File name: Pandora119s1_Athens-NOA_20180610_L2Fit_fwvt1c5d20180103p1-8.txt File generation date: 20250610T125253.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v5d20180103.txt Instrument calibration file used: Pandora119s1_CF_v5d20180103.txt Level 1 file used: Pandora119s1_Athens-NOA_20180610_L1_smca1c5d20180103p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20180610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 117 for SO2 First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0162 492.1377 492.2591 492.3806 492.5020 492.6234 492.7448 492.8662 492.9876 493.1089 493.2303 493.3516 493.4729 493.5942 493.7154 493.8367 493.9579 494.0791 494.2003 494.3215 494.4427 494.5638 494.6849 494.8061 494.9272 495.0482 495.1693 495.2904 495.4114 495.5324 495.6534 495.7744 495.8954 496.0163 496.1372 496.2582 496.3791 496.4999 496.6208 496.7416 496.8625 496.9833 497.1041 497.2249 497.3456 497.4664 497.5871 497.7078 497.8285 497.9492 498.0699 498.1905 498.3111 498.4318 498.5523 498.6729 498.7935 498.9140 499.0346 499.1551 499.2756 499.3960 499.5165 499.6370 499.7574 499.8778 499.9982 500.1186 500.2389 500.3593 500.4796 500.5999 500.7202 500.8405 500.9607 501.0810 501.2012 501.3214 501.4416 501.5618 501.6819 501.8021 501.9222 502.0423 502.1624 502.2824 502.4025 502.5225 502.6426 502.7626 502.8825 503.0025 503.1225 503.2424 503.3623 503.4822 503.6021 503.7220 503.8418 503.9617 504.0815 504.2013 504.3211 504.4408 504.5606 504.6803 504.8000 504.9197 505.0394 505.1590 505.2787 505.3983 505.5179 505.6375 505.7571 505.8767 505.9962 506.1157 506.2352 506.3547 506.4742 506.5937 506.7131 506.8325 506.9519 507.0713 507.1907 507.3101 507.4294 507.5487 507.6680 507.7873 507.9066 508.0258 508.1451 508.2643 508.3835 508.5027 508.6218 508.7410 508.8601 508.9792 509.0983 509.2174 509.3365 509.4555 509.5745 509.6936 509.8126 509.9315 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180610T030816.0Z 6735.130741 305 1 32.00 2 89.76 60.50 63.35 104.16 0.00 1 0.00 1 0 15 4.971e-02 4.925e-02 4.022e-02 3.977e-02 8.742528e+03 2.947852e+03 4.833993e+02 -6.000000e+00 2.917778e+03 287.24 -2.00 20.00 -2.00 505.30 0.00e+00 2.405658e-03 1.124265e-03 9.880516e-05 -6.000000e+00 1.433679e-03 287.24 -2.00 20.00 -2.00 500.21 0.00e+00 1.860276e+00 8.204151e-01 7.376355e-02 -6.000000e+00 1.011153e+00 232.48 -2.00 3.45 -2.00 501.83 0.00e+00 20.008 0.137 489.00 513.00 1 8.9700e+00 6.3126e-02 3.4873e-02 -6.0000e+00 7.7724e-02 1.0306e-01 1.5765e-02 2.4270e-03 -6.0000e+00 2.0044e-02 1.2351e-05 8.0649e-03 4.2994e-03 4.5048e-05 -6.0000e+00 5.7308e-03 1.5989e-02 -2.3216e-04 12 8 8 10 0 0 -16.92 21.72 6.88 0.01599 0.07193 8 2 1 4 0 4000.000 26.83 19.99 21.72 900000 -10346 6781 -3525 -3486 -2429 1402 -1309 -2688 8188 -2249 -2569 -3003 4149 4025 -3158 10612 -1717 -2120 -1598 3712 -1968 -3763 5543 -1755 8764 -4024 2734 1376 980 3598 -498 5444 -4526 -1277 -1010 -606 -1594 -443 -5005 -211 3467 1811 6227 948 -3421 6942 -731 7645 -7863 5704 -2687 431 5020 1652 5982 -4654 2026 581 -6803 6229 752 -513 -9121 11825 -681 6398 -289 -1695 -5339 -573 6317 -4643 5025 2989 -5780 -3434 3081 6884 -13462 5636 -4615 1327 4165 -3337 6837 -1983 3274 -6468 6608 -3612 3307 2829 -3407 4156 -3196 460 3604 -1625 2911 -3525 4224 -4956 723 -2901 5246 -7472 -1329 1241 5220 -1733 -5185 8686 -1180 2977 246 4734 1502 5241 6685 -1811 9191 3525 -1899 4236 -13253 11040 -10892 -476 -2321 2634 -1361 -1919 899 2486 12705 -2843 -2014 8165 133 -1617 -8443 4018 -4598 3208 1329 -4098 -150 -5359 2944 900000 -11064 6279 -3733 -3796 -2677 1512 -1463 -2965 8236 -2413 -2725 -3156 4122 3885 -3290 10032 -1827 -2311 -1754 3886 -2186 -4267 5748 -1966 8834 -4583 2870 1433 999 3526 -511 5363 -5065 -1413 -1124 -669 -1761 -479 -5640 -227 3623 1896 6308 1021 -3852 7006 -786 7417 -8693 5367 -2696 417 4680 1630 5798 -5113 2102 613 -7727 6219 795 -550 -10625 11069 -713 6139 -292 -1715 -5544 -564 5821 -4812 4768 2900 -6069 -3468 2872 6115 -14239 5057 -4499 1228 3780 -3292 6120 -1940 3030 -6589 5921 -3611 3114 2689 -3422 3800 -3065 413 3059 -1424 2412 -3132 3553 -4728 674 -2864 4801 -7726 -1283 1166 4752 -1672 -5243 7908 -1166 2839 243 4497 1476 4925 6108 -1774 7972 3224 -1839 3875 -14483 9473 -11630 -457 -2259 2414 -1282 -1799 818 2244 10525 -2804 -2003 7438 133 -1656 -9097 3929 -4787 3146 1281 -4100 -142 -5298 2689 SO 20180610T031232.0Z 6735.133704 309 1 32.00 2 89.03 61.15 62.55 104.89 0.00 1 0.00 1 0 15 2.789e-02 2.802e-02 2.366e-02 2.348e-02 7.639616e+03 1.718720e+03 4.320065e+02 -6.000000e+00 1.637133e+03 287.24 -2.00 20.00 -2.00 505.35 0.00e+00 3.245722e-03 6.689521e-04 1.854414e-04 -6.000000e+00 8.036894e-04 287.24 -2.00 20.00 -2.00 500.33 0.00e+00 3.031922e+00 4.820345e-01 6.867450e-02 -6.000000e+00 5.638692e-01 232.48 -2.00 3.45 -2.00 501.94 0.00e+00 18.617 0.110 489.00 513.00 1 8.5202e+00 3.7107e-02 3.1388e-02 -6.0000e+00 4.3412e-02 5.4053e-02 9.2194e-03 2.1742e-03 -6.0000e+00 1.1076e-02 2.1411e-05 -4.4675e-03 2.5616e-03 7.6054e-05 -6.0000e+00 3.2051e-03 -3.7974e-02 4.0041e-04 12 8 8 10 0 0 65.04 21.72 5.53 -0.03797 -0.06896 8 2 1 4 0 4000.000 26.83 19.99 21.72 876 -117 -5380 3318 -1645 3463 794 -1679 804 -4640 468 -3548 1885 -3146 3617 409 1203 -1012 -4506 2271 840 3861 -768 1020 1690 -4967 -948 275 5960 989 -1728 -2428 728 3026 -4569 3530 -567 3818 2885 -612 1382 -3025 1994 -3622 3408 445 1340 -461 -4380 4948 -2306 1625 1235 1313 1605 -1552 -3518 -2452 797 -3124 1451 1957 2819 -201 414 1372 -4921 8911 -4449 4501 2330 -2133 3714 -912 1842 -3891 859 -870 -401 60 -7239 4638 1056 5028 206 -1006 1777 -2500 2051 -1453 6213 -2851 3072 1708 -4814 -324 -1355 643 -909 2952 1124 840 1325 -2131 1059 1171 -26 466 -1819 -2920 2918 705 -6070 4819 -4852 2714 402 -150 -1548 1553 3500 -2776 2645 967 100 -3798 -1846 -550 -1486 2936 490 248 706 -1622 2684 -681 2763 1695 1558 2012 -1247 183 -1361 3781 -2616 2131 -2154 -3250 -333 -3185 806 -110 -5415 3160 -1698 3483 837 -1836 861 -5212 493 -3839 1905 -3304 3525 412 1216 -1039 -4895 2344 887 3969 -829 1085 1796 -5660 -1035 294 5904 1004 -1769 -2495 736 3066 -5128 3706 -621 3968 2999 -655 1449 -3334 2112 -4008 3640 480 1429 -495 -4815 4966 -2367 1567 1182 1260 1566 -1603 -3791 -2649 837 -3416 1516 2041 2921 -214 435 1412 -5310 8246 -4641 4241 2225 -2129 3516 -912 1800 -4009 833 -845 -382 57 -7341 4193 996 4591 194 -965 1661 -2434 1904 -1398 5568 -2825 2893 1629 -4839 -305 -1254 568 -797 2451 948 722 1167 -2010 992 1107 -25 439 -1748 -2853 2725 683 -6226 4583 -5003 2614 399 -150 -1567 1508 3285 -2740 2461 917 96 -3816 -1824 -537 -1464 2760 469 235 659 -1542 2454 -653 2611 1649 1542 2007 -1297 189 -1436 3797 -2730 2102 -2183 -3273 -323 -3173 SO 20180610T031642.0Z 6735.136597 313 1 32.00 2 88.31 61.78 61.76 105.62 0.00 1 0.00 1 0 22 1.180e-02 1.177e-02 1.123e-02 1.118e-02 1.381277e+04 8.639640e+02 9.758153e+02 -6.000000e+00 6.924588e+02 287.24 -2.00 20.00 -2.00 505.39 0.00e+00 2.804333e-03 3.177303e-04 1.485308e-04 -6.000000e+00 3.402823e-04 287.24 -2.00 20.00 -2.00 500.54 0.00e+00 1.792672e+00 2.264935e-01 7.181406e-02 -6.000000e+00 2.400681e-01 232.48 -2.00 3.45 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