2582 2027 639 -118 584 -737 -1632 -902 -1736 491 -336 1311 -414 6 215 -319 -1041 -1692 -1838 -156 -2043 -262 -2403 -1937 187 1377 673 -1044 3475 3873 3216 2443 136 -1542 -235 -1615 276 -77 807 -102 8 1978 -1923 -3499 -1769 321 -2347 202 -235 641 2392 -300 822 3379 1281 -2149 -1760 -1237 1675 -315 1617 965 393 -980 -1677 1557 -1566 -22 -679 -2392 -1095 -157 -3649 -522 -242 1215 774 1016 -1405 1331 2715 -233 -850 813 SS 20221125T024402.3Z 8364.113915 622 1 44.77 2 40.20 122.95 57.08 121.63 0.00 1 0.00 1 0 17 1.818e-02 1.063e-02 7.065e-03 4.151e-03 1.633207e-01 2.252931e-03 1.718428e-03 -6.000000e+00 1.120051e-02 226.89 -2.00 3.05 -2.00 315.61 0.00e+00 5.364388e-04 2.254203e-04 4.245130e-05 -6.000000e+00 5.086213e-04 289.30 -2.00 20.00 -2.00 314.86 0.00e+00 1.308 0.000 302.00 328.00 3 7.2857e+00 5.7856e-03 1.3789e-02 -6.0000e+00 2.7657e-02 7.9101e-02 6.4430e-03 7.2913e-03 -6.0000e+00 2.9921e-02 -3.4596e-03 3.6858e-03 3.5564e-03 -6.0000e+00 1.7935e-02 -6.6566e-03 1.6190e-03 1.0703e-03 -6.0000e+00 7.5143e-03 9.4339e-05 -3.8030e-04 1.4072e-04 1.6093e-05 -6.0000e+00 5.9909e-04 -2.8977e-04 3.7508e-05 12 8 8 10 0 0 99.89 18.78 0.49 -0.00029 -0.00315 12 4 1 5 0 3730.620 21.58 15.00 18.78 29.12 12.0 935.89 2537 -3830 291 3373 -4310 3612 -4913 -5446 -637 -6627 -3604 1281 1110 -1744 538 3583 -324 911 -2901 4399 1576 5274 936 2670 806 2911 343 -3105 600 4225 1251 2307 1338 -2468 -4329 -1672 -1650 1558 -1353 649 -876 -2100 -451 -1749 -557 1483 -1066 -1417 -1661 -1042 770 -980 2511 -193 630 2561 271 -824 1115 2400 1428 1171 1141 611 373 -770 -747 -1628 1517 668 1009 48 710 475 -18 57 -1998 -1029 -1117 -1137 -1995 -1672 -2840 -930 -380 334 -1248 1060 1085 711 707 297 -16 370 -798 1397 361 487 -243 221 427 -1930 -1175 -361 69 -892 -88 -563 746 616 193 -118 1777 -241 -184 -232 602 -100 35 -564 88 -319 316 -1096 1741 -274 575 -95 454 -499 -658 630 371 83 -223 999 176 -500 90 440 -1453 -163 160 630 -1088 80 858 -1081 817 -1225 -1473 -179 -1979 -1092 373 343 -585 195 1353 -132 376 -1272 1831 684 2207 412 1186 378 1369 164 -1463 266 1732 531 1010 617 -1198 -2079 -768 -799 795 -828 428 -642 -1638 -355 -1406 -441 1137 -818 -1054 -1199 -767 568 -741 1920 -158 523 2117 231 -709 931 1977 1216 1053 1089 587 356 -728 -652 -1377 1280 618 1008 49 724 490 -17 51 -1719 -823 -900 -987 -1847 -1681 -3087 -1008 -435 404 -1562 1337 1372 907 845 339 -16 369 -817 1498 410 599 -316 285 525 -2284 -1379 -428 82 -1144 -118 -758 1034 892 290 -178 2542 -341 -240 -284 747 -124 46 -787 126 -461 443 -1503 2209 -351 697 -115 562 -654 -865 838 504 117 -329 1468 269 -786 142 682 -2239 -242 241 SS 20221125T024541.2Z 8364.115060 626 1 44.70 2 39.86 123.21 56.74 121.77 0.00 1 0.00 1 0 17 1.134e-02 7.533e-03 4.146e-03 2.607e-03 1.569465e-01 1.419440e-03 1.644606e-03 -6.000000e+00 6.988111e-03 226.89 -2.00 3.05 -2.00 315.30 0.00e+00 5.349705e-04 1.336777e-04 3.742430e-05 -6.000000e+00 3.173502e-04 289.30 -2.00 20.00 -2.00 314.58 0.00e+00 1.301 0.000 302.00 328.00 3 6.6620e+00 3.6351e-03 1.3576e-02 -6.0000e+00 1.7256e-02 5.8140e-02 4.0394e-03 6.9915e-03 -6.0000e+00 1.8669e-02 7.5310e-04 2.3116e-03 3.4046e-03 -6.0000e+00 1.1190e-02 -6.8458e-03 1.0079e-03 1.0251e-03 -6.0000e+00 4.6877e-03 1.8063e-04 -2.8005e-04 8.8032e-05 1.5427e-05 -6.0000e+00 3.7383e-04 1.9624e-04 2.1344e-05 11 8 0 10 0 0 99.99 18.78 0.21 0.00020 -0.00191 13 4 1 5 0 3438.380 21.58 15.00 18.78 29.20 12.1 936.36 141 -1074 -231 2416 -2404 831 -3107 -3511 -1687 -3024 -2416 1165 -1437 510 1459 2886 -370 1434 -422 3671 61 2501 1035 1289 319 790 -64 -1720 355 1251 421 976 1368 -1896 -2770 -1693 -1088 -494 -349 182 -852 -1104 108 -906 -293 -417 -197 -1266 -1231 -91 621 -1977 2137 744 413 1219 957 6 605 1650 1089 1488 985 607 -353 -811 -918 -717 158 1277 859 475 -73 321 -289 -253 -1137 -1293 -613 -1032 -1236 -1406 -1842 -694 -866 -412 -553 765 1209 962 850 273 -90 89 346 571 797 564 -206 -590 -87 -1010 -698 -144 -90 -1257 -259 -514 459 538 323 266 1033 27 -236 -155 124 398 80 -200 58 -232 -218 -336 860 -44 528 345 71 -506 -660 102 -96 178 57 544 -187 -262 38 580 -29 -773 -19 40 -334 -72 696 -664 208 -821 -1005 -516 -978 -779 365 -490 188 585 1180 -162 632 -194 1651 29 1155 488 623 161 407 -33 -857 169 565 192 462 673 -974 -1394 -828 -559 -276 -218 130 -647 -883 88 -748 -240 -337 -155 -973 -947 -68 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