File name: Pandora291s1_Ashgabat_20260624_L2Fit_fout2c2d20251201p1-8.txt File generation date: 20260624T201843.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Brian Frey Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 291 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora291_OF_v3d20250701.txt Instrument calibration file used: Pandora291s1_CF_v2d20251201.txt Level 1 file used: Pandora291s1_Ashgabat_20260624_L1_smca1c2d20251201p1-8.txt Full location name: US Embassy Ashgabat, Turkmenistan Short location name: Ashgabat Country of location: Turkmenistan Location latitude [deg]: 37.8819 Location longitude [deg]: 58.3583 Location altitude [m]: 365 Local noon date: 20260624 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Lab analysis and clearance session: also used for generating OOB CF First and last pixel inside fitting window: 201 343 Nominal wavelengths inside fitting window [nm]: 305.1219 305.2624 305.4029 305.5434 305.6838 305.8243 305.9647 306.1052 306.2456 306.3860 306.5264 306.6668 306.8072 306.9476 307.0880 307.2283 307.3686 307.5090 307.6493 307.7896 307.9299 308.0702 308.2104 308.3507 308.4910 308.6312 308.7714 308.9116 309.0519 309.1920 309.3322 309.4724 309.6126 309.7527 309.8929 310.0330 310.1731 310.3132 310.4533 310.5934 310.7335 310.8735 311.0136 311.1536 311.2936 311.4336 311.5736 311.7136 311.8536 311.9936 312.1336 312.2735 312.4134 312.5534 312.6933 312.8332 312.9731 313.1130 313.2528 313.3927 313.5325 313.6724 313.8122 313.9520 314.0918 314.2316 314.3714 314.5111 314.6509 314.7906 314.9304 315.0701 315.2098 315.3495 315.4892 315.6289 315.7686 315.9082 316.0478 316.1875 316.3271 316.4667 316.6063 316.7459 316.8855 317.0250 317.1646 317.3041 317.4437 317.5832 317.7227 317.8622 318.0017 318.1411 318.2806 318.4201 318.5595 318.6989 318.8383 318.9778 319.1171 319.2565 319.3959 319.5353 319.6746 319.8139 319.9533 320.0926 320.2319 320.3712 320.5105 320.6497 320.7890 320.9282 321.0675 321.2067 321.3459 321.4851 321.6243 321.7635 321.9026 322.0418 322.1809 322.3200 322.4592 322.5983 322.7374 322.8765 323.0155 323.1546 323.2936 323.4327 323.5717 323.7107 323.8497 323.9887 324.1277 324.2667 324.4056 324.5446 324.6835 324.8224 324.9613 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20260624T014246.2Z 9671.071368 85 1 55.21 2 80.72 67.49 146.69 306.27 0.00 1 0.00 1 0 17 7.042e-01 3.849e-02 3.250e-01 1.042e-02 6.667612e-01 6.170182e-03 8.786152e-03 -6.000000e+00 4.607240e-01 232.51 -2.00 3.44 -2.00 321.47 0.00e+00 9.042489e-03 3.148574e-03 8.386906e-03 -6.000000e+00 2.143042e-02 287.39 -2.00 20.00 -2.00 320.84 0.00e+00 5.890 0.003 302.00 328.00 3 3.6903e+00 2.2196e-02 7.6833e-02 -6.0000e+00 1.1538e+00 6.8765e-01 2.7644e-02 5.8273e-02 -6.0000e+00 1.2488e+00 -9.4556e-01 2.0324e-02 2.4760e-02 -6.0000e+00 7.4103e-01 3.7961e-01 9.5624e-03 5.2655e-03 -6.0000e+00 2.9972e-01 2.1013e-05 -3.1043e-03 3.6243e-04 2.4891e-04 -6.0000e+00 2.6858e-02 3.1829e-02 0.0000e+00 12 8 8 10 0 0 10.39 26.31 1.27 0.03183 0.00850 14 1 1 5 0 3943.270 36.00 20.00 26.31 32.09 5.3 1051.88 331505 105379 900000 -147350 244689 900000 36496 -9229 -128557 71602 -81110 18063 900000 22432 189610 45476 23925 900000 137596 -19982 174782 76471 4041 79223 34240 203849 95909 -18827 217758 211675 162625 69344 93325 38490 131381 33436 -27409 900000 153822 79172 107860 900000 107890 48316 47842 35091 30873 20520 62903 148573 11975 57833 40115 25925 24637 13431 20552 -6357 10400 19236 929 25644 -4817 32753 24200 23238 -12440 98 26166 7984 27972 1365 -3341 15846 -6056 -38448 5429 -5298 -1500 900000 -7737 3612 3967 -3048 9000 1223 -4195 -263 -1799 1429 1646 1248 -2915 877 121 -7266 -3944 -6705 -1625 2102 -5101 695 -4016 4213 -2454 -2727 -1139 -1361 -2167 469 111 1540 -2297 351 200 2263 573 1420 -273 1298 2941 1461 740 1970 3545 1334 -1882 -237 666 2856 -1120 2327 -880 -339 1509 780 -686 -53 -5484 1767 948 -1477 268 3363 1069 900000 -13826 2482 900000 505 -204 -9484 726 -4039 383 900000 662 1923 1384 971 900000 1903 -1327 1773 1833 197 1826 1231 2068 1769 -1076 2209 2147 1950 2366 2668 1917 2544 1758 -2881 900000 3404 4089 4476 900000 4776 3921 3926 3301 3075 2328 4873 5206 1778 5866 5179 4040 3999 2465 3487 -1384 1880 3211 196 4611 -1288 6433 5311 5143 -3969 29 6515 2606 7919 511 -1272 4661 -2033 -16522 1608 -1666 -510 900000 -3703 1722 2048 -1804 5013 776 -2917 -178 -1221 903 984 716 -1734 532 83 -6151 -3685 -7142 -1737 2151 -5310 636 -3688 3601 -2354 -2784 -1225 -1592 -2816 655 169 2202 -3423 497 298 3264 854 2186 -409 1960 4349 2329 1149 2921 5005 1879 -2751 -362 1111 4737 -2106 4526 -1877 -765 3532 1921 -1621 -126 -13517 4233 2175 -3325 587 SS 20260624T015306.1Z 9671.078543 90 1 53.83 2 78.83 68.94 148.25 309.64 0.00 1 0.00 1 0 25 3.185e-01 1.900e-02 1.240e-01 4.497e-03 5.878840e-01 2.573561e-03 6.735166e-03 -6.000000e+00 2.059801e-01 232.51 -2.00 3.44 -2.00 320.75 0.00e+00 4.360790e-03 1.126187e-03 2.875301e-03 -6.000000e+00 9.329312e-03 287.39 -2.00 20.00 -2.00 320.06 0.00e+00 4.979 0.002 302.00 328.00 3 3.5315e+00 8.4165e-03 5.7844e-02 -6.0000e+00 5.1560e-01 1.8721e-01 1.0452e-02 3.3649e-02 -6.0000e+00 5.5707e-01 -3.0517e-01 8.3348e-03 1.6865e-02 -6.0000e+00 3.3155e-01 1.2086e-01 4.0203e-03 4.9794e-03 -6.0000e+00 1.3451e-01 7.0737e-05 -8.9518e-04 1.5484e-04 1.1790e-04 -6.0000e+00 1.1605e-02 3.3612e-02 0.0000e+00 12 8 8 10 0 0 95.26 26.31 0.55 0.03361 0.02689 29 3 1 5 0 1855.810 36.00 19.99 26.31 32.64 5.3 1054.14 -10763 12784 -7866 -201375 -24207 -34921 -103295 -124830 -130462 -67736 -129885 -47252 2108 -78854 -10687 -20948 -42128 81679 -4350 -2517 -21513 -31467 -35877 -8563 -12460 35122 26248 -23538 -12479 -9333 21827 2165 16962 4470 1255 8190 4504 40306 17392 12896 6210 900000 24030 4336 17050 1097 5492 2707 22628 28790 1803 10017 7148 5170 11826 4078 4718 -1025 663 3011 1567 9862 6406 8385 4643 6018 -790 -1188 4739 2367 6880 864 -2276 856 -1244 -14246 824 -369 -1215 -6466 -2584 -1167 -2941 -2154 460 349 -338 -828 424 1062 320 957 -308 -572 734 -1772 -1509 -1512 65 -1028 -1811 342 -326 352 -1133 -2294 -662 -270 -111 423 196 -134 -744 509 -85 655 290 209 838 223 815 423 700 1203 1376 639 174 935 296 778 -780 550 525 323 277 159 -131 -94 -1828 -74 374 -670 -503 -86 87 -66 -11239 -222 -362 -2265 -3682 -4369 -1296 -5126 -961 32 -3269 -264 -651 -1780 1074 -142 -83 -875 -1443 -1788 -341 -536 1047 852 -1259 -624 -499 976 133 967 296 87 560 361 2651 1678 1470 825 900000 2929 658 2318 178 872 457 3294 4242 380 2126 1530 1197 2673 1022 1185 -271 171 778 437 2768 2038 2781 1631 2077 -296 -473 1955 1098 3244 441 -1169 401 -550 -6678 324 -154 -574 -3696 -1617 -800 -2228 -1588 352 282 -286 -714 355 849 243 755 -244 -440 621 -1748 -1675 -1700 75 -1182 -2148 371 -346 379 -1302 -2830 -792 -347 -156 644 296 -210 -1157 814 -132 989 446 336 1296 356 1286 654 1124 1853 2044 931 256 1442 468 1341 -1473 1088 1025 669 608 363 -289 -209 -4076 -167 805 -1403 -1050 SS 20260624T015910.8Z 9671.082764 93 1 54.29 2 77.70 69.78 149.14 311.74 0.00 1 0.00 1 0 17 2.193e-01 1.147e-02 6.766e-02 2.956e-03 5.479860e-01 1.680929e-03 6.132319e-03 -6.000000e+00 1.417990e-01 232.51 -2.00 3.44 -2.00 320.26 0.00e+00 2.254473e-04 6.269990e-04 1.572976e-03 -6.000000e+00 6.395192e-03 287.39 -2.00 20.00 -2.00 319.52 0.00e+00 4.559 0.002 302.00 328.00 3 3.3660e+00 5.1678e-03 5.2692e-02 -6.0000e+00 3.5498e-01 4.5984e-02 6.2964e-03 3.0137e-02 -6.0000e+00 3.8343e-01 -1.4307e-01 4.9729e-03 1.4026e-02 -6.0000e+00 2.2832e-01 5.8467e-02 2.4508e-03 3.6004e-03 -6.0000e+00 9.2626e-02 1.3331e-04 -2.4158e-04 1.0300e-04 6.3448e-05 -6.0000e+00 7.9934e-03 3.3603e-02 0.0000e+00 12 8 8 10 0 0 96.95 26.31 0.46 0.03360 0.03179 42 4 1 5 0 1292.420 36.00 20.01 26.31 33.01 5.3 1055.78 -20511 -27397 11438 -153800 -62223 -54070 -55850 -91350 -62413 -44299 -70285 -43805 7833 -63151 -4800 -25780 -33503 25889 2374 -8302 -8060 -11305 -21230 -2451 -18286 13183 4840 -14441 -11788 -225 2302 -6183 1060 -8175 -5448 1676 -10157 16734 4268 3254 3759 -17289 7898 4013 6762 212 -2426 703 6027 8560 -496 4777 3173 2152 2500 2575 4567 932 759 1579 1196 3756 2633 4153 3036 45 -1223 2521 4307 1010 3798 337 129 833 -1226 -7135 -712 55 -1666 1874 -1858 -1780 -1833 -1488 -272 -407 -847 373 359 382 767 1052 -221 207 415 -1440 -750 -828 -378 -518 -1419 -486 -1053 158 -411 -1552 -497 -472 115 18 428 371 -327 223 164 777 397 202 42 249 -48 128 593 750 904 630 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