File name: Pandora296s1_Aosta-SC_20260106_L2Fit_fout2c2d20250723p1-8.txt File generation date: 20260106T234244.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: ---- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 296 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora296_OF_v2d20250723.txt Instrument calibration file used: Pandora296s1_CF_v2d20250723.txt Level 1 file used: Pandora296s1_Aosta-SC_20260106_L1_smca1c2d20250723p1-8.txt Full location name: Aosta-Saint-Christophe Short location name: Aosta-SC Country of location: Italy Location latitude [deg]: 45.7422 Location longitude [deg]: 7.3570 Location altitude [m]: 560 Local noon date: 20260106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1, using updated OF after UV lens was changed First and last pixel inside fitting window: 193 335 Nominal wavelengths inside fitting window [nm]: 305.0569 305.1975 305.3381 305.4786 305.6192 305.7597 305.9002 306.0408 306.1813 306.3217 306.4622 306.6027 306.7431 306.8836 307.0240 307.1644 307.3049 307.4453 307.5856 307.7260 307.8664 308.0067 308.1471 308.2874 308.4277 308.5680 308.7083 308.8486 308.9889 309.1292 309.2694 309.4097 309.5499 309.6901 309.8303 309.9705 310.1107 310.2509 310.3910 310.5312 310.6713 310.8114 310.9516 311.0917 311.2318 311.3718 311.5119 311.6520 311.7920 311.9321 312.0721 312.2121 312.3521 312.4921 312.6321 312.7720 312.9120 313.0520 313.1919 313.3318 313.4717 313.6116 313.7515 313.8914 314.0313 314.1711 314.3110 314.4508 314.5906 314.7304 314.8702 315.0100 315.1498 315.2895 315.4293 315.5690 315.7088 315.8485 315.9882 316.1279 316.2676 316.4073 316.5469 316.6866 316.8262 316.9658 317.1054 317.2451 317.3846 317.5242 317.6638 317.8034 317.9429 318.0824 318.2220 318.3615 318.5010 318.6405 318.7799 318.9194 319.0589 319.1983 319.3377 319.4772 319.6166 319.7560 319.8954 320.0347 320.1741 320.3134 320.4528 320.5921 320.7314 320.8707 321.0100 321.1493 321.2886 321.4278 321.5671 321.7063 321.8456 321.9848 322.1240 322.2632 322.4023 322.5415 322.6807 322.8198 322.9589 323.0981 323.2372 323.3763 323.5154 323.6544 323.7935 323.9325 324.0716 324.2106 324.3496 324.4886 324.6276 324.7666 324.9056 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260106T104403.0Z 9502.447257 326 1 13.28 2 69.24 167.06 103.62 305.65 0.00 1 0.00 1 0 25 5.621e-02 6.579e-03 4.023e-03 6.001e-04 4.868245e-01 2.987969e-04 6.012477e-03 -6.000000e+00 3.152593e-02 222.57 -2.00 3.61 -2.00 318.21 0.00e+00 1.139399e-03 5.424944e-05 2.285966e-04 -6.000000e+00 1.331091e-03 268.56 -2.00 20.00 -2.00 317.77 0.00e+00 2.794 0.000 302.00 328.00 3 9.7591e-01 7.9204e-04 3.6228e-02 -6.0000e+00 7.7839e-02 9.2801e-03 8.9567e-04 2.5069e-02 -6.0000e+00 8.4692e-02 -2.2775e-02 6.2359e-04 1.2777e-02 -6.0000e+00 5.0220e-02 9.4197e-03 3.3607e-04 3.9503e-03 -6.0000e+00 2.1699e-02 7.8943e-03 -4.1006e-04 1.5873e-05 4.0579e-05 -6.0000e+00 1.4803e-03 -5.1054e-02 0.0000e+00 12 9 1 12 5 1 35.99 22.90 0.26 -0.05105 -0.05414 203 82 2 8 0 65.060 19.89 22.90 -0.53 33.75 32.50 2.3 887.30 -15954 -20513 -17384 -14256 -20442 -23275 -22395 -19757 -15128 -16345 -15310 -13644 -11446 -9254 -3693 -3692 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903 591 -192 -295 -1002 -659 -173 -720 -1437 -1231 -1092 -642 283 641 779 540 636 260 189 396 434 453 295 -128 108 623 788 853 768 226 1141 1149 667 474 -42 -146 -345 -284 -372 -452 347 12 -380 -321 -734 -1060 SS 20260106T105633.8Z 9502.455946 331 1 54.54 2 68.80 170.12 105.34 308.09 0.00 1 0.00 1 0 25 5.157e-02 6.458e-03 1.095e-03 1.766e-04 4.799152e-01 8.799613e-05 5.946392e-03 -6.000000e+00 2.892477e-02 222.57 -2.00 3.61 -2.00 318.11 0.00e+00 9.890897e-04 1.548467e-05 1.834186e-04 -6.000000e+00 1.221333e-03 268.56 -2.00 20.00 -2.00 317.68 0.00e+00 2.741 0.000 302.00 328.00 3 1.5318e-02 2.3257e-04 3.5633e-02 -6.0000e+00 7.1416e-02 4.0722e-03 2.6259e-04 2.4731e-02 -6.0000e+00 7.7706e-02 -1.9939e-02 1.8030e-04 1.2603e-02 -6.0000e+00 4.6077e-02 8.5433e-03 9.6921e-05 3.8680e-03 -6.0000e+00 1.9908e-02 2.1872e-02 -3.8750e-04 4.6689e-06 3.9530e-05 -6.0000e+00 1.3582e-03 -5.0616e-02 0.0000e+00 11 9 0 11 4 0 31.50 22.90 0.26 -0.05062 -0.05353 2548 249 2 8 0 21.400 19.88 22.90 1.34 33.50 32.50 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375 -55 106 -31 -75 -263 -631 -496 -600 -958 -959 -1794 -2042 -1632 -1267 -654 -373 143 294 311 567 163 329 341 152 316 832 470 -257 -359 -892 -792 -167 -686 -1511 -1215 -1122 -612 281 486 546 489 561 279 328 559 535 465 126 -226 -64 475 663 769 915 381 1261 1205 610 553 -5 -1 -220 -185 -309 -485 303 -29 -476 -442 -763 -986 SS 20260106T110300.3Z 9502.460420 334 1 54.57 2 68.63 171.71 106.21 309.37 0.00 1 0.00 1 0 17 7.067e-02 1.137e-02 1.370e-02 1.039e-03 4.870848e-01 5.184997e-04 6.102130e-03 -6.000000e+00 3.961435e-02 222.57 -2.00 3.61 -2.00 318.88 0.00e+00 1.837681e-03 1.160747e-04 1.155301e-03 -6.000000e+00 1.673958e-03 268.56 -2.00 20.00 -2.00 318.47 0.00e+00 2.719 0.000 302.00 328.00 3 3.3231e+00 1.4007e-03 3.6080e-02 -6.0000e+00 9.7803e-02 2.9968e-02 1.6098e-03 2.5677e-02 -6.0000e+00 1.0645e-01 -2.2373e-02 1.2794e-03 1.3536e-02 -6.0000e+00 6.3121e-02 3.5851e-03 6.9829e-04 4.4099e-03 -6.0000e+00 2.7245e-02 7.9516e-04 -1.0095e-03 2.7995e-05 4.5868e-05 -6.0000e+00 1.8618e-03 -4.4740e-02 0.0000e+00 12 9 8 11 4 0 99.97 22.91 0.40 -0.04474 -0.05233 292 29 4 8 0 186.850 20.03 22.91 2.93 33.50 32.50 2.2 904.53 16659 -44913 -22301 14578 -10354 -29290 -12829 -22989 -8399 -19157 -22908 -7416 -6715 -22943 -3268 -7370 545 26 -1165 -456 6608 -2819 -2823 -4392 1869 2168 -3502 -4936 2018 -5720 -3301 -318 1527 -1428 -4345 -7617 -4618 -2140 -983 -2013 -790 -373 1427 -247 -110 -111 884 153 296 -292 1204 2175 1033 2137 1994 1287 1446 1114 549 -932 878 1388 3254 3001 1767 799 -483 -1014 -678 893 1098 2063 914 1198 139 -574 -2499 -3871 -4291 -3556 -1927 -987 -1412 -1594 -608 -7 725 1170 1206 622 -385 -1271 -2853 -3372 -2440 -1123 323 1412 1084 608 259 -610 -1102 -1020 -836 -1165 -519 -174 491 1341 1865 2387 1795 1414 249 -607 -939 -653 30 -93 -22 164 498 763 191 30 -704 -328 -200 -31 -24 -524 -836 -943 -1022 -700 -289 477 678 624 433 224 -294 238 -1415 -612 278 -231 -736 -283 -629 -226 -633 -814 -236 -248 -1234 -177 -497 38 2 -97 -40 557 -261 -264 -447 193 237 -419 -586 213 -649 -403 -44 235 -250 -775 -1327 -815 -422 -211 -529 -236 -120 474 -86 -39 -39 314 55 108 -110 477 863 452 996 990 666 771 603 292 -491 456 760 1941 1850 1187 534 -309 -638 -441 645 832 1658 756 957 105 -425 -1694 -2511 -2873 -2681 -1545 -893 -1330 -1598 -636 -7 798 1337 1398 713 -420 -1290 -2910 -3310 -2472 -1178 381 1756 1424 836 344 -794 -1299 -1216 -988 -1487 -688 -229 682 1898 2881 3731 2865 2191 386 -882 -1392 -984 44 -149 -34 266 775 1145 291 44 -988 -445 -287 -46 -40 -881 -1463 -1631 -1868 -1297 -554 922 1327 1208 802 413 -516 SS 20260106T113010.4Z 9502.479287 344 1 54.53 2 68.22 178.44 109.68 314.96 0.00 1 0.00 1 0 25 4.652e-02 6.453e-03 9.745e-04 1.685e-04 4.723889e-01 8.378624e-05 5.868769e-03 -6.000000e+00 2.608885e-02 222.57 -2.00 3.61 -2.00 318.04 0.00e+00 9.592799e-04 1.438692e-05 1.747633e-04 -6.000000e+00 1.101597e-03 268.56 -2.00 20.00 -2.00 317.60 0.00e+00 2.672 0.000 302.00 328.00 3 -1.1537e-02 2.2138e-04 3.4919e-02 -6.0000e+00 6.4414e-02 3.0870e-03 2.4994e-04 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