File name: Pandora61s1_AldineTX_20230119_L2Fit_fout2c1d20210909p1-8.txt File generation date: 20260321T203919.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: James Flynn Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 61 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora61_OF_v5d20210204.txt Instrument calibration file used: Pandora61s1_CF_v1d20210909.txt Level 1 file used: Pandora61s1_AldineTX_20230119_L1_smca1c1d20210909p1-8.txt.bz2 Full location name: University Of Houston Trailer Short location name: AldineTX Country of location: United States Location latitude [deg]: 29.9011 Location longitude [deg]: -95.3262 Location altitude [m]: 8 Local noon date: 20230119 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0902 305.2311 305.3721 305.5130 305.6539 305.7949 305.9357 306.0766 306.2175 306.3584 306.4992 306.6400 306.7809 306.9217 307.0625 307.2032 307.3440 307.4848 307.6255 307.7662 307.9070 308.0477 308.1884 308.3290 308.4697 308.6103 308.7510 308.8916 309.0322 309.1728 309.3134 309.4540 309.5946 309.7351 309.8756 310.0162 310.1567 310.2972 310.4377 310.5781 310.7186 310.8591 310.9995 311.1399 311.2803 311.4207 311.5611 311.7015 311.8418 311.9822 312.1225 312.2628 312.4031 312.5434 312.6837 312.8240 312.9643 313.1045 313.2447 313.3849 313.5252 313.6654 313.8055 313.9457 314.0859 314.2260 314.3661 314.5062 314.6464 314.7864 314.9265 315.0666 315.2066 315.3467 315.4867 315.6267 315.7667 315.9067 316.0467 316.1867 316.3266 316.4666 316.6065 316.7464 316.8863 317.0262 317.1661 317.3060 317.4458 317.5856 317.7255 317.8653 318.0051 318.1449 318.2847 318.4244 318.5642 318.7039 318.8436 318.9834 319.1231 319.2628 319.4024 319.5421 319.6817 319.8214 319.9610 320.1006 320.2402 320.3798 320.5194 320.6590 320.7985 320.9381 321.0776 321.2171 321.3566 321.4961 321.6356 321.7750 321.9145 322.0539 322.1934 322.3328 322.4722 322.6116 322.7509 322.8903 323.0297 323.1690 323.3083 323.4477 323.5870 323.7262 323.8655 324.0048 324.1440 324.2833 324.4225 324.5617 324.7009 324.8401 324.9793 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230119T134659.6Z 8419.574301 110 1 42.85 2 84.94 116.93 67.62 145.07 0.00 1 0.00 1 0 41 1.479e-01 7.568e-02 1.268e-01 6.130e-02 6.858852e-01 3.233050e-02 7.390719e-03 -6.000000e+00 8.645998e-02 224.45 -2.00 3.24 -2.00 317.55 0.00e+00 -1.358693e-02 3.879648e-03 2.305180e-03 -6.000000e+00 3.925089e-03 284.88 -2.00 20.00 -2.00 316.42 0.00e+00 9.724 0.011 302.00 328.00 3 -7.3679e-01 8.4529e-02 1.0394e-01 -6.0000e+00 2.1274e-01 2.1250e+00 9.7290e-02 4.7376e-02 -6.0000e+00 2.3163e-01 -1.5804e+00 5.3394e-02 1.5199e-02 -6.0000e+00 1.3861e-01 4.2109e-01 2.4074e-02 1.3719e-02 -6.0000e+00 5.8227e-02 2.8288e-05 6.6922e-04 1.7777e-03 1.8146e-04 -6.0000e+00 4.4821e-03 3.5422e-03 -2.1749e-04 12 8 8 10 0 0 22.95 17.85 5.50 0.00354 0.00857 54 21 1 5 0 792.610 21.98 14.99 17.85 16.68 21.1 931.10 22859 34147 3611 2094 -8786 -40824 -23990 6783 25065 13938 10683 13244 14427 18035 766 11056 37184 218 27772 6278 -1688 8691 2157 13656 19048 -2724 -28787 -38473 -26714 -41191 -31213 -4788 1707 -11009 -17635 -24276 -1056 -1405 2427 16313 14225 34353 23693 3785 5053 -9505 22882 7576 -9449 -20369 -6038 -6290 13904 18281 -1128 15592 14194 15844 11038 -995 -2954 -327 371 6376 -8232 -9329 4263 -1075 -242 11465 12904 5060 5097 -3306 -12246 -26459 -42354 -26706 -33365 -11331 7949 18108 6048 26548 7979 18306 16902 16583 3771 -243 -1121 -20658 -1181 -14035 6505 -8093 10678 11711 8145 2147 1375 -3803 439 -14022 -4576 5764 2513 9326 7581 9310 14225 7929 1302 -5341 -6428 -3783 -744 -3079 -3212 -194 -772 6307 -3984 -1916 7255 -2065 -968 -6030 -3346 -6440 -609 -857 -3087 -2744 -1276 3626 -157 1662 -31 13 2285 388 3237 8085 11320 1331 717 -2865 -17527 -9256 2101 6811 4242 3309 4103 4704 6077 325 4326 11114 92 8603 2286 -624 2786 762 4601 6314 -1095 -13610 -17353 -9582 -16788 -12213 -1535 529 -3709 -5846 -8443 -316 -489 950 6206 5798 11388 8369 1522 1867 -3822 6976 2388 -3543 -8856 -2428 -2701 5652 7431 -521 6804 6194 6440 4355 -417 -1254 -143 173 2935 -4330 -4740 1860 -514 -126 5826 6788 2874 2742 -1759 -6295 -13919 -24559 -13570 -20145 -6299 4134 9417 3796 14283 5438 11709 11215 11004 2750 -173 -744 -15684 -727 -10403 4394 -7208 8937 10711 8034 2182 1299 -3433 359 -13579 -4268 5099 2434 9087 8293 11131 17602 10854 1892 -7982 -9260 -5178 -1005 -4454 -4877 -292 -1145 8407 -5692 -2588 8631 -2616 -1215 -8579 -5221 -11587 -1129 -1701 -6662 -6316 -3089 8735 -404 4232 -79 31 5150 850 6888 SS 20230119T135700.9Z 8419.581260 113 1 42.94 2 83.01 118.29 66.46 147.04 0.00 1 0.00 1 0 25 1.378e-01 2.474e-02 8.545e-02 1.584e-02 7.051631e-01 8.499080e-03 7.513607e-03 -6.000000e+00 8.060178e-02 224.45 -2.00 3.24 -2.00 321.10 0.00e+00 -4.599380e-03 2.606535e-03 1.628333e-03 -6.000000e+00 3.656313e-03 284.88 -2.00 20.00 -2.00 320.34 0.00e+00 7.537 0.005 302.00 328.00 3 -1.7932e-01 2.5847e-02 8.2585e-02 -6.0000e+00 1.9833e-01 1.1578e+00 3.0213e-02 3.7981e-02 -6.0000e+00 2.1590e-01 -1.4660e+00 1.7644e-02 1.5945e-02 -6.0000e+00 1.2920e-01 5.8699e-01 9.2141e-03 6.8862e-03 -6.0000e+00 5.4304e-02 1.7045e-04 -3.9976e-03 4.8115e-04 8.8978e-05 -6.0000e+00 4.1750e-03 2.0644e-03 -1.2103e-04 12 8 8 10 0 0 7.70 17.83 2.48 0.00206 -0.02798 217 86 1 5 0 197.810 21.88 15.00 17.83 17.51 21.1 938.29 20122 6508 -2847 -4654 -413 -40099 -24967 -43814 5091 -33146 -28006 -40187 -21013 4837 20000 10504 9512 24502 8634 37743 -10245 15161 -19727 26135 -2983 3399 3703 -25370 -18925 -28671 -17305 -7088 21422 -13183 -13 -26185 -8437 2391 6127 15905 22331 26841 18317 33421 4524 35394 17110 19794 -3453 23826 6107 11615 22396 14653 21473 22266 23930 5293 14375 -795 3000 -284 13995 9192 5697 2821 -1082 8909 5298 5267 1875 10507 3497 4649 657 -1563 -10927 -11338 -6145 -9415 -6140 -3438 -1150 -2604 3585 -825 3025 -803 2975 2322 -1483 -4044 -4327 -3855 -4963 -841 -2458 -1251 -3267 -1896 -4827 -2993 -4000 -5727 -2748 -3551 667 -1865 1010 695 784 -639 2345 -862 1575 205 -374 -1215 -63 1450 1581 3077 1564 2794 -286 2702 1860 859 770 264 760 -269 400 -563 662 114 628 -255 -69 -696 -962 -1115 -703 1950 731 -328 -471 -34 -4393 -2350 -5231 386 -3678 -2911 -4911 -2361 476 2070 1166 1095 2688 1094 3440 -1425 1546 -2834 2463 -387 410 418 -3449 -2222 -3721 -2192 -898 2184 -1894 -1 -3843 -1095 318 918 2457 3485 4105 3028 4596 797 4429 2511 2814 -629 3460 1142 2225 4118 3079 4379 4610 4880 1259 2954 -182 663 -69 3265 2443 1611 802 -316 2436 1645 1831 727 3831 1329 1623 215 -469 -3376 -3591 -2060 -3811 -2789 -1721 -615 -1505 2071 -526 1935 -544 1917 1442 -896 -2368 -2493 -2323 -3397 -639 -2195 -1137 -3258 -1864 -4604 -2811 -3541 -5194 -2568 -3555 682 -1926 1122 870 1087 -955 3438 -1273 2179 279 -518 -1777 -96 2249 2429 4512 2252 3845 -431 3836 2635 1301 1191 462 1460 -561 879 -1331 1648 299 1680 -696 -185 -1807 -2352 -2574 -1576 SS 20230119T140732.2Z 8419.588567 116 1 42.84 2 81.02 119.75 65.31 149.16 0.00 1 0.00 1 0 17 2.230e-01 2.186e-02 4.603e-02 5.192e-03 6.203036e-01 2.798460e-03 6.858202e-03 -6.000000e+00 1.305043e-01 224.45 -2.00 3.24 -2.00 321.28 0.00e+00 4.777705e-03 1.155726e-03 2.824967e-03 -6.000000e+00 5.916120e-03 284.88 -2.00 20.00 -2.00 320.63 0.00e+00 6.066 0.003 302.00 328.00 3 -2.0668e-01 9.2317e-03 6.8047e-02 -6.0000e+00 3.2114e-01 6.1065e-01 1.1157e-02 3.2798e-02 -6.0000e+00 3.4952e-01 -8.4835e-01 7.5548e-03 1.6030e-02 -6.0000e+00 2.0917e-01 3.6522e-01 3.7509e-03 4.5674e-03 -6.0000e+00 8.7960e-02 8.0239e-04 -3.3954e-03 1.6357e-04 9.8430e-05 -6.0000e+00 6.7557e-03 6.3979e-04 -4.1594e-05 12 8 8 10 0 0 76.72 17.83 1.65 0.00064 -0.02487 540 214 1 5 0 79.320 21.88 15.00 17.83 18.66 21.1 947.71 -51564 -48340 -50805 -56257 -53971 -77503 -68670 -85533 -76395 -83841 -71706 -51802 -47073 -32959 -15263 -502 -5632 6547 3478 6741 -7340 -2581 -9262 -9053 -15938 -1429 -2912 -15176 -4702 -12157 -7863 1464 16255 229 10770 2828 -2996 11215 20700 30897 21802 30773 24251 23872 23501 23950 11685 15486 16738 16976 17112 18022 24343 18930 23462 17500 15998 11556 7913 7220 8446 8674 9687 13165 8464 11594 6065 6961 6787 6399 3785 3736 1066 2498 -575 -4171 -3527 -6234 -4803 -5033 -987 -3463 -3224 -3063 -1479 -1141 -1306 -1255 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