File name: Pandora119s1_Athens-NOA_20180414_L2Fit_fwvt1c5d20180103p1-8.txt File generation date: 20250610T122553.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v5d20180103.txt Instrument calibration file used: Pandora119s1_CF_v5d20180103.txt Level 1 file used: Pandora119s1_Athens-NOA_20180414_L1_smca1c5d20180103p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20180414 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 117 for SO2 First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0162 492.1377 492.2591 492.3806 492.5020 492.6234 492.7448 492.8662 492.9876 493.1089 493.2303 493.3516 493.4729 493.5942 493.7154 493.8367 493.9579 494.0791 494.2003 494.3215 494.4427 494.5638 494.6849 494.8061 494.9272 495.0482 495.1693 495.2904 495.4114 495.5324 495.6534 495.7744 495.8954 496.0163 496.1372 496.2582 496.3791 496.4999 496.6208 496.7416 496.8625 496.9833 497.1041 497.2249 497.3456 497.4664 497.5871 497.7078 497.8285 497.9492 498.0699 498.1905 498.3111 498.4318 498.5523 498.6729 498.7935 498.9140 499.0346 499.1551 499.2756 499.3960 499.5165 499.6370 499.7574 499.8778 499.9982 500.1186 500.2389 500.3593 500.4796 500.5999 500.7202 500.8405 500.9607 501.0810 501.2012 501.3214 501.4416 501.5618 501.6819 501.8021 501.9222 502.0423 502.1624 502.2824 502.4025 502.5225 502.6426 502.7626 502.8825 503.0025 503.1225 503.2424 503.3623 503.4822 503.6021 503.7220 503.8418 503.9617 504.0815 504.2013 504.3211 504.4408 504.5606 504.6803 504.8000 504.9197 505.0394 505.1590 505.2787 505.3983 505.5179 505.6375 505.7571 505.8767 505.9962 506.1157 506.2352 506.3547 506.4742 506.5937 506.7131 506.8325 506.9519 507.0713 507.1907 507.3101 507.4294 507.5487 507.6680 507.7873 507.9066 508.0258 508.1451 508.2643 508.3835 508.5027 508.6218 508.7410 508.8601 508.9792 509.0983 509.2174 509.3365 509.4555 509.5745 509.6936 509.8126 509.9315 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180414T035704.0Z 6678.164630 374 1 32.00 2 89.73 78.29 82.38 101.08 0.00 1 0.00 1 0 15 4.904e-02 4.866e-02 5.151e-02 5.111e-02 3.867297e+03 3.335603e+03 8.885094e+01 -6.000000e+00 2.815149e+03 281.50 -2.00 20.00 -2.00 505.31 0.00e+00 3.509664e-03 1.415106e-03 1.517048e-04 -6.000000e+00 1.393462e-03 281.50 -2.00 20.00 -2.00 500.43 0.00e+00 1.213743e+00 1.028656e+00 7.344766e-02 -6.000000e+00 9.897762e-01 228.75 -2.00 3.45 -2.00 502.02 0.00e+00 20.153 0.140 489.00 513.00 1 9.2704e+00 7.8880e-02 3.5387e-02 -6.0000e+00 7.6069e-02 1.0600e-01 1.9879e-02 2.2517e-03 -6.0000e+00 1.9412e-02 9.2967e-06 2.8312e-04 5.6979e-03 5.7955e-05 -6.0000e+00 5.6340e-03 -2.7017e-02 3.8620e-04 12 8 8 10 0 0 42.45 20.47 4.63 -0.02702 -0.02505 8 2 1 4 0 4000.000 25.79 20.00 20.47 -7802 2254 1651 -489 1044 -8823 -190 -1416 -2360 1124 -2668 -911 -6447 3643 -2961 6137 2283 3762 3527 -505 -2369 5208 -1131 3968 4934 -4436 769 3461 -3079 8304 -1626 4089 -5667 2453 1814 -2234 -302 -5856 2150 -521 2975 578 2138 5354 -1029 3052 6788 -2475 9894 -4524 11893 -6404 6058 -4671 -3680 7645 -2198 278 -1547 2259 -4745 2467 -2475 -1215 -2427 -10008 2035 -2598 -135 -2330 3492 1890 -2659 6783 7329 2058 -1418 5683 -983 5896 -4245 -5916 -8617 -1656 4875 4809 6251 743 3776 -2205 -2281 9051 -2115 3675 530 3388 1606 -13966 1505 5781 1678 -9040 4496 2005 -6038 7241 -1833 -7948 -8011 -1097 -6586 -2016 12161 6704 5807 -1221 2002 6118 4113 -1238 695 7869 -4328 3682 -3628 8957 -2672 1013 -2208 -3401 8085 5234 5977 3538 -4897 8027 -4206 -3304 -6387 -166 1423 2029 1828 -12092 3119 2 -6090 2299 -481 640 -7794 2058 1558 -487 1052 -10046 -202 -1536 -2582 1176 -2859 -945 -6966 3519 -3040 5774 2263 3749 3593 -543 -2606 5326 -1204 4031 4986 -4927 807 3488 -3242 7613 -1622 3864 -6018 2469 1880 -2433 -321 -6534 2194 -543 3007 604 2224 5459 -1128 3221 6869 -2714 9414 -4857 10568 -6702 5562 -4822 -3851 7333 -2314 288 -1641 2308 -5210 2529 -2671 -1292 -2589 -11364 2018 -2660 -133 -2325 3270 1803 -2677 6267 6753 1984 -1395 5137 -941 5255 -4198 -5985 -9018 -1630 4528 4492 5760 723 3565 -2219 -2262 8317 -2139 3506 516 3145 1483 -14704 1329 4950 1463 -8932 3992 1875 -6217 6536 -1798 -8222 -8287 -1070 -6886 -2046 10858 6387 5625 -1276 2035 5956 4049 -1268 689 7199 -4360 3521 -3660 8183 -2680 979 -2198 -3410 7153 4699 5266 3181 -4817 7045 -4248 -3360 -6785 -167 1421 2022 1833 -13942 3072 2 -6369 2171 -463 611 SO 20180414T040120.0Z 6678.167593 378 1 31.99 2 88.91 78.94 81.57 101.73 0.00 1 0.00 1 0 15 2.476e-02 2.438e-02 2.567e-02 2.554e-02 5.154828e+03 1.736376e+03 3.699370e+02 -6.000000e+00 1.421322e+03 281.50 -2.00 20.00 -2.00 505.36 0.00e+00 3.287263e-03 7.170043e-04 1.735716e-04 -6.000000e+00 7.038930e-04 281.50 -2.00 20.00 -2.00 500.53 0.00e+00 1.866413e+00 5.167764e-01 4.384875e-02 -6.000000e+00 5.008293e-01 228.75 -2.00 3.45 -2.00 502.12 0.00e+00 18.477 0.108 489.00 513.00 1 8.7399e+00 3.9708e-02 3.0787e-02 -6.0000e+00 3.8476e-02 5.9329e-02 9.9043e-03 1.8918e-03 -6.0000e+00 9.8473e-03 1.9124e-05 1.2733e-03 2.8354e-03 7.7714e-05 -6.0000e+00 2.8440e-03 -1.2347e-02 1.1186e-04 12 8 8 10 0 0 60.43 20.46 1.39 -0.01235 -0.00352 8 2 1 4 0 4000.000 25.79 20.00 20.46 995 -2936 853 -1017 -1986 392 -87 3296 -2085 865 292 -4 -306 -2203 2449 -4484 -60 1816 3865 -128 -1890 3175 -4248 1990 -2093 3746 158 -1200 1293 43 3697 -3429 -775 -414 -195 915 -1941 1073 484 336 -1788 1209 1355 229 1394 -4474 -1799 -831 1546 4038 223 2176 -2022 1538 -1623 1404 1366 -3286 2562 -182 3012 2432 1011 -662 -777 -2439 -760 4354 -5593 2546 -419 -411 -1016 153 2706 -926 2102 -2946 2246 -2863 -419 453 -1005 3672 -2401 2536 -1138 4656 525 -1922 542 1282 1835 -3071 -2699 -171 553 5838 -2957 5872 -3873 -964 -140 697 3076 -736 1361 -1856 1353 1589 2734 -4213 460 -2030 -2972 3981 -1740 1765 -482 -3351 2511 -4655 -395 505 8062 -2635 473 3556 -4154 246 -2956 3010 -663 781 3716 -1108 -2308 715 1976 -1912 3178 98 -1277 -708 -1123 2104 -1661 -303 -4683 5286 889 -2750 789 -990 -2011 398 -90 3340 -2231 892 299 -4 -307 -2222 2344 -4616 -60 1813 3862 -132 -1993 3193 -4614 2039 -2246 3800 166 -1260 1297 43 3477 -3465 -776 -424 -204 960 -2093 1114 501 346 -1886 1248 1412 244 1486 -5076 -1980 -896 1599 3985 223 2090 -2008 1485 -1613 1391 1382 -3526 2604 -190 3056 2491 1052 -699 -817 -2573 -777 4168 -5838 2423 -409 -401 -1005 151 2613 -922 2003 -2909 2085 -2786 -399 429 -973 3422 -2398 2424 -1130 4360 500 -1882 522 1240 1782 -3132 -2712 -164 515 5030 -2722 4881 -3549 -873 -129 659 2896 -723 1303 -1822 1283 1516 2617 -4390 464 -2120 -3159 3976 -1807 1772 -492 -3475 2423 -4777 -388 493 7330 -2677 467 3403 -4289 242 -2980 2822 -638 737 3424 -1087 -2336 714 1978 -2012 3204 103 -1360 -752 -1193 2141 -1724 -305 -4873 4990 SO 20180414T040529.0Z 6678.170475 382 1 32.00 2 88.10 79.58 80.78 102.37 0.00 1 0.00 1 0 22 9.381e-03 9.347e-03 9.236e-03 9.208e-03 8.794654e+03 6.513796e+02 5.968307e+02 -6.000000e+00 5.384080e+02 281.50 -2.00 20.00 -2.00 505.39 0.00e+00 3.647657e-03 2.583034e-04 1.842536e-04 -6.000000e+00 2.667373e-04 281.50 -2.00 20.00 -2.00 500.67 0.00e+00 1.266809e+00 1.847002e-01 6.771387e-02 -6.000000e+00 1.900248e-01 228.75 -2.00 3.45 -2.00 502.24 0.00e+00 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