File name: Pandora65s1_Altzomoni_20191012_L2Fit_fwvt1c3d20191005p1-8.txt File generation date: 20260113T075615.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 65 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora65_OF_v2d20180919.txt Instrument calibration file used: Pandora65s1_CF_v3d20191005.txt Level 1 file used: Pandora65s1_Altzomoni_20191012_L1_smca1c3d20191005p1-8.txt Full location name: Observatorio Atmosferico Altzomoni, UNAM Short location name: Altzomoni Country of location: Mexico Location latitude [deg]: 19.1187 Location longitude [deg]: -98.6552 Location altitude [m]: 3985 Local noon date: 20191012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1701 1851 Nominal wavelengths inside fitting window [nm]: 492.0002 492.1208 492.2415 492.3621 492.4827 492.6033 492.7239 492.8445 492.9650 493.0855 493.2060 493.3265 493.4470 493.5675 493.6879 493.8083 493.9287 494.0491 494.1695 494.2899 494.4102 494.5305 494.6508 494.7711 494.8914 495.0116 495.1319 495.2521 495.3723 495.4925 495.6127 495.7328 495.8529 495.9731 496.0932 496.2132 496.3333 496.4533 496.5734 496.6934 496.8134 496.9334 497.0533 497.1733 497.2932 497.4131 497.5330 497.6529 497.7727 497.8925 498.0124 498.1322 498.2519 498.3717 498.4915 498.6112 498.7309 498.8506 498.9703 499.0899 499.2096 499.3292 499.4488 499.5684 499.6880 499.8075 499.9271 500.0466 500.1661 500.2856 500.4050 500.5245 500.6439 500.7633 500.8827 501.0021 501.1215 501.2408 501.3601 501.4794 501.5987 501.7180 501.8372 501.9565 502.0757 502.1949 502.3141 502.4332 502.5524 502.6715 502.7906 502.9097 503.0288 503.1478 503.2669 503.3859 503.5049 503.6238 503.7428 503.8618 503.9807 504.0996 504.2185 504.3373 504.4562 504.5750 504.6939 504.8127 504.9314 505.0502 505.1689 505.2877 505.4064 505.5251 505.6437 505.7624 505.8810 505.9996 506.1182 506.2368 506.3554 506.4739 506.5924 506.7109 506.8294 506.9479 507.0663 507.1848 507.3032 507.4216 507.5399 507.6583 507.7766 507.8950 508.0133 508.1315 508.2498 508.3680 508.4863 508.6045 508.7227 508.8408 508.9590 509.0771 509.1952 509.3133 509.4314 509.5495 509.6675 509.7855 509.9035 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191012T123308.0Z 7224.523009 260 1 32.01 2 89.62 97.97 105.93 272.08 0.00 1 0.00 1 0 15 4.222e-02 4.177e-02 5.741e-02 5.701e-02 2.598320e+03 3.352369e+03 6.632398e+01 -6.000000e+00 2.200148e+03 272.22 -2.00 20.00 -2.00 505.29 0.00e+00 1.820574e-03 1.520623e-03 1.499348e-04 -6.000000e+00 1.143764e-03 272.22 -2.00 20.00 -2.00 500.37 0.00e+00 2.073397e+00 1.137839e+00 5.856964e-02 -6.000000e+00 8.336075e-01 225.15 -2.00 3.11 -2.00 501.98 0.00e+00 20.584 0.037 489.00 513.00 1 1.0099e+01 8.6822e-02 1.9521e-02 -6.0000e+00 6.3520e-02 3.4211e-02 2.2500e-02 1.3945e-03 -6.0000e+00 1.6771e-02 1.0755e-05 -9.6376e-04 5.2587e-03 4.9915e-05 -6.0000e+00 3.9942e-03 7.7263e-03 -9.7324e-05 12 8 8 10 0 0 -109.20 20.93 8.63 0.00773 0.00104 8 2 1 4 0 4000.000 24.86 20.00 20.93 900000 5244 -4367 -1291 6705 -1341 2820 -1762 6330 2614 6386 -1292 1219 -6608 1283 -4899 -3461 -18 -1161 3446 -3282 -3117 -7225 1753 -1827 5885 -449 -723 -2713 1311 9123 -9394 1352 -659 6674 10316 8795 -2226 4685 -4222 1259 -5312 3641 812 -2036 5656 1194 3746 -4198 2236 -3210 -5711 839 -5591 -4413 -2003 355 2565 2352 7978 2730 -380 1409 230 2063 -4031 925 -3142 3002 1257 384 -7897 -1467 3547 2058 3863 -3275 2022 -6447 490 1561 5405 -4666 -2496 -14 -6543 3759 -4290 -1175 -4948 -2761 -3478 961 1512 -6221 1701 -2889 -1301 869 9167 520 2469 -6027 -6607 1776 1786 864 1697 1161 1518 -1530 10386 7281 4703 3299 -1063 4171 -185 -1762 939 1807 5652 185 -1934 -5303 1231 -3095 355 -1781 4524 -6207 6958 4306 -709 5075 -5494 7506 -5698 2307 58 1025 -3565 2941 -8217 6136 6656 969 -2009 -1954 -4821 2744 900000 4650 -4264 -1271 6320 -1403 2887 -1921 6401 2722 6317 -1363 1237 -7113 1262 -5136 -3613 -19 -1235 3581 -3681 -3501 -8294 1841 -1997 5990 -487 -783 -2948 1323 8267 -10195 1329 -674 6588 10101 8763 -2449 4753 -4629 1299 -5874 3719 864 -2255 5854 1293 3925 -4606 2302 -3388 -5870 807 -5590 -4417 -2014 360 2593 2404 7701 2767 -398 1458 242 2120 -4359 937 -3264 2894 1215 368 -8196 -1439 3340 1987 3685 -3333 1918 -6412 459 1437 4818 -4558 -2397 -13 -6672 3487 -4309 -1140 -4991 -2737 -3497 938 1490 -6636 1656 -2898 -1258 799 7530 458 2134 -5762 -6549 1681 1731 831 1601 1083 1399 -1465 8981 6609 4446 3200 -1085 4063 -189 -1838 945 1778 5276 180 -1909 -5451 1194 -3142 349 -1789 4262 -6392 6353 3968 -665 4541 -5338 6479 -5759 2201 58 1016 -3731 2898 -9111 5930 6412 981 -2058 -1950 -4858 2554 SO 20191012T123726.0Z 7224.525995 264 1 32.01 2 88.62 98.33 106.91 272.44 0.00 1 0.00 1 0 15 1.740e-02 1.740e-02 2.256e-02 2.246e-02 4.468161e+03 1.369859e+03 2.744443e+02 -6.000000e+00 9.069159e+02 272.22 -2.00 20.00 -2.00 505.32 0.00e+00 7.966885e-04 5.982982e-04 5.401057e-05 -6.000000e+00 4.715737e-04 272.22 -2.00 20.00 -2.00 500.45 0.00e+00 1.369127e+00 4.443098e-01 4.730866e-02 -6.000000e+00 3.438860e-01 225.15 -2.00 3.11 -2.00 502.05 0.00e+00 18.272 0.026 489.00 513.00 1 9.4113e+00 3.3843e-02 1.6971e-02 -6.0000e+00 2.6199e-02 2.3269e-02 8.7739e-03 1.3469e-03 -6.0000e+00 6.9248e-03 2.8036e-05 3.6905e-04 2.0585e-03 4.0590e-05 -6.0000e+00 1.6463e-03 1.3629e-02 -1.9593e-04 12 9 8 11 8 0 99.89 20.92 3.18 0.01363 0.01619 8 2 1 4 0 4000.000 24.86 20.00 20.92 900000 -1008 640 1076 1677 -695 390 571 1937 -446 -2990 1501 -25 -2369 -2876 352 -1707 -358 1847 1455 269 -920 3514 -901 4269 -761 -782 150 2343 -1572 -1761 2129 1788 388 -4215 2088 -237 791 -1543 -961 -2250 3851 -199 1087 225 911 -871 -1483 -478 -479 1351 -425 -830 -5470 377 386 1329 -172 1607 2226 -86 954 -1107 1771 -1970 901 404 603 -1583 1519 -432 -2401 455 -1044 1101 609 804 2994 533 -530 -1691 -2495 -273 -934 -733 -2489 2050 86 -2276 319 268 4305 -3533 522 -1689 -2952 1140 -226 3794 -775 124 87 103 -1860 -2048 -2245 2113 -1017 -672 167 1670 -63 -418 1521 1155 4505 -593 1076 954 1175 643 1028 355 -91 -1122 -2255 -844 591 1903 -456 2388 -3029 -204 385 2351 -349 -1703 100 -2724 3263 -1035 2179 -2030 586 -621 2017 673 -1502 -759 -1428 1425 900000 -922 588 1023 1644 -715 405 602 2026 -474 -3218 1527 -25 -2425 -2925 347 -1738 -366 1895 1534 284 -986 3608 -967 4370 -824 -847 160 2406 -1623 -1770 2049 1742 392 -4621 2211 -258 841 -1660 -1016 -2394 3866 -210 1146 242 982 -938 -1594 -502 -493 1326 -412 -790 -5426 357 377 1324 -178 1645 2263 -89 980 -1169 1823 -2098 924 410 602 -1594 1461 -418 -2357 438 -1031 1075 590 772 2766 496 -492 -1582 -2369 -256 -889 -701 -2458 1953 84 -2258 309 260 4048 -3643 524 -1732 -3021 1099 -215 3375 -702 110 77 93 -1738 -1998 -2255 2043 -1006 -653 160 1579 -62 -417 1504 1158 4392 -611 1101 981 1197 650 1019 349 -89 -1117 -2243 -830 574 1824 -446 2274 -3022 -195 360 2141 -326 -1630 97 -2763 3163 -1060 2182 -2132 603 -651 2063 693 -1553 -760 -1413 1365 SO 20191012T124142.0Z 7224.528958 268 1 32.01 2 87.62 98.68 107.88 272.81 0.00 1 0.00 1 0 15 1.948e-02 1.939e-02 1.958e-02 1.949e-02 3.855420e+03 1.168345e+03 3.687908e+02 -6.000000e+00 1.014888e+03 272.22 -2.00 20.00 -2.00 505.30 0.00e+00 1.025580e-03 5.162038e-04 5.657373e-05 -6.000000e+00 5.275588e-04 272.22 -2.00 20.00 -2.00 500.43 0.00e+00 8.385873e-01 3.845146e-01 1.500339e-02 -6.000000e+00 3.843958e-01 225.15 -2.00 3.11 -2.00 502.03 0.00e+00 15.452 0.016 489.00 513.00 1 9.5521e+00 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