File name: Pandora285s1_AmesIA_20250925_L2Fit_fout2c2d20250320p1-8.txt File generation date: 20250926T061101.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Thanos Papanicolaou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 285 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora285_OF_v3d20240703.txt Instrument calibration file used: Pandora285s1_CF_v2d20250320.txt Level 1 file used: Pandora285s1_AmesIA_20250925_L1_smca1c2d20250320p1-8.txt Full location name: AmesIA USDA monitoring site Short location name: AmesIA Country of location: United States Location latitude [deg]: 42.0450 Location longitude [deg]: -93.7152 Location altitude [m]: 390 Local noon date: 20250925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 194 336 Nominal wavelengths inside fitting window [nm]: 305.0768 305.2175 305.3583 305.4990 305.6397 305.7804 305.9211 306.0618 306.2024 306.3431 306.4837 306.6244 306.7650 306.9056 307.0462 307.1868 307.3274 307.4680 307.6085 307.7491 307.8896 308.0301 308.1706 308.3111 308.4516 308.5921 308.7326 308.8730 309.0135 309.1539 309.2943 309.4347 309.5751 309.7155 309.8559 309.9963 310.1366 310.2770 310.4173 310.5576 310.6979 310.8382 310.9785 311.1188 311.2591 311.3993 311.5396 311.6798 311.8200 311.9602 312.1004 312.2406 312.3808 312.5210 312.6611 312.8013 312.9414 313.0815 313.2216 313.3617 313.5018 313.6419 313.7820 313.9220 314.0621 314.2021 314.3421 314.4821 314.6221 314.7621 314.9021 315.0420 315.1820 315.3219 315.4619 315.6018 315.7417 315.8816 316.0215 316.1613 316.3012 316.4411 316.5809 316.7207 316.8605 317.0003 317.1401 317.2799 317.4197 317.5595 317.6992 317.8389 317.9787 318.1184 318.2581 318.3978 318.5375 318.6771 318.8168 318.9564 319.0961 319.2357 319.3753 319.5149 319.6545 319.7941 319.9336 320.0732 320.2127 320.3523 320.4918 320.6313 320.7708 320.9103 321.0498 321.1892 321.3287 321.4681 321.6076 321.7470 321.8864 322.0258 322.1652 322.3045 322.4439 322.5832 322.7226 322.8619 323.0012 323.1405 323.2798 323.4191 323.5584 323.6976 323.8369 323.9761 324.1153 324.2545 324.3937 324.5329 324.6721 324.8113 324.9504 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250925T123839.9Z 9399.526851 51 1 54.81 2 84.76 96.21 125.60 86.28 0.00 1 0.00 1 0 25 8.188e-01 6.347e-02 2.844e-01 1.477e-02 9.209022e-01 8.330288e-03 1.157320e-02 -6.000000e+00 4.780914e-01 227.85 -2.00 3.52 -2.00 321.94 0.00e+00 2.131065e-02 3.673754e-03 2.703608e-03 -6.000000e+00 2.312168e-02 283.79 -2.00 20.00 -2.00 321.40 0.00e+00 9.478 0.016 302.00 328.00 3 2.6714e-01 2.9082e-02 1.0328e-01 -6.0000e+00 1.1854e+00 2.1187e+00 3.2862e-02 5.5342e-02 -6.0000e+00 1.2902e+00 -2.0838e+00 1.8856e-02 2.3091e-02 -6.0000e+00 7.6238e-01 6.9499e-01 1.0860e-02 1.7272e-02 -6.0000e+00 3.2070e-01 1.3401e-05 -2.3638e-03 3.8700e-04 2.9976e-04 -6.0000e+00 2.3191e-02 1.4243e-02 0.0000e+00 12 9 8 11 40 0 50.45 24.58 0.92 0.01424 -0.00352 33 3 1 5 0 1660.840 33.75 19.95 24.58 17.47 0.0 993.07 151985 51669 266680 -44325 900000 37580 900000 -5415 -38113 159262 250329 900000 44973 39897 24633 -1972 893 360683 48653 22286 -25038 900000 98418 141944 900000 -2932 122924 900000 -67565 13641 351190 -43526 86963 170074 52003 -23197 31445 100639 17698 291526 18215 900000 -24179 132143 23548 98428 26094 96981 -5695 -42190 18240 -10298 15010 63707 900000 4929 33502 39410 31893 55164 188304 26965 51678 121941 198267 72931 9113 15761 29327 81561 2747 -25456 37788 23062 53883 -250 195930 -553 17323 694 50580 38271 17496 67466 49081 -4540 -4039 -10553 15929 -11881 -12446 -16564 -32399 31682 10638 -3469 -12038 -3195 -912 3910 2983 -3004 -15495 34263 11837 -10863 2334 -12582 -7111 7020 809 10675 7477 -7904 -2988 -8779 -1749 -1906 864 -2407 3418 5671 3775 5575 -1774 8030 8005 -1572 1434 -4230 -873 -1831 1724 2841 -338 627 -1857 607 3131 583 -2209 -857 -2990 4554 4459 3836 -8022 900000 2113 900000 -361 -3189 2291 3600 900000 1999 2452 2190 -263 124 5188 4262 2389 -3863 900000 3474 2969 900000 -219 2411 900000 -8216 838 5051 -7000 4207 3558 3128 -2699 2138 3684 1643 4193 1905 900000 -3952 4492 2340 4633 2559 5300 -819 -9212 2361 -1912 2504 6780 900000 922 4529 4705 3807 4998 4604 3646 6243 8243 6559 8287 1953 3264 5779 10675 841 -10361 7718 4909 7362 -51 5354 -114 3488 201 10476 10238 6266 15331 14048 -2318 -2114 -5965 6804 -6374 -6211 -8100 -18313 10116 4881 -2195 -9886 -2808 -861 3520 2522 -2385 -12414 16410 7525 -9140 1833 -12559 -7599 7552 962 13726 9258 -11264 -3915 -11903 -2257 -2597 1210 -3565 5102 7847 5104 7169 -2378 9517 9384 -2193 2280 -7549 -1703 -3950 3858 6773 -895 1729 -5352 1729 8626 1565 -5655 -2012 -6900 SS 20250925T125029.2Z 9399.535061 54 1 54.49 2 82.58 98.23 123.52 88.30 0.00 1 0.00 1 0 17 5.428e-01 1.941e-02 1.325e-01 2.836e-03 7.827338e-01 1.533148e-03 9.947834e-03 -6.000000e+00 3.107853e-01 227.85 -2.00 3.52 -2.00 321.41 0.00e+00 9.947877e-03 7.958660e-04 7.524521e-03 -6.000000e+00 1.420560e-02 283.79 -2.00 20.00 -2.00 320.86 0.00e+00 7.167 0.007 302.00 328.00 3 6.8260e-01 5.4155e-03 8.5716e-02 -6.0000e+00 7.7192e-01 4.6360e-01 7.2673e-03 5.4812e-02 -6.0000e+00 8.3863e-01 -6.0380e-01 6.9391e-03 2.8907e-02 -6.0000e+00 4.9978e-01 2.3603e-01 3.2758e-03 9.6351e-03 -6.0000e+00 2.1195e-01 1.3521e-04 -5.3875e-04 7.4351e-05 2.3043e-04 -6.0000e+00 1.4876e-02 1.2327e-02 0.0000e+00 12 8 8 10 0 0 -4.78 24.75 0.32 0.01233 0.00828 136 14 1 5 0 400.580 33.75 20.15 24.75 18.20 0.0 996.75 -130851 -176234 -106458 -238811 -142558 -173452 309 -168808 -229107 -173489 -92204 900000 -89185 -143919 -108225 -78861 -94145 -26484 -55874 -82280 -83970 122894 1758 40688 29559 -10753 -26843 9367 -73483 -4877 -11079 -49677 1830 18319 -27913 -35056 -9542 7083 -290 23571 13387 37912 264 36250 5771 10119 5368 23213 7457 -2246 31049 10078 15818 19322 27990 8606 7508 14088 11063 11514 17865 10940 12823 10993 17286 12447 4905 3871 6652 9410 6323 2519 4855 3914 4038 -1503 -2390 -4711 769 -2688 1712 -5541 -529 801 1905 -1701 521 195 2089 -1457 -2340 -2975 -5605 -1220 -2350 -2839 -2179 -203 -736 -282 -783 -2409 -3842 714 -1600 -2764 -1243 -2274 -811 1022 696 1140 838 -642 -670 -1432 -308 81 927 719 1334 2074 1582 1509 357 729 668 753 849 487 -88 154 628 31 -186 -681 -64 303 389 8 -428 -723 -1310 -1217 -2969 -937 -7385 -1505 -2398 1 -2462 -6509 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-2.00 319.92 0.00e+00 5.820 0.004 302.00 328.00 3 6.5831e-01 1.9994e-03 6.6665e-02 -6.0000e+00 6.2989e-01 1.1214e-01 2.5473e-03 3.8365e-02 -6.0000e+00 6.8415e-01 -1.8227e-01 2.3767e-03 1.9972e-02 -6.0000e+00 4.0776e-01 7.2617e-02 1.1839e-03 6.1715e-03 -6.0000e+00 1.7270e-01 5.5908e-04 -2.6495e-04 3.3003e-05 9.3811e-05 -6.0000e+00 1.2134e-02 8.9914e-03 0.0000e+00 12 9 8 11 8 0 26.54 24.99 0.24 0.00899 0.00700 296 30 1 5 0 184.200 34.00 20.35 24.99 19.38 0.0 1001.85 -119781 -146323 -124252 -187525 -167558 -157050 -130524 -119741 -148416 -120523 -90608 -88764 -99219 -88491 -68899 -62900 -60909 -37491 -38615 -42699 -41930 -19941 -26143 -19360 -12205 -27560 -19161 -21349 -36262 -23563 -6544 -20840 -11230 -306 -17656 -17410 -6719 -5110 -1576 4092 369 8374 -1783 4737 3279 4802 2069 2973 891 1527 6659 2623 4926 4716 7653 3805 3351 4025 2080 2221 5112 3881 6272 5628 5749 3646 1069 812 2564 2802 1907 565 1683 948 194 -1839 -2927 -3241 -1550 -1724 -939 -2538 -1787 -1571 -494 -712 23 180 995 56 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