File name: Pandora129s1_AliceSprings_20250424_L2Fit_fout2c5d20240111p1-8.txt File generation date: 20250424T151320.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Medhavy Thankappan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 129 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora129_OF_v3d20201201.txt Instrument calibration file used: Pandora129s1_CF_v5d20240111.txt Level 1 file used: Pandora129s1_AliceSprings_20250424_L1_smca1c5d20240111p1-8.txt Full location name: Geoscience Australia, Kilgariff NT Short location name: AliceSprings Country of location: Australia Location latitude [deg]: -23.7580 Location longitude [deg]: 133.8826 Location altitude [m]: 567 Local noon date: 20250424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 238 380 Nominal wavelengths inside fitting window [nm]: 305.0577 305.1987 305.3396 305.4806 305.6215 305.7624 305.9033 306.0442 306.1851 306.3260 306.4668 306.6077 306.7485 306.8893 307.0301 307.1709 307.3117 307.4525 307.5933 307.7340 307.8747 308.0155 308.1562 308.2969 308.4375 308.5782 308.7189 308.8595 309.0001 309.1408 309.2814 309.4220 309.5625 309.7031 309.8437 309.9842 310.1247 310.2653 310.4058 310.5462 310.6867 310.8272 310.9677 311.1081 311.2485 311.3889 311.5293 311.6697 311.8101 311.9505 312.0908 312.2312 312.3715 312.5118 312.6521 312.7924 312.9327 313.0730 313.2132 313.3535 313.4937 313.6339 313.7741 313.9143 314.0545 314.1947 314.3348 314.4750 314.6151 314.7552 314.8953 315.0354 315.1755 315.3156 315.4556 315.5957 315.7357 315.8757 316.0157 316.1557 316.2957 316.4357 316.5756 316.7156 316.8555 316.9954 317.1353 317.2752 317.4151 317.5550 317.6948 317.8347 317.9745 318.1143 318.2541 318.3939 318.5337 318.6735 318.8132 318.9530 319.0927 319.2324 319.3721 319.5118 319.6515 319.7912 319.9309 320.0705 320.2101 320.3498 320.4894 320.6290 320.7686 320.9081 321.0477 321.1872 321.3268 321.4663 321.6058 321.7453 321.8848 322.0243 322.1637 322.3032 322.4426 322.5821 322.7215 322.8609 323.0003 323.1396 323.2790 323.4183 323.5577 323.6970 323.8363 323.9756 324.1149 324.2542 324.3935 324.5327 324.6720 324.8112 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250423T215702.2Z 9244.914609 150 1 48.96 2 83.11 72.66 29.77 64.79 0.00 1 0.00 1 0 17 6.484e-01 1.150e-02 4.064e-01 7.849e-03 7.560196e-01 4.309083e-03 6.829061e-03 -6.000000e+00 3.616292e-01 226.49 -2.00 3.04 -2.00 322.12 0.00e+00 4.899740e-03 1.989693e-03 9.649216e-04 -6.000000e+00 1.479301e-02 288.16 -2.00 20.00 -2.00 321.75 0.00e+00 7.628 0.002 302.00 328.00 3 9.2003e-01 1.4481e-02 7.9077e-02 -6.0000e+00 9.0294e-01 1.4192e-01 2.3682e-02 3.6704e-02 -6.0000e+00 9.8622e-01 -3.0778e-01 2.9247e-02 2.1553e-02 -6.0000e+00 5.8064e-01 1.2687e-01 1.3674e-02 7.6520e-03 -6.0000e+00 2.4456e-01 9.5791e-05 -5.8454e-04 2.3597e-04 9.1301e-05 -6.0000e+00 1.6672e-02 -6.2953e-04 0.0000e+00 12 8 8 10 0 0 34.23 13.45 0.48 -0.00063 -0.00502 121 27 4 8 0 404.530 15.00 13.45 13.69 20.96 20.67 14.1 947.06 -229512 -181286 900000 103760 -238032 -236668 -225740 -157246 89424 -175940 -235606 -219469 -160868 -74454 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2019 1616 1091 682 1153 1270 1010 1649 2098 51 1423 202 230 -747 -910 -521 -1170 933 -473 -730 -459 -1152 436 1029 1325 163 -460 -1065 -903 -257 -1306 -1163 -1738 738 -347 -687 765 -1147 -616 -1668 -276 -1477 -1292 -325 -132 347 177 1318 1007 275 -178 -1707 186 -349 -494 960 -913 1177 1082 1815 -328 678 262 311 743 -436 -468 48 277 146 519 -890 -1414 809 1123 1403 -507 -481 -159 -1591 SS 20250423T220324.3Z 9244.919031 153 1 50.62 2 81.72 71.96 28.50 62.98 0.00 1 0.00 1 0 17 4.634e-01 7.557e-03 2.443e-01 3.409e-03 6.693972e-01 1.824415e-03 6.170491e-03 -6.000000e+00 2.584309e-01 226.49 -2.00 3.04 -2.00 321.72 0.00e+00 5.583114e-03 7.840628e-04 7.208664e-04 -6.000000e+00 1.056992e-02 288.16 -2.00 20.00 -2.00 321.36 0.00e+00 6.520 0.001 302.00 328.00 3 7.5065e-01 5.8127e-03 6.7919e-02 -6.0000e+00 6.4528e-01 -8.8444e-03 8.9654e-03 3.1898e-02 -6.0000e+00 7.0478e-01 -7.3123e-02 1.1162e-02 1.8303e-02 -6.0000e+00 4.1466e-01 3.0221e-02 5.3587e-03 6.3388e-03 -6.0000e+00 1.7389e-01 3.2422e-04 -2.9534e-04 1.0158e-04 7.2780e-05 -6.0000e+00 1.1929e-02 -8.1841e-04 0.0000e+00 11 8 0 10 0 0 0.38 13.44 0.40 -0.00082 -0.00304 239 54 4 8 0 204.920 15.00 13.44 14.63 20.96 20.67 14.2 953.11 44141 -179022 -200150 -118206 -185681 -48594 -197404 -73101 -126181 -166076 -123831 -150263 900000 -64490 134726 -53157 -49822 15016 -50818 3071 -43433 -5958 10891 -43628 -8194 -19188 -12696 -29269 8643 -27308 -30547 12593 -13562 -9435 -11133 -4647 1398 -12410 -3116 2385 -3348 -8761 3622 5260 7618 5702 1156 8849 5357 12333 -502 3571 5334 3589 5554 639 5310 -2388 559 7002 1054 5563 1731 7702 4112 2857 1236 -126 2481 1378 3011 -41 919 214 -1871 -2470 -6330 -2913 -3450 -1683 -1006 -1569 -2466 -2074 -815 -309 1342 711 1648 1688 47 151 -2191 -1214 -1447 -1522 -81 985 997 -211 -174 -899 -830 -533 -1231 -971 -1234 -408 669 1231 1425 621 688 -21 -409 -638 -536 -23 -223 58 -201 789 715 -41 -21 -749 27 42 -212 52 -202 -71 -317 50 -436 -321 395 693 281 -236 168 -275 -283 147 -1202 -1818 -483 -1339 -162 -1697 -243 -702 -1467 -766 -1380 900000 -453 448 -529 -550 101 -702 27 -619 -60 97 -709 -103 -283 -182 -483 100 -490 -687 230 -370 -269 -310 -121 38 -449 -126 110 -183 -544 213 316 460 365 80 597 394 915 -47 361 584 435 701 88 720 -348 77 900 149 835 307 1465 860 593 259 -28 592 387 921 -14 298 67 -545 -653 -1637 -747 -1006 -577 -402 -721 -1253 -1112 -462 -187 841 463 1066 1058 28 84 -1205 -684 -922 -1123 -68 937 1030 -220 -170 -800 -679 -443 -1119 -930 -1247 -438 780 1611 2071 964 1070 -31 -593 -894 -762 -35 -353 95 -328 1231 1084 -61 -30 -1051 36 60 -340 94 -398 -148 -692 115 -1074 -827 1034 1840 748 -609 409 -638 -637 SS 20250423T221921.9Z 9244.930114 158 1 51.32 2 78.27 70.14 25.42 57.80 0.00 1 0.00 1 0 25 1.226e-01 6.197e-03 3.224e-02 9.749e-04 5.138437e-01 4.977856e-04 4.972170e-03 -6.000000e+00 6.836537e-02 226.49 -2.00 3.04 -2.00 320.71 0.00e+00 3.581156e-03 1.690461e-04 3.399625e-04 -6.000000e+00 2.761174e-03 288.16 -2.00 20.00 -2.00 320.37 0.00e+00 4.763 0.001 302.00 328.00 3 4.9463e-01 1.4464e-03 4.9893e-02 -6.0000e+00 1.7070e-01 -2.3036e-02 1.8212e-03 2.3366e-02 -6.0000e+00 1.8644e-01 1.6616e-03 1.9530e-03 1.2412e-02 -6.0000e+00 1.0968e-01 -7.9202e-03 1.0154e-03 3.9812e-03 -6.0000e+00 4.5973e-02 2.2503e-03 -1.0813e-05 2.8476e-05 4.3735e-05 -6.0000e+00 3.1478e-03 -1.3155e-03 0.0000e+00 10 0 0 10 0 0 3.48 13.43 0.28 -0.00132 -0.00140 674 152 2 8 0 72.570 14.99 13.43 17.23 20.96 20.67 14.5 969.22 -41585 -35595 -23630 -35655 -61929 -38991 -55056 -34837 -26678 -37429 -21766 -37873 -28045 -16128 -4855 -12786 -6204 1202 2185 4516 -899 54 -4492 -3149 -5754 -9671 -7103 -10315 -8046 -9076 -3951 -1026 -132 381 -5362 -3858 -5281 -4361 -1208 -947 -352 -1421 142 114 823 867 884 650 -155 1344 1244 1728 1639 1206 1273 577 735 -1045 -728 -433 654 2037 2618 3459 1776 1326 588 -573 497 636 1045 724 711 492 -584 -1308 -2645 -3292 -2519 -2081 -1615 -1389 -2000 -1613 -810 -67 640 883 1459 1368 933 261 -626 -694 -643 -837 330 969 552 -258 -427 -794 -931 -797 -1273 -938 -561 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