File name: Pandora211s1_Agam_20230430_L2Fit_fwvt1c6d20220913p1-8.txt File generation date: 20260325T082715.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Ednofri Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 211 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora211_OF_v4d20211214.txt Instrument calibration file used: Pandora211s1_CF_v6d20220913.txt Level 1 file used: Pandora211s1_Agam_20230430_L1_smca1c6d20220913p1-8.txt.bz2 Full location name: Agam Space and Atmosphere Observatory (Balai Pengamatan Antariksa dan Atmosfer/B Short location name: Agam Country of location: Indonesia Location latitude [deg]: -0.2046 Location longitude [deg]: 100.3195 Location altitude [m]: 865 Local noon date: 20230430 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1650 1799 Nominal wavelengths inside fitting window [nm]: 492.1208 492.2420 492.3631 492.4843 492.6055 492.7266 492.8477 492.9688 493.0899 493.2110 493.3320 493.4530 493.5741 493.6951 493.8160 493.9370 494.0580 494.1789 494.2998 494.4207 494.5416 494.6625 494.7833 494.9041 495.0250 495.1458 495.2665 495.3873 495.5081 495.6288 495.7495 495.8702 495.9909 496.1115 496.2322 496.3528 496.4734 496.5940 496.7146 496.8352 496.9557 497.0763 497.1968 497.3173 497.4378 497.5582 497.6787 497.7991 497.9195 498.0399 498.1603 498.2807 498.4010 498.5213 498.6416 498.7619 498.8822 499.0025 499.1227 499.2430 499.3632 499.4834 499.6035 499.7237 499.8438 499.9640 500.0841 500.2042 500.3243 500.4443 500.5644 500.6844 500.8044 500.9244 501.0444 501.1643 501.2843 501.4042 501.5241 501.6440 501.7639 501.8837 502.0036 502.1234 502.2432 502.3630 502.4828 502.6025 502.7223 502.8420 502.9617 503.0814 503.2010 503.3207 503.4403 503.5600 503.6796 503.7991 503.9187 504.0383 504.1578 504.2773 504.3968 504.5163 504.6358 504.7552 504.8747 504.9941 505.1135 505.2328 505.3522 505.4716 505.5909 505.7102 505.8295 505.9488 506.0680 506.1873 506.3065 506.4257 506.5449 506.6641 506.7833 506.9024 507.0215 507.1406 507.2597 507.3788 507.4979 507.6169 507.7359 507.8549 507.9739 508.0929 508.2119 508.3308 508.4497 508.5686 508.6875 508.8064 508.9252 509.0441 509.1629 509.2817 509.4005 509.5192 509.6380 509.7567 509.8754 509.9941 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230430T002130.4Z 8520.014935 131 1 10.18 2 74.24 74.72 160.83 319.25 0.00 1 0.00 1 0 15 2.402e-03 2.387e-03 6.372e-04 6.360e-04 8.767479e+03 4.415968e+01 5.796666e+02 -6.000000e+00 1.384079e+02 289.91 -2.00 20.00 -2.00 505.28 0.00e+00 5.492248e-04 1.791756e-05 4.774288e-05 -6.000000e+00 6.897289e-05 289.91 -2.00 20.00 -2.00 500.45 0.00e+00 2.528195e-01 1.267254e-02 5.438756e-02 -6.000000e+00 4.790227e-02 227.22 -2.00 3.05 -2.00 502.03 0.00e+00 3.617 0.000 489.00 513.00 1 5.1752e+00 9.7210e-04 6.6551e-03 -6.0000e+00 3.6789e-03 2.0207e-03 2.5003e-04 1.3305e-03 -6.0000e+00 9.5952e-04 6.6898e-03 6.6941e-04 6.1781e-05 5.8381e-05 -6.0000e+00 2.5181e-04 6.4589e-03 2.4512e-05 12 1 1 12 1 1 96.45 19.04 1.81 0.00646 0.01110 20 29 1 4 0 476.910 21.69 14.99 19.04 31.02 17.1 913.83 -251 -186 -85 191 125 447 424 348 327 76 -51 -67 -167 -104 -169 -127 18 33 173 78 155 318 287 296 409 237 -82 75 -117 -383 -336 -68 -10 -48 12 -106 -12 -87 -193 -112 31 -64 172 32 123 203 123 -11 -147 -419 -365 -443 -306 -215 -128 -56 -57 -22 101 72 233 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-191 -283 -167 -259 900000 SQ 20230430T003201.9Z 8520.022245 135 1 11.30 2 71.70 74.50 162.40 325.15 0.00 1 0.00 1 0 22 2.465e-03 2.454e-03 1.307e-04 1.305e-04 7.607203e+03 8.891389e+00 5.088293e+02 -6.000000e+00 1.420716e+02 289.91 -2.00 20.00 -2.00 505.27 0.00e+00 4.836106e-04 3.675749e-06 4.215776e-05 -6.000000e+00 7.079788e-05 289.91 -2.00 20.00 -2.00 500.48 0.00e+00 1.835753e-01 2.593542e-03 4.762698e-02 -6.000000e+00 4.916625e-02 227.22 -2.00 3.05 -2.00 502.06 0.00e+00 3.144 0.000 489.00 513.00 1 2.2528e+00 1.9902e-04 5.8101e-03 -6.0000e+00 3.7760e-03 -5.3320e-03 5.1170e-05 1.1681e-03 -6.0000e+00 9.8474e-04 1.3320e-01 7.3926e-04 1.2821e-05 5.2405e-05 -6.0000e+00 2.5848e-04 3.9561e-03 4.6142e-05 10 0 0 10 0 0 98.58 19.03 1.95 0.00396 0.00908 528 156 1 4 0 21.400 21.69 15.00 19.03 31.61 17.2 918.28 -351 -246 -100 212 377 537 431 340 436 249 25 -80 -157 -228 -262 -62 -4 2 149 104 142 278 291 323 412 271 -71 -66 -155 -381 -291 -75 -70 -27 -20 -53 -42 -112 -129 -89 -16 13 59 108 118 156 126 -55 -166 -355 -507 -449 -391 -259 -151 -74 -51 7 64 120 156 194 237 203 250 133 -32 -185 -125 -163 -193 -89 -134 -84 -157 -221 -310 -283 -250 -383 -439 -303 -226 -231 -251 -244 -137 -56 -1 258 257 187 272 296 193 63 -228 -302 -440 -519 -337 -241 -311 -263 -351 -367 -195 -102 -108 -127 -70 74 240 454 637 566 456 392 249 188 309 318 231 295 212 236 304 217 -29 59 -37 -186 -124 -30 -26 -58 -69 -32 69 136 194 217 232 89 -47 -157 -166 -217 -281 900000 -338 -242 -100 217 384 558 454 351 456 258 26 -81 -160 -230 -265 -62 -4 2 155 108 149 290 304 340 434 285 -74 -68 -157 -379 -288 -76 -71 -28 -21 -56 -43 -116 -132 -90 -17 13 62 111 122 160 129 -57 -167 -356 -496 -432 -377 -254 -150 -75 -52 7 66 123 161 201 245 208 254 133 -32 -185 -123 -160 -189 -88 -134 -82 -154 -220 -303 -272 -240 -368 -425 -295 -222 -224 -247 -240 -135 -55 -1 255 256 189 274 294 188 61 -215 -286 -410 -482 -317 -229 -301 -262 -348 -362 -194 -101 -107 -124 -70 74 241 457 644 565 458 392 253 188 303 309 224 288 208 231 297 211 -28 57 -36 -179 -118 -29 -25 -56 -67 -31 68 135 194 219 234 90 -47 -155 -165 -212 -272 900000 SQ 20230430T003213.4Z 8520.022377 135 2 11.31 2 71.66 74.49 162.43 325.27 0.00 1 0.00 1 0 22 2.457e-03 2.445e-03 1.428e-04 1.425e-04 7.605738e+03 9.755924e+00 5.080859e+02 -6.000000e+00 1.415864e+02 289.91 -2.00 20.00 -2.00 505.28 0.00e+00 4.944411e-04 4.023666e-06 4.274720e-05 -6.000000e+00 7.055636e-05 289.91 -2.00 20.00 -2.00 500.48 0.00e+00 1.780598e-01 2.834296e-03 4.763379e-02 -6.000000e+00 4.899971e-02 227.22 -2.00 3.05 -2.00 502.06 0.00e+00 3.137 0.000 489.00 513.00 1 2.4169e+00 2.1766e-04 5.8073e-03 -6.0000e+00 3.7632e-03 -4.6258e-03 5.5867e-05 1.1666e-03 -6.0000e+00 9.8144e-04 1.1318e-01 7.9520e-04 1.4003e-05 5.2783e-05 -6.0000e+00 2.5760e-04 5.3009e-03 3.5738e-05 10 0 0 10 0 0 88.33 19.03 1.94 0.00530 0.01082 528 156 1 4 0 21.400 21.69 15.00 19.03 31.61 17.3 919.32 -370 -251 -64 225 365 530 408 362 430 247 19 -103 -168 -193 -265 -40 -26 -2 145 88 143 264 263 321 428 267 -79 -89 -125 -371 -304 -85 -93 -19 7 -37 -16 -86 -122 -102 -31 21 53 118 136 165 132 -85 -169 -343 -542 -429 -381 -229 -149 -65 -31 4 51 129 170 189 234 214 254 145 -36 -168 -116 -186 -205 -89 -109 -101 -149 -218 -291 -261 -225 -394 -426 -300 -259 -244 -268 -241 -131 -80 26 262 257 174 264 298 202 38 -204 -330 -421 -537 -314 -235 -311 -273 -337 -372 -166 -87 -108 -141 -76 78 251 463 606 575 448 374 268 190 309 299 237 262 210 225 342 234 -23 31 -41 -207 -137 -39 -22 -83 -73 -13 93 150 204 222 213 89 -57 -167 -205 -224 -254 900000 -362 -245 -64 227 376 542 424 377 444 252 20 -105 -168 -192 -265 -41 -26 -2 151 93 151 278 278 340 454 283 -83 -91 -128 -373 -304 -86 -95 -20 7 -39 -16 -89 -126 -105 -32 22 54 122 141 171 135 -86 -171 -338 -535 -417 -372 -227 -149 -67 -31 4 52 130 172 192 237 216 260 147 -36 -166 -112 -184 -203 -87 -107 -100 -148 -213 -287 -254 -217 -382 -416 -295 -251 -239 -265 -239 -130 -80 26 260 258 172 262 298 198 36 -195 -308 -386 -491 -292 -225 -303 -269 -336 -370 -162 -85 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