File name: Pandora291s1_Ashgabat_20251225_L2Fit_fout2c2d20251201p1-8.txt File generation date: 20260330T120545.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 291 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora291_OF_v2d20250701.txt Instrument calibration file used: Pandora291s1_CF_v2d20251201.txt Level 1 file used: Pandora291s1_Ashgabat_20251225_L1_smca1c2d20251201p1-8.txt Full location name: US Embassy Ashgabat, Turkmenistan Short location name: Ashgabat Country of location: Turkmenistan Location latitude [deg]: 37.8819 Location longitude [deg]: 58.3583 Location altitude [m]: 365 Local noon date: 20251225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Lab analysis and clearance session: also used for generating OOB CF First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1219 305.2624 305.4029 305.5434 305.6838 305.8243 305.9647 306.1052 306.2456 306.3860 306.5264 306.6668 306.8072 306.9476 307.0880 307.2283 307.3686 307.5090 307.6493 307.7896 307.9299 308.0702 308.2104 308.3507 308.4910 308.6312 308.7714 308.9116 309.0519 309.1920 309.3322 309.4724 309.6126 309.7527 309.8929 310.0330 310.1731 310.3132 310.4533 310.5934 310.7335 310.8735 311.0136 311.1536 311.2936 311.4336 311.5736 311.7136 311.8536 311.9936 312.1336 312.2735 312.4134 312.5534 312.6933 312.8332 312.9731 313.1130 313.2528 313.3927 313.5325 313.6724 313.8122 313.9520 314.0918 314.2316 314.3714 314.5111 314.6509 314.7906 314.9304 315.0701 315.2098 315.3495 315.4892 315.6289 315.7686 315.9082 316.0478 316.1875 316.3271 316.4667 316.6063 316.7459 316.8855 317.0250 317.1646 317.3041 317.4437 317.5832 317.7227 317.8622 318.0017 318.1411 318.2806 318.4201 318.5595 318.6989 318.8383 318.9778 319.1171 319.2565 319.3959 319.5353 319.6746 319.8139 319.9533 320.0926 320.2319 320.3712 320.5105 320.6497 320.7890 320.9282 321.0675 321.2067 321.3459 321.4851 321.6243 321.7635 321.9026 322.0418 322.1809 322.3200 322.4592 322.5983 322.7374 322.8765 323.0155 323.1546 323.2936 323.4327 323.5717 323.7107 323.8497 323.9887 324.1277 324.2667 324.4056 324.5446 324.6835 324.8224 324.9613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20251225T041035.4Z 9490.174021 93 1 55.28 2 82.57 127.49 120.74 81.28 0.00 1 0.00 1 0 25 4.965e-01 4.693e-02 3.114e-01 1.418e-02 9.018725e-01 8.558887e-03 9.533273e-03 -6.000000e+00 3.140075e-01 223.41 -2.00 3.44 -2.00 321.98 0.00e+00 -3.006118e-02 4.385230e-03 1.427637e-02 -6.000000e+00 1.509301e-02 277.06 -2.00 20.00 -2.00 321.47 0.00e+00 7.168 0.006 302.00 328.00 3 2.8554e+00 3.0709e-02 1.3879e-01 -6.0000e+00 7.7118e-01 1.0815e+00 3.9586e-02 1.7125e-01 -6.0000e+00 8.4292e-01 -1.5339e+00 3.0681e-02 4.4125e-02 -6.0000e+00 5.0229e-01 6.1512e-01 1.4320e-02 2.4323e-02 -6.0000e+00 2.0415e-01 1.3201e-05 -3.4464e-03 4.5473e-04 2.3926e-04 -6.0000e+00 1.9086e-02 3.7914e-02 0.0000e+00 12 8 8 10 0 0 49.11 26.67 1.41 0.03791 0.01202 17 2 1 5 0 3251.340 36.25 20.01 26.67 12.65 5.4 948.46 51776 -2322 26839 -57859 -67327 1694 -79758 -71957 93886 -40649 -69183 -2347 900000 39892 70764 900000 30165 108758 900000 6769 87432 25674 23664 60978 -38556 900000 900000 10372 79370 72998 177731 25685 98235 47617 123114 7824 157164 900000 139271 94924 224665 900000 900000 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3189 2893 288 2013 -2920 2859 1112 -5095 -5257 121 -4705 -5629 -12860 3060 -4248 4427 864 -7204 2350 -1112 -2684 2413 2891 1355 -2965 -533 2405 4464 -394 -93 1842 2837 4479 3809 571 716 8753 -3827 -4136 -1663 1953 2351 -3530 2624 -1432 -5473 1494 2563 -3911 11 3189 2374 882 -3636 -1455 SU 20251225T041345.3Z 9490.176219 96 1 54.78 2 82.08 128.03 120.14 81.79 0.00 1 0.00 1 0 17 7.253e-01 3.411e-02 3.206e-01 9.544e-03 8.658370e-01 5.676717e-03 9.262531e-03 -6.000000e+00 4.563720e-01 223.41 -2.00 3.44 -2.00 321.94 0.00e+00 -5.273247e-03 3.112086e-03 7.854656e-03 -6.000000e+00 2.159671e-02 277.06 -2.00 20.00 -2.00 321.46 0.00e+00 6.782 0.005 302.00 328.00 3 2.6857e+00 2.0294e-02 9.1895e-02 -6.0000e+00 1.1196e+00 9.2220e-01 2.6625e-02 7.9229e-02 -6.0000e+00 1.2215e+00 -1.2721e+00 2.3025e-02 2.9850e-02 -6.0000e+00 7.2900e-01 5.0555e-01 1.0715e-02 8.1743e-03 -6.0000e+00 2.9830e-01 2.2167e-05 -1.6751e-03 3.0217e-04 1.4119e-04 -6.0000e+00 2.7637e-02 3.7302e-02 0.0000e+00 12 8 8 10 0 0 39.97 26.67 1.37 0.03730 0.02471 24 2 1 5 0 2282.060 36.25 20.00 26.67 12.76 5.4 949.09 67035 46723 900000 -108708 -149329 66312 -51773 -156313 -39448 -29540 -100254 58258 900000 -8228 900000 359317 -44913 62408 187490 -18193 78992 105928 -32570 -6798 -41454 900000 -5358 774 -23114 144439 73473 -10116 34197 16103 65334 68831 40290 900000 137373 121108 464750 900000 149535 235134 53998 49963 13966 23440 54884 56034 23770 41812 41064 27341 16446 31988 32981 -1093 4074 38753 8925 46788 16098 29427 9821 22107 2175 201 37355 32512 39014 14603 11864 20574 -6662 -51610 12448 4566 -4364 900000 -2415 6540 4244 -2215 14439 4313 -2847 1600 9436 4523 2299 -4241 -4482 36 -2111 -5083 -6050 -2289 -1518 -2788 -7825 -1748 -4235 3166 -658 -5524 13 31 -2501 -963 506 365 -1436 717 843 775 302 244 1240 922 594 2630 1736 1962 3668 -748 -1752 -238 1845 3119 -1271 2336 233 -845 827 -1080 -1654 480 809 550 -161 -1206 -1215 623 434 900000 -3705 -7056 616 -1050 -9643 -800 -574 -4321 591 900000 -223 900000 3340 -2277 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0.004 302.00 328.00 3 2.6512e+00 1.4496e-02 8.7612e-02 -6.0000e+00 9.7307e-01 4.8144e-01 2.0707e-02 7.5785e-02 -6.0000e+00 1.0613e+00 -7.0208e-01 2.1086e-02 2.8358e-02 -6.0000e+00 6.3257e-01 2.7769e-01 9.6285e-03 9.3749e-03 -6.0000e+00 2.5866e-01 3.5201e-05 -1.1215e-03 2.1584e-04 1.3467e-04 -6.0000e+00 2.3546e-02 3.7570e-02 0.0000e+00 12 9 8 11 32 0 13.71 26.67 1.46 0.03757 0.02914 32 3 1 5 0 1706.660 36.25 20.00 26.67 12.90 5.4 949.87 -98765 -94082 900000 -236595 -181617 -115920 -209029 -217844 56963 -196384 -185409 -48120 900000 -93213 83536 -61779 -74515 -43311 63268 -54202 8116 44953 -96423 -47353 -40786 900000 900000 15758 65084 -6542 114890 -25483 181043 12029 36668 3726 -2093 210509 141484 54546 132965 900000 128546 50830 38692 2456 54549 7911 51653 34693 11467 18108 22863 20051 18101 12020 6667 -7199 959 21917 3423 30730 16948 17102 6090 8192 -228 4371 18845 17702 18052 1715 4375 11070 -9217 -38761 2554 1943 -53 104620 -2734 1165 -2211 -236 2994 785 -619 -1876 1486 -1690 1964 5 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