File name: Pandora119s1_Athens-NOA_20180725_L2Fit_fwvt1c5d20180103p1-8.txt File generation date: 20250610T132128.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v5d20180103.txt Level 1 file used: Pandora119s1_Athens-NOA_20180725_L1_smca1c5d20180103p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20180725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 117 for SO2 First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0162 492.1377 492.2591 492.3806 492.5020 492.6234 492.7448 492.8662 492.9876 493.1089 493.2303 493.3516 493.4729 493.5942 493.7154 493.8367 493.9579 494.0791 494.2003 494.3215 494.4427 494.5638 494.6849 494.8061 494.9272 495.0482 495.1693 495.2904 495.4114 495.5324 495.6534 495.7744 495.8954 496.0163 496.1372 496.2582 496.3791 496.4999 496.6208 496.7416 496.8625 496.9833 497.1041 497.2249 497.3456 497.4664 497.5871 497.7078 497.8285 497.9492 498.0699 498.1905 498.3111 498.4318 498.5523 498.6729 498.7935 498.9140 499.0346 499.1551 499.2756 499.3960 499.5165 499.6370 499.7574 499.8778 499.9982 500.1186 500.2389 500.3593 500.4796 500.5999 500.7202 500.8405 500.9607 501.0810 501.2012 501.3214 501.4416 501.5618 501.6819 501.8021 501.9222 502.0423 502.1624 502.2824 502.4025 502.5225 502.6426 502.7626 502.8825 503.0025 503.1225 503.2424 503.3623 503.4822 503.6021 503.7220 503.8418 503.9617 504.0815 504.2013 504.3211 504.4408 504.5606 504.6803 504.8000 504.9197 505.0394 505.1590 505.2787 505.3983 505.5179 505.6375 505.7571 505.8767 505.9962 506.1157 506.2352 506.3547 506.4742 506.5937 506.7131 506.8325 506.9519 507.0713 507.1907 507.3101 507.4294 507.5487 507.6680 507.7873 507.9066 508.0258 508.1451 508.2643 508.3835 508.5027 508.6218 508.7410 508.8601 508.9792 509.0983 509.2174 509.3365 509.4555 509.5745 509.6936 509.8126 509.9315 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180725T032800.0Z 6780.144444 302 1 32.00 2 89.76 64.93 115.26 262.32 0.00 1 0.00 1 0 29 7.500e-02 7.240e-02 6.784e-02 6.675e-02 1.039385e+04 5.089126e+03 3.638996e+02 -6.000000e+00 4.459375e+03 290.72 -2.00 20.00 -2.00 505.30 0.00e+00 3.533015e-03 1.910674e-03 2.102075e-04 -6.000000e+00 2.182360e-03 290.72 -2.00 20.00 -2.00 500.20 0.00e+00 1.763896e+00 1.391876e+00 1.029132e-01 -6.000000e+00 1.521741e+00 232.25 -2.00 3.45 -2.00 501.83 0.00e+00 19.908 0.135 489.00 513.00 1 9.5048e+00 1.0727e-01 3.5328e-02 -6.0000e+00 1.1714e-01 1.0497e-01 2.7020e-02 2.6203e-03 -6.0000e+00 3.0164e-02 7.2084e-06 -1.0611e-02 7.2049e-03 8.8089e-05 -6.0000e+00 8.6487e-03 -5.0563e-02 1.8624e-04 12 9 8 11 8 0 54.97 21.90 4.53 -0.05056 -0.12417 8 2 1 4 0 4000.000 26.94 20.00 21.90 900000 -2375 -1034 4667 -8541 2687 -10615 5214 -1639 4752 4514 6681 7828 4283 -4089 -3672 -9 -6066 -11648 -164 342 -2662 -8509 6990 -3289 -2074 9296 3029 5040 6102 3103 -8996 -5705 2981 8482 -2597 -8552 7015 171 16531 -5720 8129 -8012 1797 -2413 2947 12788 -4810 -1853 -3976 3688 6480 -225 -3337 26115 10528 -742 10478 8264 6891 6262 4760 3310 -3337 -1027 433 -11068 -8442 8193 -6407 -6766 -4535 -11997 7914 -4775 -6393 -5921 6521 12631 -3814 -3693 -3318 -2694 9056 -6159 10296 1066 7195 -10146 8793 11569 -491 6334 -1383 10730 -7941 -9520 10224 367 888 7874 7596 -16464 4969 7900 1393 -557 5682 -12116 -2044 1979 4496 1821 -4346 -7307 1202 8892 17127 5647 6600 -7524 8407 8199 -1915 1333 -1217 965 -2639 -1048 14308 -15600 4045 -10843 -3219 954 1634 -2566 -11185 8967 3489 21048 -5846 870 6108 -7223 11031 336 -4818 702 -8268 900000 -2347 -1018 4454 -9348 2705 -12495 5329 -1811 4923 4645 6633 7571 4231 -4342 -3861 -9 -6639 -13751 -176 370 -2986 -10148 7157 -3747 -2344 9390 3243 5221 6121 3129 -10078 -6195 3022 8364 -2852 -10066 7231 182 15220 -6378 7906 -9229 1898 -2691 3143 12393 -5533 -2045 -4400 3691 6150 -223 -3396 19968 9621 -779 10032 8175 6933 6342 4901 3469 -3743 -1122 463 -12756 -9329 7748 -6919 -7068 -4604 -13140 7338 -4942 -6741 -6166 5906 10865 -3729 -3586 -3211 -2603 7832 -6252 8938 1019 6469 -10815 7734 9910 -478 5809 -1377 9402 -8230 -9758 8357 323 759 6204 6023 -16957 4273 6832 1316 -541 5165 -12754 -1943 1821 4087 1723 -4415 -7704 1171 8084 14450 5359 6169 -7992 7496 7232 -1860 1256 -1182 920 -2614 -1022 11935 -17467 3684 -11311 -3081 873 1496 -2489 -11755 8023 3345 17121 -6125 858 5734 -7749 9807 329 -4876 661 -8444 SO 20180725T033222.0Z 6780.147477 306 1 32.00 2 88.97 65.59 116.08 262.92 0.00 1 0.00 1 0 22 5.408e-02 5.389e-02 4.166e-02 4.120e-02 9.589225e+03 3.086594e+03 7.527048e+02 -6.000000e+00 3.215145e+03 290.72 -2.00 20.00 -2.00 505.30 0.00e+00 2.858802e-03 1.176355e-03 1.432317e-04 -6.000000e+00 1.572628e-03 290.72 -2.00 20.00 -2.00 500.24 0.00e+00 1.569007e+00 8.402166e-01 4.171318e-02 -6.000000e+00 1.092642e+00 232.25 -2.00 3.45 -2.00 501.86 0.00e+00 18.420 0.107 489.00 513.00 1 9.2412e+00 6.4681e-02 3.0536e-02 -6.0000e+00 8.4210e-02 9.1765e-02 1.6211e-02 2.0296e-03 -6.0000e+00 2.1517e-02 1.1900e-05 -2.9379e-05 4.4507e-03 8.0282e-05 -6.0000e+00 6.2161e-03 8.0176e-03 -4.1590e-05 12 9 8 11 8 0 64.95 21.90 1.07 0.00802 0.00781 8 2 1 4 0 4000.000 26.94 20.00 21.90 928 4629 -3719 -7189 4262 -3257 5498 -7925 5943 6139 4305 8357 282 -5022 -6188 -2838 -380 4023 -4184 -4657 10448 -1590 9285 -6161 9650 -5094 1609 5463 -5458 12482 -5700 1786 5965 1404 265 -5627 1025 -7072 5385 1438 11059 -1587 2859 -2069 -6072 -4445 -11085 6724 -4976 622 3031 -1437 -244 -2983 2643 1873 5267 1632 3116 7794 2580 3979 -6462 739 -7267 1543 302 1200 4620 -8399 3905 148 5034 -2813 -1965 2976 1266 3492 -6571 11941 -8672 -419 8157 -6097 6845 -6665 -305 -629 3297 -982 3770 1576 -7759 9347 -1057 4587 3107 -2261 5093 -7048 2233 -12555 5267 1930 2186 2384 -9765 -2560 -1256 5095 -1790 5787 1762 933 6451 -2202 3219 545 407 -5716 -1391 4746 -6370 -466 -3498 11356 7042 9088 3680 -8555 -3262 -6894 -735 -1067 7037 1150 -2837 1766 -3286 7503 -2224 6778 -2242 2113 2590 -4200 7690 -3355 7838 -10235 872 4215 -3769 -7783 4238 -3578 5637 -9396 6143 6287 4431 8142 294 -5308 -6572 -2920 -386 3985 -4595 -5216 10134 -1745 9160 -7117 9560 -5858 1724 5570 -6085 11344 -6101 1771 5761 1458 285 -6507 1108 -8221 5474 1511 10555 -1730 3012 -2260 -6968 -5038 -13381 6891 -5494 634 2942 -1427 -237 -2992 2558 1875 5209 1695 3202 7647 2669 4072 -7357 782 -8266 1587 309 1201 4411 -9028 3685 145 4730 -2885 -2007 2877 1228 3260 -6705 10063 -8980 -401 7220 -6123 6245 -6832 -294 -606 3049 -948 3493 1507 -8198 8293 -1024 4097 2738 -2046 4188 -6454 1865 -12375 4486 1761 2043 2247 -10365 -2510 -1212 4641 -1768 5368 1719 925 6092 -2229 3109 543 404 -5961 -1368 4330 -6453 -445 -3463 9725 6309 7975 3403 -8906 -3191 -6905 -685 -993 6068 1067 -2790 1687 -3351 6953 -2291 6424 -2336 2110 2564 -4302 7044 -3295 6969 -10656 SO 20180725T033634.0Z 6780.150394 310 1 32.00 2 88.22 66.23 116.87 263.50 0.00 1 0.00 1 0 15 2.357e-02 2.373e-02 1.829e-02 1.818e-02 1.628187e+04 1.455453e+03 9.747243e+02 -6.000000e+00 1.401484e+03 290.72 -2.00 20.00 -2.00 505.40 0.00e+00 4.116761e-03 5.238604e-04 2.140414e-04 -6.000000e+00 6.854354e-04 290.72 -2.00 20.00 -2.00 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