File name: Pandora129s1_AliceSprings_20250909_L2Fit_fwvt1c5d20240111p1-8.txt File generation date: 20250909T151413.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Medhavy Thankappan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 129 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora129_OF_v3d20201201.txt Instrument calibration file used: Pandora129s1_CF_v5d20240111.txt Level 1 file used: Pandora129s1_AliceSprings_20250909_L1_smca1c5d20240111p1-8.txt Full location name: Geoscience Australia, Kilgariff NT Short location name: AliceSprings Country of location: Australia Location latitude [deg]: -23.7580 Location longitude [deg]: 133.8826 Location altitude [m]: 567 Local noon date: 20250909 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1660 1810 Nominal wavelengths inside fitting window [nm]: 492.0419 492.1627 492.2835 492.4043 492.5251 492.6458 492.7665 492.8873 493.0080 493.1287 493.2493 493.3700 493.4906 493.6112 493.7318 493.8524 493.9730 494.0935 494.2141 494.3346 494.4551 494.5756 494.6961 494.8165 494.9369 495.0574 495.1778 495.2981 495.4185 495.5389 495.6592 495.7795 495.8998 496.0201 496.1404 496.2606 496.3808 496.5011 496.6213 496.7414 496.8616 496.9817 497.1019 497.2220 497.3421 497.4622 497.5822 497.7023 497.8223 497.9423 498.0623 498.1823 498.3023 498.4222 498.5421 498.6620 498.7819 498.9018 499.0217 499.1415 499.2613 499.3811 499.5009 499.6207 499.7405 499.8602 499.9799 500.0996 500.2193 500.3390 500.4587 500.5783 500.6979 500.8175 500.9371 501.0567 501.1762 501.2958 501.4153 501.5348 501.6543 501.7738 501.8932 502.0127 502.1321 502.2515 502.3709 502.4902 502.6096 502.7289 502.8482 502.9675 503.0868 503.2061 503.3253 503.4446 503.5638 503.6830 503.8021 503.9213 504.0405 504.1596 504.2787 504.3978 504.5169 504.6359 504.7550 504.8740 504.9930 505.1120 505.2310 505.3499 505.4689 505.5878 505.7067 505.8256 505.9445 506.0633 506.1822 506.3010 506.4198 506.5386 506.6573 506.7761 506.8948 507.0136 507.1323 507.2509 507.3696 507.4883 507.6069 507.7255 507.8441 507.9627 508.0813 508.1998 508.3183 508.4369 508.5554 508.6738 508.7923 508.9107 509.0292 509.1476 509.2660 509.3843 509.5027 509.6211 509.7394 509.8577 509.9760 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250908T231226.5Z 9382.966973 251 1 43.72 2 62.99 70.26 108.58 264.63 0.00 1 0.00 1 0 15 2.586e-03 2.579e-03 8.161e-04 8.134e-04 3.968638e+03 5.196115e+01 2.825958e+02 -6.000000e+00 1.462163e+02 285.50 -2.00 20.00 -2.00 505.24 0.00e+00 4.423127e-04 2.253064e-05 2.934703e-05 -6.000000e+00 7.307945e-05 285.50 -2.00 20.00 -2.00 500.29 0.00e+00 2.242567e-01 1.618894e-02 2.617536e-02 -6.000000e+00 5.109524e-02 227.99 -2.00 3.04 -2.00 501.91 0.00e+00 2.190 0.000 489.00 513.00 1 6.8854e+00 1.2440e-03 3.7601e-03 -6.0000e+00 3.9276e-03 1.5012e-02 3.1740e-04 6.5709e-04 -6.0000e+00 1.0088e-03 1.4527e-03 1.3699e-03 8.0830e-05 3.1332e-05 -6.0000e+00 2.6832e-04 -5.0030e-03 -4.6731e-05 10 0 0 10 0 0 99.98 13.64 2.04 -0.00500 0.00450 31 8 1 2 0 1409.920 15.00 13.64 25.68 21.27 20.87 15.2 948.78 -368 -497 -145 -303 177 562 213 333 256 284 76 -261 -70 -251 -24 -137 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-284 -387 -268 -661 -482 -219 -113 -31 -94 -207 -42 129 247 459 648 697 283 342 392 -41 284 35 200 13 52 167 87 309 0 42 -73 -206 -168 -259 29 -160 -22 -61 203 216 113 271 154 142 -146 -211 -240 -250 -76 -203 SQ 20250908T232613.3Z 9382.976542 259 1 1.31 2 60.04 68.27 111.62 263.24 0.00 1 0.00 1 0 15 2.756e-03 2.754e-03 8.082e-04 8.069e-04 3.427203e+03 5.039051e+01 2.350930e+02 -6.000000e+00 1.558336e+02 285.51 -2.00 20.00 -2.00 505.26 0.00e+00 4.971374e-04 2.233670e-05 3.335554e-05 -6.000000e+00 7.788123e-05 285.51 -2.00 20.00 -2.00 500.43 0.00e+00 1.457096e-01 1.589887e-02 2.556222e-02 -6.000000e+00 5.443377e-02 227.99 -2.00 3.04 -2.00 502.03 0.00e+00 1.994 0.000 489.00 513.00 1 3.6635e+00 1.2213e-03 3.5214e-03 -6.0000e+00 4.1846e-03 1.6947e-03 3.1163e-04 6.0918e-04 -6.0000e+00 1.0743e-03 3.7624e-02 6.3078e-04 8.0855e-05 2.7484e-05 -6.0000e+00 2.8592e-04 -6.8523e-03 -6.5311e-06 12 1 1 12 1 1 70.86 13.63 1.95 -0.00685 -0.00248 13 119 1 2 0 92.880 15.00 13.63 26.59 21.27 20.87 15.3 954.42 -375 -403 -363 -211 220 591 480 489 333 295 126 -72 -247 -97 -158 -98 -5 41 28 -140 238 48 177 220 299 260 -12 -183 -401 -171 -183 -299 -1 28 -117 -162 -67 185 35 59 173 207 290 325 236 334 354 216 -9 -307 -373 -565 -515 -448 -549 -262 -286 -98 103 319 361 361 395 441 188 222 75 -93 -293 -146 -67 -186 -230 -88 -187 -303 -317 -172 -352 -243 -397 -420 -601 -120 67 -246 -62 -69 -27 8 188 157 166 55 364 167 53 -81 -93 -385 -525 -243 -228 -357 -313 -437 -132 -164 -58 113 -116 -159 74 253 568 715 649 538 348 300 371 232 243 229 -22 -49 103 104 65 145 -178 -127 -14 -107 -87 -9 -57 -204 -51 297 76 236 240 302 52 -20 -94 -362 -231 -262 -284 -369 -402 -366 -215 226 609 503 509 347 310 130 -74 -254 -98 -159 -99 -5 42 29 -147 251 51 187 233 317 275 -13 -192 -418 -173 -184 -301 -1 29 -122 -170 -69 193 36 60 177 212 300 339 245 347 366 225 -9 -308 -370 -557 -501 -437 -539 -264 -290 -101 106 327 370 371 400 446 190 225 75 -93 -290 -143 -66 -180 -225 -87 -184 -297 -312 -166 -337 -235 -385 -403 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1.89 -0.00542 0.00225 34 8 1 2 0 1270.930 15.00 13.64 27.75 21.27 20.87 15.3 959.48 -397 -390 -378 -436 -7 602 314 141 410 147 -21 -116 -382 52 -136 111 -67 16 -227 -164 166 267 94 389 -49 149 -106 -225 -237 -217 -79 -149 424 253 -172 -149 41 342 66 -80 -3 -95 321 495 526 289 338 366 -81 -418 -401 -331 -523 -413 -509 -282 -7 -136 162 93 492 392 337 262 237 36 84 -84 -224 -266 23 -309 -160 -61 -21 -55 -345 -177 -304 -235 -69 -268 -344 -172 170 -327 132 295 -19 73 -9 193 257 251 29 406 78 -139 -357 103 -373 -43 -466 -202 -371 -399 -333 3 -244 204 121 -125 -162 66 359 377 594 326 374 137 166 413 228 372 -74 -61 252 174 174 -103 -70 -25 -238 -90 -455 39 -122 -108 -137 -143 186 267 199 177 172 -26 -65 -271 -347 -281 -279 -391 -389 -388 -463 -7 631 336 152 442 157 -22 -121 -393 52 -137 112 -69 17 -243 -178 180 290 102 423 -54 163 -116 -242 -250 -222 -79 -149 431 266 -187 -163 44 367 70 -85 -4 -100 342 531 569 314 365 390 -85 -431 -402 -323 -505 -400 -505 -287 -7 -144 171 93 515 393 340 264 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