File name: Pandora65s1_Altzomoni_20191022_L2Fit_fwvt1c3d20191005p1-8.txt File generation date: 20260113T075646.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 65 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora65_OF_v2d20180919.txt Instrument calibration file used: Pandora65s1_CF_v3d20191005.txt Level 1 file used: Pandora65s1_Altzomoni_20191022_L1_smca1c3d20191005p1-8.txt Full location name: Observatorio Atmosferico Altzomoni, UNAM Short location name: Altzomoni Country of location: Mexico Location latitude [deg]: 19.1187 Location longitude [deg]: -98.6552 Location altitude [m]: 3985 Local noon date: 20191022 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1701 1851 Nominal wavelengths inside fitting window [nm]: 492.0002 492.1208 492.2415 492.3621 492.4827 492.6033 492.7239 492.8445 492.9650 493.0855 493.2060 493.3265 493.4470 493.5675 493.6879 493.8083 493.9287 494.0491 494.1695 494.2899 494.4102 494.5305 494.6508 494.7711 494.8914 495.0116 495.1319 495.2521 495.3723 495.4925 495.6127 495.7328 495.8529 495.9731 496.0932 496.2132 496.3333 496.4533 496.5734 496.6934 496.8134 496.9334 497.0533 497.1733 497.2932 497.4131 497.5330 497.6529 497.7727 497.8925 498.0124 498.1322 498.2519 498.3717 498.4915 498.6112 498.7309 498.8506 498.9703 499.0899 499.2096 499.3292 499.4488 499.5684 499.6880 499.8075 499.9271 500.0466 500.1661 500.2856 500.4050 500.5245 500.6439 500.7633 500.8827 501.0021 501.1215 501.2408 501.3601 501.4794 501.5987 501.7180 501.8372 501.9565 502.0757 502.1949 502.3141 502.4332 502.5524 502.6715 502.7906 502.9097 503.0288 503.1478 503.2669 503.3859 503.5049 503.6238 503.7428 503.8618 503.9807 504.0996 504.2185 504.3373 504.4562 504.5750 504.6939 504.8127 504.9314 505.0502 505.1689 505.2877 505.4064 505.5251 505.6437 505.7624 505.8810 505.9996 506.1182 506.2368 506.3554 506.4739 506.5924 506.7109 506.8294 506.9479 507.0663 507.1848 507.3032 507.4216 507.5399 507.6583 507.7766 507.8950 508.0133 508.1315 508.2498 508.3680 508.4863 508.6045 508.7227 508.8408 508.9590 509.0771 509.1952 509.3133 509.4314 509.5495 509.6675 509.7855 509.9035 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20191022T123620.0Z 7234.525232 267 1 32.01 2 89.62 101.85 13.24 84.88 0.00 1 0.00 1 0 15 3.386e-02 3.296e-02 4.404e-02 4.370e-02 1.094661e+04 2.927194e+03 8.825611e+02 -6.000000e+00 1.762278e+03 271.96 -2.00 20.00 -2.00 505.45 0.00e+00 2.297136e-03 1.167986e-03 1.565230e-04 -6.000000e+00 9.166218e-04 271.96 -2.00 20.00 -2.00 500.91 0.00e+00 1.370282e+00 8.489128e-01 6.016292e-02 -6.000000e+00 6.684575e-01 224.88 -2.00 3.11 -2.00 502.44 0.00e+00 20.592 0.037 489.00 513.00 1 9.8626e+00 6.4503e-02 1.9788e-02 -6.0000e+00 5.0930e-02 -3.1238e-02 1.6413e-02 2.0284e-03 -6.0000e+00 1.3452e-02 1.4059e-05 3.2551e-03 3.8956e-03 1.2291e-04 -6.0000e+00 3.2027e-03 5.5128e-02 -4.0440e-04 12 8 8 10 0 0 55.41 20.77 2.64 0.05513 0.07771 8 2 1 4 0 4000.000 24.75 20.00 20.77 900000 1223 955 -2997 4501 -1661 4545 5532 566 699 -852 7270 3409 1083 -3358 -2739 -11 1506 -420 -2409 5448 1197 2308 3457 -721 -600 -1378 -1094 -4990 1920 -4796 226 2054 1108 -3342 -136 5787 3322 -2391 276 -5318 1104 -5941 393 18 1387 -1076 -4642 -761 2197 3498 -6411 520 -1895 1227 -3100 836 5620 -3946 -2139 1894 1296 -7063 6285 -574 -1380 1020 -954 -2897 -282 5000 2792 1585 1068 929 1662 -1182 -2714 -3464 -1286 -719 -794 5709 9523 5310 -3941 -2653 4947 -4986 -3958 -119 166 -3839 -186 -4110 -298 3512 -4158 9698 -2156 5820 -9966 4982 4095 -3514 -4632 -522 -187 3967 -1700 -795 2965 4557 -2071 -491 498 2065 1924 -2438 -1783 6410 -1341 32 5058 -3842 -4147 186 -67 -2696 -1002 1434 -1632 1492 3668 -1298 -2382 3253 490 4414 3102 -935 -2773 438 -196 771 4837 771 824 2292 517 -4319 900000 1022 823 -2805 4043 -1624 4265 5221 563 688 -840 6543 3141 1003 -3232 -2636 -11 1435 -411 -2452 5165 1188 2271 3371 -738 -617 -1430 -1126 -5232 1816 -4744 213 1923 1076 -3528 -142 5694 3315 -2501 279 -5665 1112 -6369 402 19 1434 -1140 -5056 -787 2162 3298 -6489 483 -1807 1155 -3149 842 5496 -4278 -2275 1931 1336 -7977 6232 -608 -1457 1035 -975 -2982 -279 4628 2645 1505 1030 907 1619 -1173 -2686 -3400 -1221 -677 -754 5133 8291 4873 -4027 -2695 4643 -5141 -4034 -117 165 -4022 -189 -4231 -294 3244 -3941 7906 -1894 4764 -9454 4184 3625 -3519 -4836 -528 -187 3766 -1701 -798 2918 4469 -2190 -515 519 2139 2025 -2704 -1956 6387 -1392 32 4906 -4025 -4392 190 -69 -2847 -1039 1451 -1687 1469 3505 -1300 -2419 3182 507 4471 3233 -1030 -3143 485 -220 861 5178 852 894 2400 534 -4692 SO 20191022T124037.0Z 7234.528206 271 1 32.01 2 88.63 102.20 12.25 84.86 0.00 1 0.00 1 0 22 7.993e-02 7.674e-02 1.078e-01 1.060e-01 -3.994603e+02 5.797823e+03 4.531472e+01 -6.000000e+00 4.161021e+03 271.96 -2.00 20.00 -2.00 505.31 0.00e+00 2.569921e-03 2.806240e-03 1.598041e-04 -6.000000e+00 2.164004e-03 271.96 -2.00 20.00 -2.00 500.26 0.00e+00 3.901857e+00 2.114811e+00 4.568013e-02 -6.000000e+00 1.577371e+00 224.88 -2.00 3.11 -2.00 501.90 0.00e+00 18.318 0.026 489.00 513.00 1 1.0801e+01 1.6160e-01 1.7294e-02 -6.0000e+00 1.2020e-01 -8.5756e-05 4.1784e-02 1.1414e-03 -6.0000e+00 3.1717e-02 5.6337e-06 5.7990e-03 9.8835e-03 5.3369e-05 -6.0000e+00 7.5620e-03 -1.5817e-02 7.8917e-05 12 8 8 10 0 0 -9.77 20.77 5.61 -0.01582 0.02441 8 2 1 4 0 4000.000 24.75 20.00 20.77 900000 -3282 4219 5034 16124 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-6633 14162 985 6421 3908 9982 9593 -301 -10114 1074 91 73 14679 12124 13731 -8941 -298 4040 -11444 5115 -3378 5849 -4577 11867 13463 -7375 -6458 -9293 11485 1089 -10382 -5702 -12974 2265 9336 -712 7631 -4009 -6164 -6890 2998 -3385 -8693 -1524 -1069 6898 -3707 16195 -6146 -10353 1558 -592 242 11341 -3189 3317 2625 1871 6336 -431 -730 -9572 12571 11370 5737 -6088 -11675 6788 -2276 -2544 -6002 -3151 -1017 -8312 3474 10105 -2496 703 -5240 -3459 -1500 6430 -3846 1721 5561 -747 2210 4890 13825 -2561 9963 15637 -2632 1273 7680 -1330 -9304 3625 -6720 13240 -14441 -4411 -12383 10079 8789 -9896 9838 -7863 -16759 1467 9173 5142 -8636 4036 11209 693 -4262 6656 SO 20191022T124454.0Z 7234.531181 275 1 32.01 2 87.64 102.56 11.27 84.82 0.00 1 0.00 1 0 22 6.241e-02 6.219e-02 6.967e-02 6.891e-02 2.074159e+03 3.937978e+03 3.896691e+02 -6.000000e+00 3.247281e+03 271.96 -2.00 20.00 -2.00 505.30 0.00e+00 1.004101e-03 1.838063e-03 2.565212e-05 -6.000000e+00 1.690182e-03 271.96 -2.00 20.00 -2.00 500.31 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