File name: Pandora296s1_Aosta-SC_20260802_L2Fit_fout2c4d20251001p1-8.txt File generation date: 20260802T234757.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Stefano Casadio Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 296 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora296_OF_v3d20250723.txt Instrument calibration file used: Pandora296s1_CF_v4d20251001.txt Level 1 file used: Pandora296s1_Aosta-SC_20260802_L1_smca1c4d20251001p1-8.txt Full location name: Aosta-Saint-Christophe Short location name: Aosta-SC Country of location: Italy Location latitude [deg]: 45.7422 Location longitude [deg]: 7.3570 Location altitude [m]: 560 Local noon date: 20260802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 193 336 Nominal wavelengths inside fitting window [nm]: 305.0081 305.1486 305.2892 305.4297 305.5702 305.7107 305.8512 305.9917 306.1322 306.2727 306.4131 306.5536 306.6940 306.8344 306.9749 307.1153 307.2556 307.3960 307.5364 307.6768 307.8171 307.9574 308.0978 308.2381 308.3784 308.5187 308.6589 308.7992 308.9395 309.0797 309.2199 309.3602 309.5004 309.6406 309.7808 309.9210 310.0611 310.2013 310.3414 310.4816 310.6217 310.7618 310.9019 311.0420 311.1821 311.3221 311.4622 311.6022 311.7422 311.8823 312.0223 312.1623 312.3023 312.4422 312.5822 312.7222 312.8621 313.0020 313.1420 313.2819 313.4218 313.5617 313.7015 313.8414 313.9812 314.1211 314.2609 314.4007 314.5405 314.6803 314.8201 314.9599 315.0997 315.2394 315.3791 315.5189 315.6586 315.7983 315.9380 316.0777 316.2173 316.3570 316.4967 316.6363 316.7759 316.9155 317.0551 317.1947 317.3343 317.4739 317.6134 317.7530 317.8925 318.0320 318.1716 318.3111 318.4505 318.5900 318.7295 318.8689 319.0084 319.1478 319.2872 319.4267 319.5661 319.7054 319.8448 319.9842 320.1235 320.2629 320.4022 320.5415 320.6808 320.8201 320.9594 321.0987 321.2380 321.3772 321.5164 321.6557 321.7949 321.9341 322.0733 322.2125 322.3516 322.4908 322.6299 322.7691 322.9082 323.0473 323.1864 323.3255 323.4646 323.6036 323.7427 323.8817 324.0208 324.1598 324.2988 324.4378 324.5768 324.7158 324.8547 324.9937 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Column 101: Humidity inside spectrometer box [%], -9=no humidity signal Column 102: Temperature inside spectrometer box [°C], 999=no temperature signal Column 103: Pressure inside spectrometer box [hPa], -9=no pressure signal Columns 104-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-391: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260802T051802.2Z 9710.220859 171 1 54.98 2 80.58 74.19 63.09 234.46 0.00 1 0.00 1 0 17 7.461e-01 4.524e-02 2.257e-01 9.352e-03 7.120967e-01 5.412214e-03 8.354157e-03 -6.000000e+00 4.461937e-01 232.32 -2.00 3.61 -2.00 321.54 0.00e+00 -2.631375e-03 2.794621e-03 6.296591e-03 -6.000000e+00 2.674626e-02 284.08 -2.00 20.00 -2.00 320.96 0.00e+00 5.816 0.004 302.00 328.00 3 3.6301e+00 1.9170e-02 7.5893e-02 -6.0000e+00 1.1229e+00 6.9484e-01 2.4270e-02 6.1423e-02 -6.0000e+00 1.2303e+00 -1.0589e+00 1.9337e-02 2.2445e-02 -6.0000e+00 7.2316e-01 4.4579e-01 9.3002e-03 7.0116e-03 -6.0000e+00 3.0023e-01 2.7501e-05 -8.1514e-04 2.7759e-04 6.6719e-05 -6.0000e+00 2.2189e-02 -6.6350e-03 0.0000e+00 12 8 8 10 0 0 98.92 24.31 0.63 -0.00664 -0.01276 19 2 2 8 0 2893.250 20.00 24.31 27.43 34.75 33.25 1.2 989.35 13.3 24.15 952.74 900000 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-5021 900000 900000 900000 900000 900000 -10268 900000 3145 900000 2708 1394 -4431 900000 2973 900000 -916 4002 2935 900000 3125 2428 -5721 2957 3521 4441 4608 5014 5488 2107 2421 1055 4502 4046 6254 7224 3385 6633 -1284 3867 1836 2440 139 5559 2628 1690 1301 4984 11432 -14 7752 3123 6392 4608 -2690 3087 -2709 5459 7006 -4314 -10649 106 149 -938 5741 -2223 -1498 -1416 4351 -1412 -4249 -1100 -1235 -3755 -1474 -5118 -491 1758 -5634 -3758 5212 -3846 -4882 -5449 -7262 3589 -6139 3918 4688 -3274 2696 2444 -11416 -1725 -1456 706 3629 2380 3621 -303 17005 -1240 -235 1899 2404 2701 -505 2584 1224 -821 4368 2380 -3480 4171 3200 -6122 542 1331 -416 -5170 -4922 SS 20260802T053630.7Z 9710.233689 178 1 54.84 2 77.46 77.34 65.66 238.58 0.00 1 0.00 1 0 17 1.974e-01 7.438e-03 3.822e-02 1.305e-03 5.675239e-01 6.688691e-04 6.627329e-03 -6.000000e+00 1.129562e-01 232.32 -2.00 3.61 -2.00 320.00 0.00e+00 1.930848e-03 2.219788e-04 7.486503e-04 -6.000000e+00 4.954388e-03 284.08 -2.00 20.00 -2.00 319.30 0.00e+00 4.478 0.002 302.00 328.00 3 2.1583e+00 1.9742e-03 5.2249e-02 -6.0000e+00 2.8366e-01 2.9564e-02 2.4115e-03 3.1002e-02 -6.0000e+00 3.0747e-01 -6.5892e-02 2.1139e-03 1.5467e-02 -6.0000e+00 1.8271e-01 2.1353e-02 1.0847e-03 4.7684e-03 -6.0000e+00 7.6269e-02 4.9812e-04 -2.8686e-04 3.5064e-05 4.9523e-05 -6.0000e+00 5.2037e-03 -6.7527e-03 0.0000e+00 11 8 0 10 0 0 -5.40 24.30 0.32 -0.00675 -0.00891 143 14 4 8 0 383.470 20.01 24.30 28.26 34.50 33.25 1.2 993.18 13.3 24.14 952.80 -5391 -78324 -68632 22380 -27505 -89780 -39548 -105564 -61490 -61004 -67093 -51426 1711 -38243 -5330 -29506 -4231 -1774 -3068 -7717 19333 -14869 -28528 -19496 18127 4166 -766 927 14755 -23541 -4885 -2983 8806 3054 -5914 -13018 -2808 -2608 1584 -3042 -2182 -2516 2796 -445 -1169 -2954 1142 272 -3 113 3980 2636 274 776 781 1737 908 1105 1740 54 2684 448 1823 2324 1888 685 1852 -71 -90 794 961 2310 73 1204 187 149 -452 -1951 -608 -934 -548 -482 -1844 -2613 -1264 -608 40 589 478 445 707 602 -89 -459 60 29 -31 537 326 -72 -20 -902 -791 -336 -752 -1589 -1378 -1086 -394 -186 519 512 95 441 134 -509 201 189 280 131 -187 134 397 803 202 461 99 637 914 260 400 -128 -26 -78 -8 -194 -173 278 -194 -84 -112 59 -398 -335 -32 -1156 -1022 137 -256 -1463 -408 -2378 -1025 -1126 -1383 -962 22 -944 -119 -1018 -130 -58 -112 -315 632 -691 -1547 -1042 727 206 -41 49 648 -1531 -296 -210 642 265 -563 -1266 -258 -277 196 -484 -400 -461 514 -88 -236 -618 234 57 -1 26 933 700 82 252 273 629 345 427 657 20 983 178 734 1052 937 344 880 -34 -46 451 574 1468 49 770 113 88 -243 -1015 -324 -572 -364 -368 -1488 -2278 -1153 -553 39 590 488 449 675 571 -80 -397 54 28 -34 631 407 -96 -26 -1142 -901 -385 -852 -1963 -1679 -1395 -538 -262 806 817 156 708 205 -775 294 283 442 210 -310 218 621 1279 311 679 140 924 1329 406 690 -228 -48 -145 -16 -391 -363 593 -405 -173 -231 114 -773 -640 SS 20260802T054306.4Z 9710.238269 181 1 54.70 2 76.34 78.47 66.60 240.01 0.00 1 0.00 1 0 17 1.259e-01 6.358e-03 1.705e-02 9.380e-04 5.283385e-01 4.778249e-04 6.205168e-03 -6.000000e+00 7.203350e-02 232.32 -2.00 3.61 -2.00 319.53 0.00e+00 1.543466e-03 1.350581e-04 6.355923e-04 -6.000000e+00 3.159365e-03 284.08 -2.00 20.00 -2.00 318.80 0.00e+00 4.134 0.001 302.00 328.00 3 1.9325e+00 1.3691e-03 4.8331e-02 -6.0000e+00 1.8089e-01 1.2381e-02 1.6178e-03 2.8707e-02 -6.0000e+00 1.9607e-01 -4.2963e-02 1.3072e-03 1.4159e-02 -6.0000e+00 1.1652e-01 1.2277e-02 6.8287e-04 4.1752e-03 -6.0000e+00 4.8640e-02 8.8667e-04 -2.8876e-04 2.5322e-05 4.2286e-05 -6.0000e+00 3.3183e-03 -7.1082e-03 0.0000e+00 10 0 0 10 0 0 -7.30 24.30 0.38 -0.00711 -0.00928 212 21 4 8 0 257.980 20.00 24.30 28.88 34.50 33.25 1.2 995.28 13.3 24.12 952.82 -35156 -56162 -31831 -8236 -32837 -54789 -28933 -63363 -31141 -40750 -37236 -34341 -9979 -28530 -4311 -15169 -3026 -705 -4301 -7563 6075 -6826 -14284 -10296 7883 902 -2129 795 3850 -13515 -1868 -943 4325 1800 -3793 -8534 -2024 -3793 1056 -1336 -555 -2087 469 -603 -571 -1242 -423 -509 -370 74 2253 1542 762 1404 1082 1263 951 719 1211 47 1591 634 1662 2218 1501 688 1125 -256 606 960 1001 1520 0 709 126 -2 -454 -1371 -690 -970 -925 -486 -1601 -2176 -1187 -940 -117 458 501 374 514 628 33 -308 115 -100 11 452 305 -92 -203 -920 -870 -490 -704 -1330 -1141 -1073 -324 111 331 437 178 346 47 -294 234 318 352 143 -31 134 271 638 334 445 191 748 676 206 299 -116 37 -107 -30 -172 -238 262 -42 -140 6 -223 -322 -303 -454 -1079 -530 -110 -517 -1008 -429 -1496 -613 -981 -906 -855 -229 -984 -145 -684 -137 -34 -235 -455 335 -432 -989 -738 513 67 -171 61 274 -1146 -156 -92 461 220 -490 -1098 -255 -561 181 -261 -125 -520 120 -163 -156 -346 -119 -145 -108 22 709 499 273 542 450 547 429 331 546 21 701 299 799 1192 882 406 628 -143 349 581 691 1125 0 528 89 -1 -282 -814 -419 -625 -698 -391 -1368 -2000 -1144 -916 -120 491 547 404 526 631 31 -279 109 -100 12 555 400 -121 -258 -1147 -1033 -551 -834 -1624 -1460 -1378 -440 155 512 695 291 551 71 -435 333 462 540 224 -51 215 420 1002 504 643 278 1051 1008 328 501 -201 65 -192 -55 -338 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