File name: Pandora129s1_AliceSprings_20250829_L2Fit_fout2c5d20240111p1-8.txt File generation date: 20250829T151812.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Medhavy Thankappan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 129 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora129_OF_v3d20201201.txt Instrument calibration file used: Pandora129s1_CF_v5d20240111.txt Level 1 file used: Pandora129s1_AliceSprings_20250829_L1_smca1c5d20240111p1-8.txt Full location name: Geoscience Australia, Kilgariff NT Short location name: AliceSprings Country of location: Australia Location latitude [deg]: -23.7580 Location longitude [deg]: 133.8826 Location altitude [m]: 567 Local noon date: 20250829 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 238 380 Nominal wavelengths inside fitting window [nm]: 305.0577 305.1987 305.3396 305.4806 305.6215 305.7624 305.9033 306.0442 306.1851 306.3260 306.4668 306.6077 306.7485 306.8893 307.0301 307.1709 307.3117 307.4525 307.5933 307.7340 307.8747 308.0155 308.1562 308.2969 308.4375 308.5782 308.7189 308.8595 309.0001 309.1408 309.2814 309.4220 309.5625 309.7031 309.8437 309.9842 310.1247 310.2653 310.4058 310.5462 310.6867 310.8272 310.9677 311.1081 311.2485 311.3889 311.5293 311.6697 311.8101 311.9505 312.0908 312.2312 312.3715 312.5118 312.6521 312.7924 312.9327 313.0730 313.2132 313.3535 313.4937 313.6339 313.7741 313.9143 314.0545 314.1947 314.3348 314.4750 314.6151 314.7552 314.8953 315.0354 315.1755 315.3156 315.4556 315.5957 315.7357 315.8757 316.0157 316.1557 316.2957 316.4357 316.5756 316.7156 316.8555 316.9954 317.1353 317.2752 317.4151 317.5550 317.6948 317.8347 317.9745 318.1143 318.2541 318.3939 318.5337 318.6735 318.8132 318.9530 319.0927 319.2324 319.3721 319.5118 319.6515 319.7912 319.9309 320.0705 320.2101 320.3498 320.4894 320.6290 320.7686 320.9081 321.0477 321.1872 321.3268 321.4663 321.6058 321.7453 321.8848 322.0243 322.1637 322.3032 322.4426 322.5821 322.7215 322.8609 323.0003 323.1396 323.2790 323.4183 323.5577 323.6970 323.8363 323.9756 324.1149 324.2542 324.3935 324.5327 324.6720 324.8112 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250828T215632.2Z 9371.914261 41 1 50.31 2 82.32 76.18 120.32 130.84 0.00 1 0.00 1 0 17 4.392e-01 7.939e-03 2.827e-01 3.867e-03 6.953319e-01 2.107323e-03 6.421621e-03 -6.000000e+00 2.478995e-01 227.57 -2.00 3.04 -2.00 321.79 0.00e+00 8.579630e-03 9.011826e-04 7.595612e-04 -6.000000e+00 1.020300e-02 285.32 -2.00 20.00 -2.00 321.42 0.00e+00 6.957 0.002 302.00 328.00 3 4.6419e-01 6.6886e-03 7.2382e-02 -6.0000e+00 6.2123e-01 8.9006e-02 1.0447e-02 3.3506e-02 -6.0000e+00 6.7823e-01 -1.3681e-01 1.3100e-02 1.9291e-02 -6.0000e+00 3.9676e-01 5.5504e-02 6.2802e-03 6.6915e-03 -6.0000e+00 1.6573e-01 2.6723e-04 -6.1069e-04 1.1496e-04 7.7505e-05 -6.0000e+00 1.1628e-02 -7.2172e-03 0.0000e+00 11 8 0 10 0 0 26.97 13.88 0.32 -0.00722 -0.01181 209 47 4 8 0 233.950 15.00 13.88 13.06 21.48 21.06 14.7 950.07 -141664 -186205 -78668 -226495 900000 -113821 -182385 900000 -196574 -28434 -128582 -61380 900000 -26455 79182 -104183 12630 -46916 47950 -48223 40017 -8568 -32592 24783 -58069 -16708 -23476 -28721 -10535 -22898 10211 -12438 11494 29178 10660 10003 -24976 22570 -26807 -872 6119 -2364 7961 -2164 8222 -5216 4087 7021 10439 11936 3358 9918 3836 4880 5174 2593 6785 -537 3019 15704 3234 1442 4713 6450 1159 2418 658 1983 1050 2790 1430 -687 1519 -840 -835 -2085 -2749 -5224 -2807 -941 -2628 -1455 -2488 -1418 -357 -1887 39 281 1222 1701 1615 -499 -2054 -1222 -2542 -1111 83 1526 804 109 14 -827 -1057 -934 -1176 -1332 -1035 -322 247 1216 1387 1032 835 -327 -638 -809 -125 -379 210 44 355 731 428 11 -250 -499 -525 383 -65 -252 -64 -168 -417 -16 -370 -224 294 708 93 -35 -25 -50 -216 -534 -1340 -296 -2716 900000 -429 -1312 900000 -2020 -107 -749 -231 900000 -118 298 -1678 74 -563 246 -694 247 -85 -424 195 -1114 -223 -346 -443 -137 -377 150 -286 248 580 245 226 -808 539 -1288 -39 288 -131 428 -135 475 -360 268 472 721 877 279 877 398 549 616 329 852 -72 383 1735 422 214 784 1214 247 501 137 422 251 765 410 -211 487 -260 -236 -535 -665 -1324 -790 -315 -1059 -620 -1184 -708 -189 -1086 23 173 748 1002 889 -262 -1055 -644 -1541 -780 67 1418 832 114 14 -736 -851 -753 -1031 -1240 -1014 -337 283 1564 1997 1591 1302 -500 -926 -1129 -175 -560 329 72 574 1127 639 17 -351 -681 -690 522 -102 -452 -127 -356 -936 -38 -887 -566 755 1844 245 -88 -64 -118 -497 SS 20250828T220251.3Z 9371.918650 44 1 51.09 2 80.91 75.50 119.25 129.74 0.00 1 0.00 1 0 17 3.041e-01 6.935e-03 1.518e-01 2.058e-03 6.211540e-01 1.084577e-03 5.833463e-03 -6.000000e+00 1.704086e-01 227.58 -2.00 3.04 -2.00 321.37 0.00e+00 5.220921e-03 4.305548e-04 5.578761e-04 -6.000000e+00 6.848052e-03 285.32 -2.00 20.00 -2.00 321.01 0.00e+00 6.006 0.001 302.00 328.00 3 4.0790e-01 3.3195e-03 6.2759e-02 -6.0000e+00 4.2656e-01 3.6765e-02 4.7082e-03 2.9198e-02 -6.0000e+00 4.6539e-01 -4.8872e-02 5.6466e-03 1.6288e-02 -6.0000e+00 2.7358e-01 1.3842e-02 2.7925e-03 5.4951e-03 -6.0000e+00 1.1450e-01 7.0520e-04 -4.3467e-04 6.0292e-05 6.0461e-05 -6.0000e+00 7.8075e-03 -7.0254e-03 0.0000e+00 11 8 0 10 0 0 0.07 13.88 0.30 -0.00703 -0.01029 356 80 2 8 0 137.670 15.00 13.88 13.94 21.48 21.06 14.9 956.20 -65270 -148974 21862 -133783 -21892 -82568 -148491 -29671 -115175 -56567 -105116 -82231 -76765 -59343 6678 -35883 3166 -30547 7960 3459 -3965 13706 -32410 12796 -19035 -18777 -6005 -21669 -7774 -25626 22124 -14916 6735 2735 -3994 -3601 -7910 7580 -2717 169 -456 -246 4702 -339 5312 5028 4702 -32 445 4688 1900 7259 2007 5055 969 2273 544 -1911 -46 -2119 2156 1210 3258 3920 2024 2692 141 550 443 1296 1310 -289 583 -426 -292 -2995 -2986 -4049 -4121 -1439 -1807 -1027 -1966 -1534 -847 -408 917 598 2188 1234 1436 -65 -1572 -951 -1578 -655 -10 1449 627 -178 -373 -1023 -395 -849 -1023 -1216 -709 -59 419 1154 1086 918 552 -149 -620 -480 -244 -280 62 58 90 545 468 229 -211 -504 -466 174 29 -557 -107 -306 -124 -246 -337 -240 466 838 368 -57 -30 -322 -220 -236 -1359 44 -1147 -62 -414 -1409 -107 -1009 -329 -940 -660 -756 -650 54 -491 34 -507 99 48 -62 178 -692 189 -417 -435 -126 -522 -162 -692 448 -487 227 96 -144 -127 -320 313 -154 11 -34 -20 387 -30 461 453 438 -3 47 509 237 892 286 762 161 389 98 -352 -8 -377 381 240 724 984 549 706 37 148 132 445 499 -117 233 -163 -102 -965 -894 -1235 -1410 -573 -848 -548 -1162 -956 -561 -289 677 457 1653 910 984 -42 -986 -606 -1134 -542 -9 1454 696 -200 -393 -974 -340 -798 -972 -1226 -749 -66 511 1569 1640 1470 886 -232 -913 -674 -343 -416 97 96 148 859 712 338 -301 -750 -665 256 45 -981 -206 -627 -266 -559 -823 -577 1138 2080 921 -147 -74 -742 -491 SS 20250828T221450.8Z 9371.926976 49 1 50.92 2 78.26 74.16 117.16 127.73 0.00 1 0.00 1 0 25 9.871e-02 6.261e-03 2.795e-02 9.011e-04 5.103786e-01 4.615588e-04 4.968434e-03 -6.000000e+00 5.532447e-02 227.58 -2.00 3.04 -2.00 320.59 0.00e+00 3.480159e-03 1.510841e-04 3.211322e-04 -6.000000e+00 2.223008e-03 285.32 -2.00 20.00 -2.00 320.26 0.00e+00 4.761 0.001 302.00 328.00 3 3.4039e-01 1.3330e-03 4.9999e-02 -6.0000e+00 1.3849e-01 2.2880e-02 1.6580e-03 2.3321e-02 -6.0000e+00 1.5109e-01 -1.7073e-02 1.7428e-03 1.2323e-02 -6.0000e+00 8.8819e-02 -1.5765e-03 9.1157e-04 3.9325e-03 -6.0000e+00 3.7178e-02 2.5397e-03 -2.4180e-04 2.6134e-05 4.2567e-05 -6.0000e+00 2.5345e-03 -7.6518e-03 0.0000e+00 10 0 0 10 0 0 11.01 13.88 0.28 -0.00765 -0.00947 697 157 2 8 0 70.220 14.99 13.88 16.08 21.48 21.06 15.1 968.70 -17992 -35522 -25974 -27486 -41818 -30598 -38941 -19488 -39799 -21904 -34066 -33652 -19836 -17899 -6949 -3390 -3966 -3190 -1292 737 -377 1103 -4497 -2463 -4997 -4980 -5701 -9438 -5662 -5985 -2163 -372 1358 356 -5325 -4454 -6275 -2579 -3265 -1467 -117 -813 111 -354 931 958 1136 1026 -45 1184 1371 1486 1945 1654 1329 680 -196 -821 -600 -214 277 2054 2517 3310 1880 1504 320 -642 174 481 1052 694 761 294 -594 -1435 -2596 -3200 -2646 -2129 -1501 -1448 -2105 -1718 -683 -60 450 859 1607 1508 734 162 -812 -697 -606 -801 105 985 475 -117 -315 -795 -897 -700 -1075 -967 -699 -183 596 1064 1168 798 622 2 -500 -341 -377 -260 134 -93 -27 275 459 -46 -86 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