File name: Pandora65s1_Altzomoni_20211212_L2Fit_fout2c5d20210115p1-8.txt File generation date: 20260113T092313.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 65 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora65_OF_v4d20201007.txt Instrument calibration file used: Pandora65s1_CF_v5d20210115.txt Level 1 file used: Pandora65s1_Altzomoni_20211212_L1_smca1c5d20210115p1-8.txt Full location name: Observatorio Atmosferico Altzomoni, UNAM Short location name: Altzomoni Country of location: Mexico Location latitude [deg]: 19.1187 Location longitude [deg]: -98.6552 Location altitude [m]: 3985 Local noon date: 20211212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 277 418 Nominal wavelengths inside fitting window [nm]: 305.1298 305.2707 305.4115 305.5524 305.6932 305.8340 305.9748 306.1156 306.2564 306.3971 306.5379 306.6786 306.8193 306.9600 307.1007 307.2414 307.3821 307.5227 307.6634 307.8040 307.9446 308.0852 308.2258 308.3664 308.5069 308.6475 308.7880 308.9286 309.0691 309.2096 309.3501 309.4905 309.6310 309.7714 309.9119 310.0523 310.1927 310.3331 310.4735 310.6139 310.7542 310.8946 311.0349 311.1752 311.3155 311.4558 311.5961 311.7363 311.8766 312.0168 312.1570 312.2973 312.4375 312.5776 312.7178 312.8580 312.9981 313.1383 313.2784 313.4185 313.5586 313.6987 313.8387 313.9788 314.1188 314.2588 314.3989 314.5389 314.6788 314.8188 314.9588 315.0987 315.2387 315.3786 315.5185 315.6584 315.7983 315.9381 316.0780 316.2178 316.3577 316.4975 316.6373 316.7771 316.9168 317.0566 317.1963 317.3361 317.4758 317.6155 317.7552 317.8949 318.0346 318.1742 318.3138 318.4535 318.5931 318.7327 318.8723 319.0119 319.1514 319.2910 319.4305 319.5700 319.7095 319.8490 319.9885 320.1280 320.2674 320.4069 320.5463 320.6857 320.8251 320.9645 321.1039 321.2432 321.3826 321.5219 321.6613 321.8006 321.9399 322.0791 322.2184 322.3577 322.4969 322.6361 322.7754 322.9146 323.0538 323.1929 323.3321 323.4712 323.6104 323.7495 323.8886 324.0277 324.1668 324.3059 324.4449 324.5840 324.7230 324.8620 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211212T131104.5Z 8016.549358 69 1 43.24 2 88.17 115.26 160.05 334.55 0.00 1 0.00 1 0 85 2.239e+00 4.633e-01 6.507e-01 1.440e-01 9.852138e-01 9.769201e-02 5.685014e-03 -6.000000e+00 1.361640e+00 222.98 -2.00 3.11 -2.00 315.40 0.00e+00 5.930567e-02 1.096457e-02 3.148589e-04 -6.000000e+00 6.045221e-02 270.74 -2.00 20.00 -2.00 315.53 0.00e+00 17.021 0.021 302.00 328.00 3 -2.3310e+00 2.3168e-01 1.1049e-01 -6.0000e+00 3.3650e+00 5.9043e+00 2.7108e-01 3.1355e-02 -6.0000e+00 3.6817e+00 -8.1885e-01 1.4590e-01 1.4758e-02 -6.0000e+00 2.1734e+00 -1.2132e+00 6.9626e-02 4.9892e-03 -6.0000e+00 9.3581e-01 2.4280e-06 1.3976e-02 4.4104e-03 2.0581e-05 -6.0000e+00 6.7828e-02 1.6266e-02 0.0000e+00 12 9 9 12 9 1 3.05 21.60 2.55 0.01627 0.12129 10 3 1 5 0 3914.280 25.47 19.99 21.60 5.29 8.4 634.51 -16159 900000 25930 900000 900000 -48144 -52516 -113960 -37742 -192553 37270 900000 900000 346969 320621 425084 900000 382124 229945 514308 256332 900000 186340 287604 86146 231290 95582 900000 900000 272513 900000 2951 900000 226658 900000 234455 337905 385191 289071 302201 900000 239644 393861 900000 302442 900000 606933 375768 900000 399591 376747 510381 326778 356354 330894 264367 900000 247397 900000 212167 350946 301899 900000 -32738 321446 337879 395939 285337 287526 534943 203370 900000 266988 157349 112295 266687 128498 272008 180979 419890 198774 183935 192977 176766 277214 113359 186823 157048 163376 176969 139925 119522 132649 154407 102362 153015 84813 102693 68054 78509 31085 56273 30716 53345 24058 32850 65902 37817 27358 28903 30744 -3312 -2888 -15762 -482 -8323 -4644 -17905 -19400 -26462 -12913 -8718 -25012 -17632 -41645 -27700 2289 16740 -6339 -5860 -9500 -15624 -12891 -14129 4818 -6288 1315 -3008 12933 8509 17584 34384 -2916 900000 3626 900000 900000 -8688 -8055 -28276 -5278 -109454 5212 900000 900000 48524 44840 59449 900000 53441 39662 71927 35849 900000 26060 40222 25300 32346 28963 900000 900000 39382 900000 9000 900000 66567 900000 61056 47257 53870 44610 42264 900000 65874 55082 900000 53966 900000 84881 52552 900000 55884 52689 71378 56732 49837 46276 58646 900000 52495 900000 66506 49081 49761 900000 -150783 44955 47253 55373 52732 53136 74813 76183 900000 37339 53442 50479 37297 48778 38041 54237 58723 56591 59716 54941 57389 38769 63981 47590 49418 42433 35749 34945 34625 35115 37019 47548 48913 58883 60012 51666 46271 24221 28669 18870 25845 15501 19853 31404 25122 22410 25264 27026 -3987 -3274 -19052 -481 -9063 -5010 -22447 -24128 -33043 -13093 -8309 -25736 -16896 -48258 -29700 2063 15607 -8422 -8868 -16607 -31760 -27880 -33732 10132 -15485 3140 -7618 27325 18276 33989 60198 SS 20211212T132739.4Z 8016.560872 76 1 46.51 2 84.65 116.73 161.27 345.98 0.00 1 0.00 1 0 25 8.667e-01 9.423e-03 2.096e-01 3.112e-03 8.566708e-01 1.749193e-03 8.201449e-03 -6.000000e+00 5.000758e-01 222.98 -2.00 3.11 -2.00 321.99 0.00e+00 1.283316e-02 7.938771e-04 1.107198e-03 -6.000000e+00 2.033597e-02 270.74 -2.00 20.00 -2.00 321.68 0.00e+00 9.444 0.004 302.00 328.00 3 5.3701e-01 5.7639e-03 7.1095e-02 -6.0000e+00 1.2383e+00 1.2005e-01 1.0282e-02 4.2506e-02 -6.0000e+00 1.3497e+00 -2.7992e-01 1.3048e-02 2.6199e-02 -6.0000e+00 7.9604e-01 1.3409e-01 6.0320e-03 9.5417e-03 -6.0000e+00 3.3881e-01 3.8297e-04 -1.6236e-03 9.1804e-05 1.2143e-04 -6.0000e+00 2.4936e-02 1.4708e-02 0.0000e+00 12 8 8 10 0 0 -15.73 21.60 0.27 0.01471 0.00251 331 80 1 5 0 140.490 25.39 20.00 21.60 6.15 8.4 638.73 -320959 -325408 -195875 -305203 -256509 -306079 -260877 -297823 -229868 -262317 -198221 -234286 -165532 -121583 -92741 -76857 -101612 -81958 -99066 -80157 -50536 -40442 -48704 -67065 -63522 -87772 -80787 -88880 -69759 -57193 -46126 -31131 4098 -8365 -15254 -29964 -15429 -5910 -406 -3372 -2514 1496 -2493 -3760 5144 12650 10806 10591 2140 4727 7297 9709 11124 7757 10776 6447 8118 6739 5639 -601 5111 4577 4231 13050 4418 5615 3359 3076 2903 4479 4101 4508 3213 3669 2229 1026 -77 212 -701 -285 -1392 -1337 -934 -764 -772 -28 728 1401 861 1852 2106 1313 743 236 6 -88 -672 -758 -396 93 -210 -235 -33 -1028 -788 -1320 -607 -1174 -958 -1037 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3.11 -2.00 321.26 0.00e+00 8.332204e-03 2.382306e-04 6.690159e-04 -6.000000e+00 9.031777e-03 270.74 -2.00 20.00 -2.00 320.96 0.00e+00 7.105 0.002 302.00 328.00 3 4.5745e-01 1.8262e-03 5.4522e-02 -6.0000e+00 5.5002e-01 -2.5054e-02 2.6964e-03 3.3102e-02 -6.0000e+00 5.9949e-01 -4.3608e-02 3.3187e-03 1.9173e-02 -6.0000e+00 3.5358e-01 2.7156e-02 1.6306e-03 6.6358e-03 -6.0000e+00 1.5050e-01 1.9234e-03 -1.0346e-03 3.2883e-05 8.7007e-05 -6.0000e+00 1.1075e-02 1.4143e-02 0.0000e+00 10 0 0 10 0 0 -7.10 21.60 0.24 0.01414 0.00637 725 176 1 5 0 61.360 25.39 20.04 21.60 6.60 8.4 641.01 -141982 -127626 -105961 -146812 -99131 -170787 -93720 -151675 -71073 -124391 -80325 -111038 -73522 -60526 -53405 -21151 -35275 -12549 -30981 -5984 -32927 -20933 -23438 -10274 -24276 -19257 -25523 -29242 -16184 -22991 -4760 -14649 -2578 -670 -3481 -8031 -5418 -2939 232 1890 2467 1923 -209 4093 -1860 1643 -2848 780 -109 867 71 1224 2029 1390 3813 1474 3973 1539 3291 1103 1330 189 597 2130 -130 93 1060 438 -159 594 262 627 470 1458 1015 827 -128 -754 -1123 -1790 -1285 -2222 -1424 -1525 -804 -568 301 720 707 1253 921 946 788 970 439 580 407 42 -109 13 -53 227 681 -253 -76 -623 -345 -778 -355 -506 -154 -58 222 213 432 103 -46 -224 -678 -713 -423 -407 -84 324 391 637 1083 497 558 344 215 -74 182 -84 41 -2 168 -118 -63 -10 -381 -159 -683 -614 -431 -848 -339 -1242 -341 -1087 -251 -798 -369 -891 -550 -531 -560 -192 -422 -134 -431 -68 -493 -284 -348 -142 -405 -321 -459 -544 -286 -526 -112 -454 -81 -21 -109 -280 -211 -133 11 105 150 126 -15 288 -144 128 -244 68 -10 90 8 159 287 214 598 244 648 252 522 183 238 39 141 543 -35 24 284 126 -52 218 103 250 181 513 324 243 -37 -240 -422 -803 -665 -1306 -892 -1017 -571 -424 231 559 541 899 617 606 506 674 353 497 407 47 -128 14 -55 213 656 -234 -74 -648 -383 -946 -477 -762 -251 -98 369 339 652 153 -71 -360 -1147 -1220 -702 -651 -128 475 550 870 1481 746 946 650 410 -151 390 -191 98 -5 426 -304 -158 -23 -852 -337 SS 20211212T135543.5Z 8016.580364 84 1 41.12 2 78.80 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