File name: Pandora207s1_ArlingtonTX_20230927_L2Fit_fout2c7d20230612p1-8.txt File generation date: 20240823T133233.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Yang Li Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 207 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora207_OF_v5d20210722.txt Instrument calibration file used: Pandora207s1_CF_v7d20230612.txt Level 1 file used: Pandora207s1_ArlingtonTX_20230927_L1_smca1c7d20230612p1-8.txt Full location name: University Of Texas, Arlington Science Hall Short location name: ArlingtonTX Country of location: United States Location latitude [deg]: 32.7316 Location longitude [deg]: -97.1142 Location altitude [m]: 15 Local noon date: 20230927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 6, but with summer RefDay for AC on period. First and last pixel inside fitting window: 200 341 Nominal wavelengths inside fitting window [nm]: 305.1272 305.2686 305.4099 305.5513 305.6926 305.8339 305.9752 306.1165 306.2578 306.3990 306.5403 306.6815 306.8228 306.9640 307.1052 307.2464 307.3876 307.5287 307.6699 307.8111 307.9522 308.0933 308.2344 308.3755 308.5166 308.6577 308.7988 308.9398 309.0809 309.2219 309.3629 309.5040 309.6450 309.7859 309.9269 310.0679 310.2088 310.3498 310.4907 310.6316 310.7725 310.9134 311.0543 311.1952 311.3361 311.4769 311.6178 311.7586 311.8994 312.0402 312.1810 312.3218 312.4625 312.6033 312.7440 312.8848 313.0255 313.1662 313.3069 313.4476 313.5883 313.7289 313.8696 314.0102 314.1509 314.2915 314.4321 314.5727 314.7133 314.8539 314.9944 315.1350 315.2755 315.4160 315.5566 315.6971 315.8376 315.9780 316.1185 316.2590 316.3994 316.5398 316.6803 316.8207 316.9611 317.1015 317.2419 317.3822 317.5226 317.6629 317.8032 317.9436 318.0839 318.2242 318.3645 318.5047 318.6450 318.7852 318.9255 319.0657 319.2059 319.3461 319.4863 319.6265 319.7667 319.9068 320.0470 320.1871 320.3273 320.4674 320.6075 320.7476 320.8876 321.0277 321.1678 321.3078 321.4478 321.5879 321.7279 321.8679 322.0079 322.1478 322.2878 322.4277 322.5677 322.7076 322.8475 322.9874 323.1273 323.2672 323.4071 323.5470 323.6868 323.8266 323.9665 324.1063 324.2461 324.3859 324.5257 324.6654 324.8052 324.9449 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230927T130244.2Z 8670.543567 156 1 49.01 2 81.84 97.29 125.48 278.03 0.00 1 0.00 1 0 25 4.510e-01 1.616e-02 3.373e-01 1.012e-02 7.622123e-01 6.468178e-03 8.138842e-03 -6.000000e+00 3.084347e-01 228.19 -2.00 3.32 -2.00 321.97 0.00e+00 2.522310e-03 4.252661e-03 4.125148e-03 -6.000000e+00 1.452086e-02 291.33 -2.00 20.00 -2.00 321.39 0.00e+00 6.598 0.004 302.00 328.00 3 1.1186e+00 2.7914e-02 7.8909e-02 -6.0000e+00 7.6223e-01 5.8108e-01 3.7581e-02 4.7716e-02 -6.0000e+00 8.2256e-01 -7.7920e-01 2.9206e-02 2.2897e-02 -6.0000e+00 4.9296e-01 3.0932e-01 1.2860e-02 5.7778e-03 -6.0000e+00 2.0118e-01 1.1247e-04 -1.3180e-03 3.7640e-04 1.6368e-04 -6.0000e+00 1.9081e-02 4.9393e-03 0.0000e+00 12 8 8 10 0 0 21.34 19.65 0.35 0.00494 -0.00496 45 11 4 8 0 1088.830 15.00 19.65 32.26 19.85 19.64 17.0 943.98 -129090 900000 -184398 -138672 -142608 46835 -19067 -105171 -7106 -175519 -64722 -152703 -86008 -109306 -37419 10613 40 128304 -25279 99271 -84023 65733 -69792 -6605 -53621 -50253 10387 -43904 22589 22884 95349 -15135 9449 15836 75427 6965 -29457 61043 19440 44278 -10973 75566 3148 42943 23825 19131 16192 18161 28010 25555 24921 12442 34572 -2174 18296 8159 26394 7006 6515 11313 5093 21602 4260 14002 7054 5518 6945 11121 7621 8036 11090 2947 9439 -3474 4364 -3775 478 202 635 3936 -2811 2381 -2453 94 -1579 -334 503 131 648 -564 517 -1062 65 -2937 606 -2804 -598 -3021 -2895 -1836 -1678 -1065 -1206 449 -2003 -1432 -2614 -900 -1282 -495 218 258 289 -54 344 -171 1483 -659 945 603 761 680 483 2184 967 1632 -497 1259 -166 672 146 425 324 8 540 -664 -278 -206 139 -515 -319 -488 -1911 900000 -5004 -2281 -2346 462 -188 -1297 -70 -5052 -692 -5069 -1775 -3432 -671 133 1 1266 -544 980 -3317 649 -2505 -130 -1732 -1578 177 -1300 365 411 941 -502 263 426 1150 225 -1533 1479 820 1629 -758 2305 203 1888 1282 1098 988 1255 1880 1917 2066 1277 3071 -296 2113 1063 2865 913 849 1440 734 2878 736 2335 1309 1073 1398 2316 1797 2038 2845 820 2366 -926 999 -898 111 51 183 1266 -1101 985 -1157 46 -837 -182 278 73 350 -296 259 -537 34 -1745 396 -2169 -507 -2830 -2768 -1695 -1467 -879 -977 366 -1760 -1339 -2691 -1005 -1591 -668 311 378 424 -79 488 -246 2150 -1008 1453 929 1147 993 684 2944 1295 2192 -718 1959 -291 1287 306 954 777 20 1433 -1835 -771 -565 367 -1311 -779 -1177 SS 20230927T130915.6Z 8670.548097 159 1 48.72 2 80.49 98.21 126.76 279.05 0.00 1 0.00 1 0 25 4.605e-01 1.234e-02 2.100e-01 4.974e-03 6.930610e-01 3.102114e-03 7.419678e-03 -6.000000e+00 3.148583e-01 228.19 -2.00 3.32 -2.00 321.53 0.00e+00 6.834631e-03 1.857871e-03 5.954802e-04 -6.000000e+00 1.459195e-02 291.33 -2.00 20.00 -2.00 320.91 0.00e+00 5.759 0.003 302.00 328.00 3 8.8404e-01 1.2262e-02 6.7542e-02 -6.0000e+00 7.7831e-01 3.0760e-01 1.6476e-02 3.7884e-02 -6.0000e+00 8.3982e-01 -3.6006e-01 1.3766e-02 1.8290e-02 -6.0000e+00 5.0330e-01 1.3295e-01 6.2543e-03 9.5706e-03 -6.0000e+00 2.0489e-01 3.3804e-04 -1.2736e-03 1.8462e-04 1.7214e-04 -6.0000e+00 1.9482e-02 4.4794e-03 0.0000e+00 12 8 8 10 0 0 -13.97 19.65 0.35 0.00448 -0.00509 88 21 4 8 0 553.080 15.00 19.65 32.71 19.85 19.64 17.1 947.21 -207016 -76859 -168462 -97041 -157369 -74969 -185694 -193729 -112041 -171897 -55345 -118177 -37936 -65117 -39522 -43154 -54529 -56830 -62658 -24759 -68850 3171 -50433 -4086 -37685 -9396 -28159 -56363 -19175 -40163 -3487 -33980 2407 -3343 599 -9729 -5649 -6026 1285 12450 -9951 17057 -8 19230 9664 10206 1297 8959 2010 3771 4585 6386 11905 8591 13380 8532 5292 2288 -612 6640 1686 8239 2005 8055 4001 6575 5973 4818 4441 4249 2794 -646 2337 -671 300 -3359 -1628 -1354 -1547 -1828 -1953 -871 -713 -430 -970 98 -610 253 378 -329 214 -1218 219 -1398 754 -652 -74 -223 -81 -514 -599 -879 -2434 -999 -1198 -676 -741 75 -259 23 -257 -283 663 200 1352 541 1095 -3883 990 314 -286 74 555 881 1192 1849 -158 1121 436 289 324 -7 -12 -339 498 -337 -222 -81 -105 -271 80 -569 -3347 -373 -2111 -588 -1717 -364 -3111 -3758 -1037 -3183 -366 -1771 -318 -890 -505 -666 -1058 -1228 -1519 -426 -1882 43 -1223 -65 -864 -166 -608 -1665 -423 -1239 -86 -1288 69 -106 19 -369 -232 -287 66 706 -772 1075 -1 1278 726 787 114 769 199 401 531 796 1518 1204 1862 1274 821 365 -101 1059 303 1522 431 1734 929 1531 1463 1283 1297 1343 938 -225 764 -212 88 -974 -471 -423 -551 -750 -910 -445 -395 -254 -611 64 -409 168 246 -207 129 -732 134 -952 569 -567 -72 -232 -86 -533 -589 -824 -2275 -942 -1189 -713 -846 93 -355 34 -404 -454 1044 310 2029 821 1692 -6516 1619 518 -465 116 839 1283 1694 2620 -239 1817 784 571 692 -15 -27 -796 1210 -849 -566 -203 -258 -636 180 -1278 SS 20230927T131949.3Z 8670.555432 164 1 49.63 2 78.29 99.70 128.82 280.75 0.00 1 0.00 1 0 25 3.100e-01 6.766e-03 7.356e-02 2.178e-03 5.938085e-01 1.332110e-03 6.398560e-03 -6.000000e+00 2.119668e-01 228.19 -2.00 3.32 -2.00 321.02 0.00e+00 2.364296e-03 6.674982e-04 1.298637e-03 -6.000000e+00 9.822409e-03 291.33 -2.00 20.00 -2.00 320.31 0.00e+00 4.768 0.001 302.00 328.00 3 7.1023e-01 4.6395e-03 5.5942e-02 -6.0000e+00 5.2397e-01 1.1509e-01 6.0358e-03 3.0139e-02 -6.0000e+00 5.6536e-01 -1.2135e-01 5.0067e-03 1.5409e-02 -6.0000e+00 3.3882e-01 3.6870e-02 2.3654e-03 4.7611e-03 -6.0000e+00 1.3795e-01 1.1815e-03 -8.2172e-04 8.5793e-05 9.6332e-05 -6.0000e+00 1.3114e-02 3.7254e-03 0.0000e+00 11 8 0 10 0 0 8.01 19.65 0.39 0.00373 -0.00245 183 43 4 8 0 265.330 15.00 19.65 33.72 19.85 19.64 17.3 953.22 -103062 -115900 -96486 -115964 -67061 -106734 -76597 -122955 -87613 -110871 -76014 -84615 -58900 -15215 -35348 -19138 -31522 -7608 -35822 -25182 -36287 -13130 -16999 -22553 -7997 -20172 -3631 -24161 -7799 -23631 -5729 -15937 -8530 -9872 -10168 -3047 -6147 2065 -3588 1292 -1881 -806 -516 1951 2992 1111 5708 -976 4915 384 4855 666 2813 2825 2883 3306 1019 3486 340 3519 2215 1960 1393 2404 1223 1364 3326 1179 3236 1272 1574 -586 -412 -199 -637 -203 -682 182 -870 126 -964 -315 -1644 -1226 -610 -115 -220 -174 718 -354 689 216 259 436 839 145 -523 -61 -874 -338 -97 -337 -1304 54 -950 -1210 -545 -549 -8 -290 132 -102 355 374 647 842 563 197 9 63 -687 148 73 228 917 860 340 483 620 123 153 -121 -19 -141 276 -476 -483 -129 -257 -115 236 174 -803 -1231 -876 -1276 -453 -1113 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