File name: Pandora119s1_Athens-NOA_20180504_L2Fit_fwvt1c5d20180103p1-8.txt File generation date: 20250610T122848.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v5d20180103.txt Instrument calibration file used: Pandora119s1_CF_v5d20180103.txt Level 1 file used: Pandora119s1_Athens-NOA_20180504_L1_smca1c5d20180103p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20180504 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 117 for SO2 First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0162 492.1377 492.2591 492.3806 492.5020 492.6234 492.7448 492.8662 492.9876 493.1089 493.2303 493.3516 493.4729 493.5942 493.7154 493.8367 493.9579 494.0791 494.2003 494.3215 494.4427 494.5638 494.6849 494.8061 494.9272 495.0482 495.1693 495.2904 495.4114 495.5324 495.6534 495.7744 495.8954 496.0163 496.1372 496.2582 496.3791 496.4999 496.6208 496.7416 496.8625 496.9833 497.1041 497.2249 497.3456 497.4664 497.5871 497.7078 497.8285 497.9492 498.0699 498.1905 498.3111 498.4318 498.5523 498.6729 498.7935 498.9140 499.0346 499.1551 499.2756 499.3960 499.5165 499.6370 499.7574 499.8778 499.9982 500.1186 500.2389 500.3593 500.4796 500.5999 500.7202 500.8405 500.9607 501.0810 501.2012 501.3214 501.4416 501.5618 501.6819 501.8021 501.9222 502.0423 502.1624 502.2824 502.4025 502.5225 502.6426 502.7626 502.8825 503.0025 503.1225 503.2424 503.3623 503.4822 503.6021 503.7220 503.8418 503.9617 504.0815 504.2013 504.3211 504.4408 504.5606 504.6803 504.8000 504.9197 505.0394 505.1590 505.2787 505.3983 505.5179 505.6375 505.7571 505.8767 505.9962 506.1157 506.2352 506.3547 506.4742 506.5937 506.7131 506.8325 506.9519 507.0713 507.1907 507.3101 507.4294 507.5487 507.6680 507.7873 507.9066 508.0258 508.1451 508.2643 508.3835 508.5027 508.6218 508.7410 508.8601 508.9792 509.0983 509.2174 509.3365 509.4555 509.5745 509.6936 509.8126 509.9315 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180504T033143.0Z 6698.147025 272 1 31.99 2 89.72 69.85 64.71 209.25 0.00 1 0.00 1 0 92 4.473e-01 2.895e-01 3.835e-01 3.045e-01 -3.676956e+04 1.877844e+04 3.088548e+03 -6.000000e+00 2.588155e+04 283.57 -2.00 20.00 -2.00 505.27 0.00e+00 1.432622e-02 9.163167e-03 5.887687e-04 -6.000000e+00 1.277506e-02 283.57 -2.00 20.00 -2.00 500.27 0.00e+00 1.647815e+01 6.623102e+00 1.710080e-01 -6.000000e+00 9.044374e+00 230.28 -2.00 3.45 -2.00 501.90 0.00e+00 20.076 0.138 489.00 513.00 1 9.8612e+00 5.1861e-01 3.9853e-02 -6.0000e+00 6.9537e-01 -1.2534e-01 1.2430e-01 4.8907e-03 -6.0000e+00 1.7773e-01 1.3890e-06 3.7913e-03 2.1237e-02 6.2021e-04 -6.0000e+00 5.1388e-02 1.9614e-03 9.6395e-05 12 8 8 10 0 0 26.53 21.09 22.07 0.00196 0.02826 8 2 1 4 0 4000.000 26.32 20.00 21.09 7369 43232 -4090 20651 3459 58323 20342 -6609 -16823 33016 28295 32954 73737 -10340 34584 28508 1538 4148 -18204 10125 9777 29079 28794 -31326 35985 -24621 39662 37433 3100 18980 4648 -13350 22681 49907 -14839 12635 26032 -3498 -14625 14253 -11048 84419 -40678 21080 51323 70188 -24574 6861 -56777 5518 21122 8960 26083 107600 6616 -5494 82269 25464 -986 7416 44946 16707 21441 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1.8956e-03 -6.0000e+00 9.3109e-02 2.6604e-06 -1.2100e-02 1.7188e-02 1.8698e-04 -6.0000e+00 2.6882e-02 4.1385e-02 -2.0244e-04 12 8 8 10 0 0 54.08 21.08 13.62 0.04139 -0.04255 8 2 1 4 0 4000.000 26.32 20.00 21.08 2335 26825 -15259 -512 -16141 25971 1659 11329 31065 9151 28248 -25535 20557 22405 -627 20436 -433 -23643 -13289 29431 -21339 17586 6722 29335 82355 -12642 -3836 -6856 7784 -7504 -27841 2847 11913 9212 -26483 4697 -2796 44861 6208 47568 -15687 4930 22764 6696 23314 -1884 594 17547 38178 830 4471 20044 -15884 8121 36522 15812 9720 -21868 16853 2352 -3214 16566 -121 12074 -37961 83092 -5404 11108 -7281 42302 -10400 -12578 31208 -26200 28103 -29067 18542 12630 -1535 35201 -7246 35331 -7704 29936 -13598 22809 6484 -682 19838 5074 34315 -3111 27968 -14655 11725 51708 -13656 38648 -31572 6522 -1847 12239 4596 -5908 1856 -12476 75951 -1219 9213 6394 -14215 -3972 21 38699 -16067 29413 13977 2045 -6110 -9352 -3468 -24499 18947 -6245 -16149 20674 -12890 23359 -10247 4203 4351 14192 21471 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20180504T034109.0Z 6698.153576 280 1 31.99 2 87.97 71.28 65.63 211.40 0.00 1 0.00 1 0 22 5.422e-02 5.423e-02 5.404e-02 5.347e-02 1.557980e+04 4.183693e+03 8.204596e+02 -6.000000e+00 3.137016e+03 283.58 -2.00 20.00 -2.00 505.41 0.00e+00 3.441994e-03 1.513169e-03 1.765305e-04 -6.000000e+00 1.548319e-03 283.58 -2.00 20.00 -2.00 500.59 0.00e+00 2.180208e+00 1.082877e+00 1.414296e-01 -6.000000e+00 1.096167e+00 230.28 -2.00 3.45 -2.00 502.16 0.00e+00 15.968 0.069 489.00 513.00 1 9.8051e+00 8.3122e-02 2.7482e-02 -6.0000e+00 8.4277e-02 7.5347e-03 2.0383e-02 3.2438e-03 -6.0000e+00 2.1542e-02 8.9603e-06 1.0475e-04 5.5233e-03 7.3924e-05 -6.0000e+00 6.2304e-03 5.3565e-02 -2.0995e-04 12 8 8 10 0 0 -33.06 21.07 4.77 0.05356 0.05429 8 2 1 4 0 4000.000 26.32 19.99 21.07 11432 -6601 -5176 1558 -2145 -1474 -3877 2061 -12644 8523 308 859 1363 -2468 7222 -6391 7843 -84 8658 1299 5389 5887 2587 7578 -4897 585 -3453 -288 1644 2415 8750 -7599 11511 -4629 3317 1016 440 -2952 -9108 -8570 -136 2429 -8901 7877 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