File name: Pandora129s1_AliceSprings_20250818_L2Fit_fout2c5d20240111p1-8.txt File generation date: 20250818T152526.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Medhavy Thankappan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 129 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora129_OF_v3d20201201.txt Instrument calibration file used: Pandora129s1_CF_v5d20240111.txt Level 1 file used: Pandora129s1_AliceSprings_20250818_L1_smca1c5d20240111p1-8.txt Full location name: Geoscience Australia, Kilgariff NT Short location name: AliceSprings Country of location: Australia Location latitude [deg]: -23.7580 Location longitude [deg]: 133.8826 Location altitude [m]: 567 Local noon date: 20250818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 238 380 Nominal wavelengths inside fitting window [nm]: 305.0577 305.1987 305.3396 305.4806 305.6215 305.7624 305.9033 306.0442 306.1851 306.3260 306.4668 306.6077 306.7485 306.8893 307.0301 307.1709 307.3117 307.4525 307.5933 307.7340 307.8747 308.0155 308.1562 308.2969 308.4375 308.5782 308.7189 308.8595 309.0001 309.1408 309.2814 309.4220 309.5625 309.7031 309.8437 309.9842 310.1247 310.2653 310.4058 310.5462 310.6867 310.8272 310.9677 311.1081 311.2485 311.3889 311.5293 311.6697 311.8101 311.9505 312.0908 312.2312 312.3715 312.5118 312.6521 312.7924 312.9327 313.0730 313.2132 313.3535 313.4937 313.6339 313.7741 313.9143 314.0545 314.1947 314.3348 314.4750 314.6151 314.7552 314.8953 315.0354 315.1755 315.3156 315.4556 315.5957 315.7357 315.8757 316.0157 316.1557 316.2957 316.4357 316.5756 316.7156 316.8555 316.9954 317.1353 317.2752 317.4151 317.5550 317.6948 317.8347 317.9745 318.1143 318.2541 318.3939 318.5337 318.6735 318.8132 318.9530 319.0927 319.2324 319.3721 319.5118 319.6515 319.7912 319.9309 320.0705 320.2101 320.3498 320.4894 320.6290 320.7686 320.9081 321.0477 321.1872 321.3268 321.4663 321.6058 321.7453 321.8848 322.0243 322.1637 322.3032 322.4426 322.5821 322.7215 322.8609 323.0003 323.1396 323.2790 323.4183 323.5577 323.6970 323.8363 323.9756 324.1149 324.2542 324.3935 324.5327 324.6720 324.8112 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250817T220551.6Z 9360.920737 156 1 50.29 2 82.55 72.10 52.77 4.71 0.00 1 0.00 1 0 17 6.782e-01 1.256e-02 2.961e-01 4.553e-03 7.826579e-01 2.556470e-03 7.141250e-03 -6.000000e+00 3.840092e-01 227.16 -2.00 3.04 -2.00 322.04 0.00e+00 9.795063e-03 1.143253e-03 9.460753e-04 -6.000000e+00 1.645679e-02 285.13 -2.00 20.00 -2.00 321.68 0.00e+00 7.143 0.002 302.00 328.00 3 4.4464e-01 8.3686e-03 7.5904e-02 -6.0000e+00 9.6132e-01 2.1584e-01 1.3693e-02 3.7714e-02 -6.0000e+00 1.0514e+00 -3.3281e-01 1.7125e-02 2.2022e-02 -6.0000e+00 6.1521e-01 1.3820e-01 8.0469e-03 7.7647e-03 -6.0000e+00 2.5643e-01 2.0702e-04 -6.8903e-04 1.3473e-04 9.2475e-05 -6.0000e+00 1.7842e-02 -6.2865e-03 0.0000e+00 12 8 8 10 0 0 6.62 13.75 0.37 -0.00629 -0.01146 194 44 4 8 0 252.700 14.99 13.75 9.19 21.38 20.96 14.5 960.16 -184267 84253 94847 -252799 900000 -316146 900000 -229908 -169618 -181765 -202548 900000 -195034 900000 -56851 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1132 204 1468 465 1852 700 1251 979 96 1823 352 2158 754 707 196 -622 363 -1903 -202 -1098 176 -339 -1311 -34 -1587 246 55 342 455 -122 772 -1532 -533 -1557 -918 -1073 -736 1250 -112 221 -564 -150 -1145 -1233 -875 -2488 -723 -965 613 1019 1015 2038 -562 463 -1667 -571 -695 -968 949 -131 1477 830 1841 338 -692 648 -467 1430 -429 843 398 -407 403 -1462 41 -2020 1724 1306 429 658 -710 -114 -1922 SS 20250817T221208.9Z 9360.925103 159 1 50.75 2 81.18 71.40 52.68 3.02 0.00 1 0.00 1 0 17 4.235e-01 6.857e-03 2.008e-01 2.381e-03 6.995685e-01 1.269320e-03 6.452791e-03 -6.000000e+00 2.372105e-01 227.16 -2.00 3.04 -2.00 321.67 0.00e+00 5.894100e-03 5.446942e-04 7.409000e-04 -6.000000e+00 9.703306e-03 285.13 -2.00 20.00 -2.00 321.32 0.00e+00 6.169 0.001 302.00 328.00 3 4.0903e-01 4.0423e-03 6.5954e-02 -6.0000e+00 5.9294e-01 5.5832e-02 6.2106e-03 3.3316e-02 -6.0000e+00 6.4725e-01 -9.3531e-02 7.7413e-03 1.9117e-02 -6.0000e+00 3.8033e-01 3.4466e-02 3.7336e-03 6.5915e-03 -6.0000e+00 1.5949e-01 5.5956e-04 -2.8743e-04 6.9577e-05 7.4812e-05 -6.0000e+00 1.1014e-02 -6.0597e-03 0.0000e+00 11 8 0 10 0 0 25.42 13.76 0.31 -0.00606 -0.00822 332 75 2 8 0 147.490 15.00 13.76 10.29 21.38 20.96 14.7 966.74 -171075 -138825 -38798 -175159 900000 -174146 -94027 -150718 -131329 -115444 -151105 50352 -153004 39835 -30872 -2566 -21486 -55689 19195 -38955 -24313 -32704 -26931 -21142 -45617 -1199 -59951 -17244 -25891 -33535 6022 -22390 7151 -8987 8057 -12141 -2076 -3829 705 9049 -6332 7326 -2290 3070 2978 -202 10097 1001 7847 2313 6871 5423 3075 5968 2578 5002 468 1378 -291 -1136 1820 550 5377 4126 3368 2961 473 1201 -19 2780 549 911 -120 367 -1184 -2753 -2061 -4580 -2227 -2037 -1657 -782 -2702 -1048 -1146 -473 495 910 2012 1400 1499 -611 -562 -1371 -1214 -814 31 1397 123 226 -575 -697 -643 -1070 -1386 -1353 -412 -334 400 958 1035 939 580 126 -804 -370 -364 -232 25 -346 206 409 883 293 -342 -359 -610 400 -86 4 -95 -329 -77 -240 -232 -298 382 658 277 -9 -134 -118 -433 -903 -645 -90 -1294 900000 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3 3.2784e-01 1.4444e-03 5.1395e-02 -6.0000e+00 1.9750e-01 2.3409e-02 1.8722e-03 2.5961e-02 -6.0000e+00 2.1555e-01 -2.4566e-02 2.0867e-03 1.4029e-02 -6.0000e+00 1.2675e-01 1.9329e-03 1.0732e-03 4.5696e-03 -6.0000e+00 5.3092e-02 2.3619e-03 -2.3977e-04 2.7385e-05 5.0273e-05 -6.0000e+00 3.6239e-03 -6.4203e-03 0.0000e+00 10 0 0 10 0 0 7.72 13.77 0.29 -0.00642 -0.00822 713 161 2 8 0 68.620 15.00 13.77 12.84 21.38 20.96 14.9 981.72 -47229 -46679 -27242 -47042 -37401 -59765 -42589 -38412 -52756 -32271 -53731 -40741 -39165 -21713 -11796 -6107 -7350 -7706 2663 -3905 -2388 -3515 -5837 -6081 -9343 -5612 -7821 -10054 -9367 -10024 -4024 -4275 -1367 -1089 -3517 -2180 -5335 -2086 -1282 -1722 -715 -512 -599 615 1912 1117 952 391 1105 1024 956 1927 2177 2535 1384 1227 -291 -1482 -669 -943 478 1627 2905 3228 2014 1731 150 -109 215 784 831 632 770 115 -491 -1600 -2679 -3669 -2467 -1976 -1495 -1420 -2017 -1446 -844 16 711 763 1529 1449 1124 205 -884 -708 -834 -700 110 1060 485 -180 -370 -793 -787 -569 -1144 -1030 -721 -128 496 989 1096 811 512 -26 -460 -433 -216 -174 67 -179 60 332 484 57 -128 -575 -417 261 -101 -240 -167 -252 -197 -123 -326 -201 482 680 245 -45 -98 -199 -259 -295 -343 -180 -372 -244 -473 -305 -300 -540 -291 -564 -417 -500 -301 -188 -111 -152 -177 60 -100 -62 -92 -162 -184 -315 -193 -281 -360 -327 -376 -154 -196 -71 -61 -191 -114 -319 -143 -108 -174 -81 -62 -77 80 250 152 132 56 163 160 166 370 455 574 334 284 -71 -363 -158 -221 114 425 850 1059 702 583 50 -37 80 335 392 313 378 54 -212 -626 -980 -1352 -995 -940 -825 -891 -1390 -1045 -649 13 609 674 1342 1228 888 152 -626 -507 -663 -641 115 1165 584 -218 -419 -812 -794 -580 -1274 -1125 -825 -156 649 1433 1744 1358 854 -41 -693 -621 -310 -263 107 -302 101 538 755 86 -186 -808 -603 387 -156 -418 -315 -505 -410 -252 -719 -467 1136 1630 591 -106 -217 -414 -522 SS 20250817T223217.0Z 9360.939086 167 1 51.28 2 76.84 69.07 52.67 357.61 0.00 1 0.00 1 0 17 9.307e-02 6.175e-03 2.059e-02 6.863e-04 5.148872e-01 3.470658e-04 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