File name: Pandora65s1_Altzomoni_20210823_L2Fit_fout2c5d20210115p1-8.txt File generation date: 20260113T090140.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 65 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora65_OF_v4d20201007.txt Instrument calibration file used: Pandora65s1_CF_v5d20210115.txt Level 1 file used: Pandora65s1_Altzomoni_20210823_L1_smca1c5d20210115p1-8.txt Full location name: Observatorio Atmosferico Altzomoni, UNAM Short location name: Altzomoni Country of location: Mexico Location latitude [deg]: 19.1187 Location longitude [deg]: -98.6552 Location altitude [m]: 3985 Local noon date: 20210823 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 277 418 Nominal wavelengths inside fitting window [nm]: 305.1298 305.2707 305.4115 305.5524 305.6932 305.8340 305.9748 306.1156 306.2564 306.3971 306.5379 306.6786 306.8193 306.9600 307.1007 307.2414 307.3821 307.5227 307.6634 307.8040 307.9446 308.0852 308.2258 308.3664 308.5069 308.6475 308.7880 308.9286 309.0691 309.2096 309.3501 309.4905 309.6310 309.7714 309.9119 310.0523 310.1927 310.3331 310.4735 310.6139 310.7542 310.8946 311.0349 311.1752 311.3155 311.4558 311.5961 311.7363 311.8766 312.0168 312.1570 312.2973 312.4375 312.5776 312.7178 312.8580 312.9981 313.1383 313.2784 313.4185 313.5586 313.6987 313.8387 313.9788 314.1188 314.2588 314.3989 314.5389 314.6788 314.8188 314.9588 315.0987 315.2387 315.3786 315.5185 315.6584 315.7983 315.9381 316.0780 316.2178 316.3577 316.4975 316.6373 316.7771 316.9168 317.0566 317.1963 317.3361 317.4758 317.6155 317.7552 317.8949 318.0346 318.1742 318.3138 318.4535 318.5931 318.7327 318.8723 319.0119 319.1514 319.2910 319.4305 319.5700 319.7095 319.8490 319.9885 320.1280 320.2674 320.4069 320.5463 320.6857 320.8251 320.9645 321.1039 321.2432 321.3826 321.5219 321.6613 321.8006 321.9399 322.0791 322.2184 322.3577 322.4969 322.6361 322.7754 322.9146 323.0538 323.1929 323.3321 323.4712 323.6104 323.7495 323.8886 324.0277 324.1668 324.3059 324.4449 324.5840 324.7230 324.8620 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210823T125317.3Z 7905.537006 231 1 48.02 2 82.60 80.61 85.18 256.19 0.00 1 0.00 1 0 25 5.772e-01 5.187e-03 1.285e-01 1.348e-03 8.138681e-01 7.498052e-04 7.934712e-03 -6.000000e+00 3.364136e-01 225.55 -2.00 3.11 -2.00 321.50 0.00e+00 2.444191e-03 3.096185e-04 8.768505e-04 -6.000000e+00 1.354060e-02 273.02 -2.00 20.00 -2.00 321.19 0.00e+00 7.231 0.002 302.00 328.00 3 5.5511e-01 2.3524e-03 5.9328e-02 -6.0000e+00 8.3779e-01 7.0561e-02 3.7465e-03 4.0013e-02 -6.0000e+00 9.1141e-01 -7.9522e-02 4.7284e-03 2.3811e-02 -6.0000e+00 5.3653e-01 2.5188e-02 2.2691e-03 8.3485e-03 -6.0000e+00 2.2725e-01 1.3498e-03 -1.1120e-03 3.8863e-05 1.0786e-04 -6.0000e+00 1.6615e-02 1.0887e-02 0.0000e+00 10 0 0 10 0 0 80.48 21.48 0.28 0.01089 0.00253 598 145 1 5 0 80.280 25.28 19.97 21.48 6.96 6.9 629.89 -241261 -141678 -223398 -108653 -242210 -147515 -207254 -147763 -199745 -145588 -155048 -151920 -85943 -112816 -42596 -56128 -27818 -86095 -17580 -62852 -28428 -61392 -44148 -43416 -39928 -20368 -58298 -17073 -51072 -6177 -29415 -3539 -18743 -8377 -13969 -10790 -6953 -6319 -1540 -6322 3505 -3118 3454 -3621 4935 -3971 3692 -301 1219 2726 2114 3870 2356 5217 1622 3397 591 2999 -347 1511 854 3103 3019 2704 3113 1502 355 628 2445 1307 2126 127 1591 246 454 39 -1319 142 -866 207 -1153 -1242 -1771 -1076 -1391 -570 -260 673 485 929 850 306 647 -283 204 97 623 -50 254 -83 -71 -283 -120 -841 -1002 -569 -614 -296 -210 -110 -41 88 128 149 374 238 356 -79 -193 -569 9 -292 184 209 261 422 907 235 293 429 119 -106 -67 -146 -237 -17 104 -18 -74 -40 -196 81 -1331 -335 -1262 -186 -1528 -388 -1116 -505 -1312 -612 -815 -998 -395 -904 -218 -398 -172 -1075 -120 -710 -232 -726 -487 -525 -504 -225 -950 -182 -819 -77 -580 -65 -463 -192 -330 -265 -191 -210 -61 -309 173 -161 175 -202 285 -237 236 -20 85 211 188 381 262 618 211 454 83 400 -47 200 122 494 558 558 659 326 81 155 676 416 720 44 525 76 125 10 -337 39 -285 81 -535 -654 -1013 -651 -904 -386 -181 470 333 599 512 179 382 -185 154 86 591 -53 285 -90 -72 -278 -110 -797 -1008 -599 -636 -335 -267 -159 -65 146 210 237 569 356 544 -127 -323 -958 14 -451 273 296 356 558 1206 346 493 813 249 -220 -147 -343 -594 -44 271 -48 -189 -96 -441 185 SS 20210823T131019.1Z 7905.548833 236 1 48.27 2 78.62 81.91 88.95 257.66 0.00 1 0.00 1 0 25 1.290e-01 4.175e-03 1.400e-02 4.100e-04 5.832927e-01 2.172410e-04 5.955728e-03 -6.000000e+00 7.517518e-02 225.55 -2.00 3.11 -2.00 320.34 0.00e+00 7.556025e-04 6.835170e-05 3.554747e-04 -6.000000e+00 3.025637e-03 273.02 -2.00 20.00 -2.00 320.06 0.00e+00 4.915 0.000 302.00 328.00 3 2.1468e-01 6.1376e-04 4.0756e-02 -6.0000e+00 1.8721e-01 1.8769e-02 7.6930e-04 2.6951e-02 -6.0000e+00 2.0366e-01 -9.0777e-03 8.1919e-04 1.4558e-02 -6.0000e+00 1.1989e-01 -4.4265e-03 4.2949e-04 4.6867e-03 -6.0000e+00 5.0785e-02 9.5534e-03 -7.0939e-04 1.2135e-05 5.6923e-05 -6.0000e+00 3.7126e-03 1.0509e-02 0.0000e+00 10 0 0 10 0 0 -12.60 21.47 0.25 0.01051 0.00518 1821 441 1 5 0 26.100 25.28 19.98 21.47 9.78 6.9 648.38 -53059 -42815 -45928 -43761 -52434 -47098 -45903 -35697 -37633 -31670 -30792 -27898 -19312 -14619 -8999 -10285 -7429 -7799 -3952 -5858 -4047 -5341 -4507 -5326 -4891 -2757 -6010 -5520 -5929 -3464 -3241 -343 -2024 -2794 -3820 -4071 -3201 -1964 -1595 -1297 -714 -1359 -363 -62 139 -295 620 -117 778 923 1048 1194 848 1010 690 756 408 561 272 751 747 1582 1488 992 891 547 38 347 460 291 544 2 402 58 218 -150 -414 -412 -459 -543 -823 -1417 -1323 -1048 -1006 -418 -181 505 380 772 713 697 755 711 448 498 579 47 76 -129 -359 -247 72 -740 -773 -808 -542 -396 37 -9 134 73 151 77 344 316 292 36 -307 -605 -233 -388 -24 268 376 349 1081 453 418 307 122 -185 -3 -64 -103 -124 71 -94 -113 27 -244 32 -431 -351 -398 -346 -432 -390 -420 -337 -408 -346 -359 -379 -303 -272 -193 -257 -200 -230 -120 -189 -130 -179 -163 -212 -207 -120 -268 -235 -258 -167 -183 -20 -132 -203 -272 -309 -252 -184 -182 -172 -103 -209 -57 -10 22 -49 103 -20 140 180 227 284 220 282 202 229 126 170 81 223 237 552 584 422 378 227 16 153 227 162 325 1 236 32 108 -68 -181 -189 -241 -333 -579 -1025 -1023 -859 -883 -385 -172 484 357 680 582 538 573 571 407 517 688 63 95 -169 -440 -275 76 -821 -914 -1003 -714 -517 52 -14 224 124 253 123 513 460 434 56 -506 -1019 -383 -619 -37 390 525 508 1554 649 665 535 229 -343 -7 -131 -223 -278 163 -217 -256 58 -497 62 SS 20210823T131543.0Z 7905.552581 239 1 48.33 2 77.36 82.31 90.15 258.12 0.00 1 0.00 1 0 25 7.847e-02 4.158e-03 8.261e-03 3.316e-04 5.330647e-01 1.738385e-04 5.519988e-03 -6.000000e+00 4.573872e-02 225.55 -2.00 3.11 -2.00 320.01 0.00e+00 6.381365e-04 5.023642e-05 2.845747e-04 -6.000000e+00 1.840844e-03 273.02 -2.00 20.00 -2.00 319.73 0.00e+00 4.457 0.000 302.00 328.00 3 1.9774e-01 4.8804e-04 3.7090e-02 -6.0000e+00 1.1391e-01 1.2702e-02 5.8691e-04 2.4524e-02 -6.0000e+00 1.2391e-01 -3.4738e-03 5.7554e-04 1.2940e-02 -6.0000e+00 7.2945e-02 -5.9223e-03 3.0643e-04 4.0478e-03 -6.0000e+00 3.0899e-02 1.3557e-02 -6.2810e-04 9.9007e-06 4.9676e-05 -6.0000e+00 2.2588e-03 1.0348e-02 0.0000e+00 10 0 0 10 0 0 -9.52 21.48 0.24 0.01035 0.00563 2161 523 1 5 0 21.920 25.28 19.98 21.48 10.47 6.9 652.15 -29535 -26136 -22818 -29216 -30031 -34996 -23830 -25905 -18210 -19874 -19169 -18011 -14728 -8645 -7172 -4536 -4773 -3169 -4142 -2500 -3863 -2827 -3890 -3093 -3263 -3026 -2680 -4219 -3105 -2641 -479 -348 -265 -1945 -2652 -3386 -2663 -1940 -1516 -1015 -1025 -815 -637 -71 -130 -136 -133 -71 23 222 611 950 1092 947 849 673 585 468 386 671 855 1452 1396 1067 841 677 -199 512 461 234 262 4 257 122 241 36 -150 -213 -285 -719 -725 -1491 -1268 -1155 -917 -484 -245 352 294 803 640 877 713 764 445 587 489 61 -13 -99 -380 -367 31 -784 -705 -733 -428 -404 26 3 102 7 95 95 298 298 253 158 -288 -568 -221 -280 13 249 324 345 1032 453 527 294 160 -144 64 -61 -83 -95 82 -64 -163 -1 -321 7 -317 -301 -259 -328 -322 -416 -283 -357 -260 -306 -313 -343 -336 -228 -224 -157 -182 -129 -181 -112 -177 -132 -199 -169 -190 -184 -161 -245 -180 -171 -35 -26 -22 -166 -220 -301 -270 -234 -221 -171 -188 -157 -127 -14 -26 -28 -28 -15 5 53 160 271 337 314 294 241 212 167 135 236 319 596 640 525 410 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