File name: Pandora296s1_Aosta-SC_20260510_L2Fit_fout2c4d20251001p1-8.txt File generation date: 20260510T233501.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: ---- Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 296 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora296_OF_v2d20250723.txt Instrument calibration file used: Pandora296s1_CF_v4d20251001.txt Level 1 file used: Pandora296s1_Aosta-SC_20260510_L1_smca1c4d20251001p1-8.txt Full location name: Aosta-Saint-Christophe Short location name: Aosta-SC Country of location: Italy Location latitude [deg]: 45.7422 Location longitude [deg]: 7.3570 Location altitude [m]: 560 Local noon date: 20260510 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 193 336 Nominal wavelengths inside fitting window [nm]: 305.0081 305.1486 305.2892 305.4297 305.5702 305.7107 305.8512 305.9917 306.1322 306.2727 306.4131 306.5536 306.6940 306.8344 306.9749 307.1153 307.2556 307.3960 307.5364 307.6768 307.8171 307.9574 308.0978 308.2381 308.3784 308.5187 308.6589 308.7992 308.9395 309.0797 309.2199 309.3602 309.5004 309.6406 309.7808 309.9210 310.0611 310.2013 310.3414 310.4816 310.6217 310.7618 310.9019 311.0420 311.1821 311.3221 311.4622 311.6022 311.7422 311.8823 312.0223 312.1623 312.3023 312.4422 312.5822 312.7222 312.8621 313.0020 313.1420 313.2819 313.4218 313.5617 313.7015 313.8414 313.9812 314.1211 314.2609 314.4007 314.5405 314.6803 314.8201 314.9599 315.0997 315.2394 315.3791 315.5189 315.6586 315.7983 315.9380 316.0777 316.2173 316.3570 316.4967 316.6363 316.7759 316.9155 317.0551 317.1947 317.3343 317.4739 317.6134 317.7530 317.8925 318.0320 318.1716 318.3111 318.4505 318.5900 318.7295 318.8689 319.0084 319.1478 319.2872 319.4267 319.5661 319.7054 319.8448 319.9842 320.1235 320.2629 320.4022 320.5415 320.6808 320.8201 320.9594 321.0987 321.2380 321.3772 321.5164 321.6557 321.7949 321.9341 322.0733 322.2125 322.3516 322.4908 322.6299 322.7691 322.9082 323.0473 323.1864 323.3255 323.4646 323.6036 323.7427 323.8817 324.0208 324.1598 324.2988 324.4378 324.5768 324.7158 324.8547 324.9937 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-388: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260510T081808.8Z 9626.345935 221 1 53.96 2 48.02 109.80 67.46 214.45 0.00 1 0.00 1 0 17 1.897e-02 7.870e-03 4.327e-03 1.644e-03 2.536344e-01 8.231756e-04 3.079081e-03 -6.000000e+00 1.076039e-02 230.13 -2.00 3.61 -2.00 316.84 0.00e+00 5.877617e-04 1.041528e-04 9.032618e-05 -6.000000e+00 4.620483e-04 276.95 -2.00 20.00 -2.00 316.21 0.00e+00 1.492 0.000 302.00 328.00 3 5.5630e+00 2.1690e-03 1.9544e-02 -6.0000e+00 2.6940e-02 2.0847e-02 2.4326e-03 1.3359e-02 -6.0000e+00 2.9288e-02 4.3660e-04 1.4300e-03 6.5436e-03 -6.0000e+00 1.7364e-02 -6.2043e-03 6.8034e-04 1.8482e-03 -6.0000e+00 7.2316e-03 3.5982e-04 4.3675e-05 4.5959e-05 1.9354e-05 -6.0000e+00 4.9958e-04 -5.6392e-03 0.0000e+00 11 9 0 11 8 0 97.34 24.26 0.49 -0.00564 -0.00531 19 2 1 8 0 2839.010 19.99 24.26 19.61 34.50 33.25 1.5 963.25 2994 -6915 -5468 3974 -1547 -7405 531 -2436 709 -104 -8147 2700 1659 -2061 4148 -2428 -333 538 1520 -170 6089 226 -2448 -3991 4508 2493 392 593 4012 -3138 1251 1173 3298 193 -1279 -3489 -2043 127 1059 -1991 -930 -1362 193 -2142 -855 -1458 -1267 -746 -858 642 2545 1659 876 1612 -25 94 398 1348 730 -550 1795 546 1413 1179 984 -488 -372 -886 -554 1032 221 1605 305 1332 -51 706 -235 -909 -676 -647 -1230 -188 -2160 -1984 -831 -629 -448 448 56 146 33 668 -705 -467 51 185 -352 854 118 187 -70 -439 -534 31 -432 -1023 -888 -1033 -116 -109 348 587 72 170 54 -302 -257 114 1015 485 54 124 389 830 548 -122 197 1518 431 280 307 -431 -200 -99 305 -864 139 231 -61 -5 -83 -248 -537 -330 376 -1083 -886 571 -209 -969 65 -339 108 -17 -1474 432 290 -429 930 -653 -93 154 408 -48 1835 65 -726 -1254 1375 811 133 193 1284 -1025 401 405 1097 71 -461 -1199 -715 49 485 -1124 -538 -839 121 -1403 -552 -946 -813 -463 -520 377 1505 1059 600 1155 -19 73 313 1061 569 -426 1368 443 1137 1029 895 -430 -298 -728 -456 854 208 1592 314 1330 -49 616 -200 -712 -518 -539 -1079 -182 -2326 -2081 -907 -737 -559 541 69 178 41 752 -730 -479 52 204 -402 1071 153 250 -90 -562 -629 36 -526 -1265 -1147 -1399 -162 -161 511 897 110 246 76 -394 -343 143 1337 693 82 178 580 1197 754 -160 263 1907 562 367 430 -634 -299 -150 453 -1383 230 390 -99 -8 -139 -399 -835 -506 SS 20260510T082846.2Z 9626.353313 223 1 55.03 2 46.28 112.32 68.48 216.93 0.00 1 0.00 1 0 17 9.576e-03 6.140e-03 1.415e-03 7.364e-04 2.431928e-01 3.715166e-04 2.984730e-03 -6.000000e+00 5.432392e-03 230.13 -2.00 3.61 -2.00 315.97 0.00e+00 3.213835e-04 3.788647e-05 4.449682e-05 -6.000000e+00 2.332905e-04 276.95 -2.00 20.00 -2.00 315.37 0.00e+00 1.445 0.000 302.00 328.00 3 4.3079e+00 9.6740e-04 1.8829e-02 -6.0000e+00 1.3600e-02 1.1479e-02 1.0808e-03 1.2804e-02 -6.0000e+00 1.4787e-02 -1.9378e-03 6.2081e-04 6.2695e-03 -6.0000e+00 8.7664e-03 -3.2977e-03 2.8164e-04 1.7406e-03 -6.0000e+00 3.6503e-03 1.3518e-03 -1.3523e-04 2.0325e-05 2.0108e-05 -6.0000e+00 2.5225e-04 -4.4858e-03 0.0000e+00 10 0 0 10 0 0 93.28 24.26 0.29 -0.00449 -0.00550 64 6 1 8 0 859.590 20.00 24.26 20.31 34.50 33.25 1.5 965.74 625 -2173 -1526 -910 -2914 -3987 -1030 -683 961 -658 -3294 -661 -687 -616 1241 -689 -356 529 443 849 2220 454 463 -307 1781 1056 465 226 623 -577 1492 1302 2459 841 -1857 -1964 -1689 -766 48 -730 -927 -1167 -466 -1113 -591 -554 -723 -455 -622 -120 928 912 631 1279 547 768 776 648 695 262 903 924 1442 1660 656 -370 -344 -739 85 720 248 609 236 619 178 154 -71 -773 -396 -551 -928 -1018 -1873 -1904 -1142 -892 -488 -58 136 209 195 434 -205 128 294 273 236 669 456 8 -154 -576 -549 -33 -262 -939 -837 -792 -363 43 260 322 66 105 103 -4 311 274 450 340 46 2 275 507 539 500 317 1060 758 348 348 -154 -83 -32 19 -203 -190 121 -15 -131 -158 -289 -446 -569 122 -491 -359 -207 -601 -758 -193 -141 219 -165 -852 -164 -183 -172 388 -246 -124 187 163 323 858 178 181 -126 757 472 213 100 253 -225 581 546 1099 407 -895 -883 -783 -370 27 -468 -630 -843 -345 -796 -419 -417 -540 -329 -438 -82 648 680 472 1001 450 643 626 528 590 220 756 767 1291 1517 629 -342 -305 -618 71 659 244 605 241 619 179 142 -61 -653 -326 -466 -892 -1033 -1986 -2120 -1265 -1062 -589 -73 167 264 233 497 -225 135 311 297 270 808 579 11 -195 -709 -651 -37 -306 -1198 -1068 -1057 -482 60 369 476 97 153 137 -5 395 354 585 457 65 3 387 693 731 644 405 1284 945 449 476 -212 -117 -46 28 -309 -290 189 -23 -208 -243 -448 -668 -842 SS 20260510T084353.8Z 9626.363817 229 1 54.33 2 43.88 116.11 70.04 220.38 0.00 1 0.00 1 0 17 9.723e-03 6.135e-03 1.556e-03 8.195e-04 2.342255e-01 4.132823e-04 2.875664e-03 -6.000000e+00 5.516099e-03 230.13 -2.00 3.61 -2.00 315.92 0.00e+00 3.475436e-04 4.200542e-05 3.784760e-05 -6.000000e+00 2.368819e-04 276.96 -2.00 20.00 -2.00 315.34 0.00e+00 1.385 0.000 302.00 328.00 3 4.5537e+00 1.0749e-03 1.8097e-02 -6.0000e+00 1.3810e-02 1.4675e-02 1.2002e-03 1.2336e-02 -6.0000e+00 1.5014e-02 -1.9288e-03 6.8896e-04 6.0403e-03 -6.0000e+00 8.9014e-03 -3.5877e-03 3.1236e-04 1.6796e-03 -6.0000e+00 3.7067e-03 1.1331e-03 -8.1570e-05 2.2665e-05 1.9081e-05 -6.0000e+00 2.5613e-04 -4.6633e-03 0.0000e+00 10 0 0 10 0 0 98.32 24.26 0.30 -0.00466 -0.00528 63 6 1 8 0 862.230 20.00 24.26 21.39 34.50 33.25 1.4 969.94 1014 -2445 -1726 -924 -2950 -3754 -750 -974 1062 -369 -3300 147 -138 -762 880 -1085 -412 413 767 728 2181 406 380 -6 2086 1145 37 189 963 -611 1610 1172 2758 319 -1814 -1992 -1920 -713 243 -948 -1047 -1127 -519 -1191 -682 -649 -737 -491 -800 -171 936 940 783 1274 593 597 750 743 708 211 941 918 1501 1424 735 -615 -87 -756 56 855 123 610 143 523 208 110 -144 -540 -247 -625 -1120 -847 -1903 -1892 -1144 -825 -403 -9 262 177 28 470 -298 -2 410 135 94 685 458 10 27 -511 -521 -1 -306 -847 -700 -896 -320 -20 391 314 95 217 -41 104 68 162 417 278 -12 -13 324 489 483 515 151 1023 782 429 310 -161 0 -28 -34 -296 -104 155 32 -110 -254 -240 -416 -576 201 -563 -413 -213 -616 -719 -141 -202 244 -93 -857 36 -37 -231 275 -385 -154 157 301 296 900 170 159 -3 868 502 17 82 413 -252 661 518 1192 151 -846 -865 -862 -358 133 -587 -731 -782 -370 -870 -494 -469 -527 -363 -576 -120 665 712 592 1007 492 505 608 607 605 178 793 765 1346 1302 702 -567 -77 -629 49 776 119 632 145 545 207 106 -124 -453 -202 -556 -1066 -845 -1979 -2065 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