File name: Pandora119s1_Athens-NOA_20180913_L2Fit_fwvt1c5d20180103p1-8.txt File generation date: 20250610T135051.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v5d20180103.txt Level 1 file used: Pandora119s1_Athens-NOA_20180913_L1_smca1c5d20180103p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20180913 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 117 for SO2 First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0162 492.1377 492.2591 492.3806 492.5020 492.6234 492.7448 492.8662 492.9876 493.1089 493.2303 493.3516 493.4729 493.5942 493.7154 493.8367 493.9579 494.0791 494.2003 494.3215 494.4427 494.5638 494.6849 494.8061 494.9272 495.0482 495.1693 495.2904 495.4114 495.5324 495.6534 495.7744 495.8954 496.0163 496.1372 496.2582 496.3791 496.4999 496.6208 496.7416 496.8625 496.9833 497.1041 497.2249 497.3456 497.4664 497.5871 497.7078 497.8285 497.9492 498.0699 498.1905 498.3111 498.4318 498.5523 498.6729 498.7935 498.9140 499.0346 499.1551 499.2756 499.3960 499.5165 499.6370 499.7574 499.8778 499.9982 500.1186 500.2389 500.3593 500.4796 500.5999 500.7202 500.8405 500.9607 501.0810 501.2012 501.3214 501.4416 501.5618 501.6819 501.8021 501.9222 502.0423 502.1624 502.2824 502.4025 502.5225 502.6426 502.7626 502.8825 503.0025 503.1225 503.2424 503.3623 503.4822 503.6021 503.7220 503.8418 503.9617 504.0815 504.2013 504.3211 504.4408 504.5606 504.6803 504.8000 504.9197 505.0394 505.1590 505.2787 505.3983 505.5179 505.6375 505.7571 505.8767 505.9962 506.1157 506.2352 506.3547 506.4742 506.5937 506.7131 506.8325 506.9519 507.0713 507.1907 507.3101 507.4294 507.5487 507.6680 507.7873 507.9066 508.0258 508.1451 508.2643 508.3835 508.5027 508.6218 508.7410 508.8601 508.9792 509.0983 509.2174 509.3365 509.4555 509.5745 509.6936 509.8126 509.9315 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180913T041021.1Z 6830.173855 397 1 32.12 2 89.74 85.35 131.86 64.43 0.00 1 0.00 1 0 15 6.382e-02 6.209e-02 5.403e-02 5.327e-02 6.822806e+03 3.815480e+03 2.447746e+02 -6.000000e+00 3.772045e+03 289.27 -2.00 20.00 -2.00 505.29 0.00e+00 1.995709e-03 1.523442e-03 8.735221e-05 -6.000000e+00 1.848466e-03 289.27 -2.00 20.00 -2.00 500.19 0.00e+00 1.726583e+00 1.088477e+00 8.698525e-02 -6.000000e+00 1.282523e+00 229.45 -2.00 3.45 -2.00 501.83 0.00e+00 19.942 0.136 489.00 513.00 1 9.3200e+00 8.4053e-02 3.4806e-02 -6.0000e+00 9.8863e-02 1.1342e-01 2.0951e-02 2.4255e-03 -6.0000e+00 2.5173e-02 8.9412e-06 -1.7121e-03 5.8105e-03 3.2132e-05 -6.0000e+00 7.3373e-03 7.1866e-02 -2.1028e-04 12 8 8 10 0 0 -58.53 21.32 4.75 0.07187 0.05999 8 2 1 4 0 4000.000 26.51 19.99 21.32 2512 -2461 -4876 -2286 -1165 -6600 4937 -3990 4619 -4188 -3845 -115 6016 7167 -15420 9535 -4655 6451 -43 3175 3126 -2332 5004 -2620 3273 7657 -2940 -6975 -1308 1515 -253 -3380 -1016 3935 -3930 -1238 3480 -6872 15172 -7747 5631 3421 2018 1218 -1647 1298 -5689 4593 6382 11314 4902 7524 814 3474 14464 -2965 375 -3581 1986 3637 -3483 4678 -7662 3844 -4276 -717 273 -2856 12116 -3996 4329 112 -2034 -1303 -6628 2614 -14893 5385 -2220 8087 -280 11109 8056 -9509 10966 -8624 2941 -6811 4100 12858 2210 515 -6307 5246 -5716 509 -4151 967 -826 -8488 8012 -4584 4350 -1564 16273 -9511 -1923 15034 -7580 8105 -2821 2292 1488 6160 12985 -1093 14597 -9619 -7329 5369 -1799 318 -4076 2898 -2799 5045 6234 10425 3846 -1315 4156 -10236 7205 -6878 243 -3408 -4611 -6030 -6456 8504 -4362 -1229 -1172 7360 6869 2642 2439 -2292 4613 -13656 2329 -2424 -5050 -2380 -1233 -7552 5120 -4565 4847 -4758 -4294 -122 5917 6891 -18491 8946 -5102 6460 -46 3397 3366 -2591 5313 -2935 3469 7768 -3297 -8037 -1393 1530 -256 -3542 -1059 4013 -4434 -1372 3666 -7956 13950 -8906 5668 3544 2142 1317 -1847 1416 -6616 4758 6372 10494 4723 6919 794 3329 12699 -3178 396 -3879 2039 3673 -3782 4694 -8708 3883 -4643 -741 275 -2926 10546 -4042 4005 108 -2026 -1299 -6989 2494 -16675 4849 -2135 6986 -263 9379 7065 -10026 9502 -9138 2779 -7083 3820 11006 2120 507 -6528 4936 -5763 471 -3922 867 -738 -7900 6503 -4202 3766 -1484 13176 -10014 -1866 12211 -7701 7089 -2787 2180 1441 5740 11373 -1109 12729 -10690 -7903 5031 -1785 305 -4073 2708 -2780 4644 5674 9092 3574 -1251 3703 -10393 6228 -6659 220 -3257 -4544 -6130 -6684 7662 -4505 -1237 -1184 6833 6377 2528 2297 -2225 4139 -14748 SO 20180913T041437.0Z 6830.176817 401 1 32.00 2 88.90 86.01 131.14 65.37 0.00 1 0.00 1 0 15 3.957e-02 3.918e-02 3.219e-02 3.190e-02 7.593418e+03 2.335910e+03 5.112672e+02 -6.000000e+00 2.338685e+03 289.27 -2.00 20.00 -2.00 505.31 0.00e+00 2.511382e-03 9.138773e-04 1.063461e-04 -6.000000e+00 1.146706e-03 289.27 -2.00 20.00 -2.00 500.24 0.00e+00 2.151552e+00 6.544503e-01 4.993669e-02 -6.000000e+00 7.968800e-01 229.45 -2.00 3.45 -2.00 501.87 0.00e+00 18.288 0.104 489.00 513.00 1 8.9809e+00 5.0473e-02 3.0165e-02 -6.0000e+00 6.1406e-02 8.1738e-02 1.2556e-02 2.0058e-03 -6.0000e+00 1.5675e-02 1.5258e-05 -1.4236e-03 3.4633e-03 5.6001e-05 -6.0000e+00 4.5474e-03 7.4810e-03 1.1170e-05 12 8 8 10 0 0 -99.79 21.31 4.29 0.00748 -0.00239 8 2 1 4 0 4000.000 26.51 20.00 21.31 -8217 -4686 1064 -750 1744 -8594 3565 -1248 5236 -4055 -716 3086 -4536 5261 -113 2635 -667 4190 -172 -1159 3013 2349 1027 -4991 6171 586 -2587 4356 -4067 214 -5109 1306 4490 596 2344 -6898 2716 -3231 8500 555 1043 2993 -3519 766 -4711 1853 58 1270 1247 3513 -387 1607 7459 -3445 3587 -615 -2005 2944 -1887 4816 -6217 10522 1669 -3474 -1369 -2860 3318 -1644 2190 -4861 1691 3305 823 2503 -5609 -1096 -1242 4795 1376 -615 3199 -10273 9980 -823 2195 1027 -406 -1195 -591 2509 -3848 4177 -1984 5524 2289 -2683 3244 -4714 8844 -4020 2203 -267 -3803 2305 -3227 1495 -1445 6184 -549 6036 -2875 -5012 1480 735 962 -6014 3383 414 -3351 3129 -3044 -546 -4104 3667 4350 9657 714 2192 8351 -7358 5099 -6717 283 -275 2185 1348 -1886 -2352 -6742 193 2040 1874 3490 -782 986 -4019 -692 -6073 1162 285 -8325 -4608 1038 -749 1750 -9802 3669 -1364 5371 -4534 -764 3127 -4889 5081 -114 2600 -688 4198 -184 -1271 3192 2514 1117 -5781 6420 645 -2932 4556 -4537 223 -5377 1320 4463 617 2444 -7989 2855 -3576 8284 582 1087 3078 -3902 823 -5397 1996 64 1356 1309 3522 -393 1565 6773 -3505 3470 -637 -2151 3044 -2056 4908 -6906 10164 1765 -3767 -1442 -3020 3243 -1663 2104 -4951 1602 3080 792 2387 -5829 -1083 -1212 4335 1273 -577 2888 -10660 8515 -789 2059 980 -394 -1166 -572 2359 -3878 3923 -1997 5147 2173 -2616 2903 -4450 7127 -3632 1869 -236 -3593 2120 -3137 1398 -1388 5459 -517 5346 -2818 -5088 1424 719 945 -6378 3288 416 -3476 3007 -3065 -529 -4102 3397 4021 8496 688 2082 7445 -7472 4641 -6636 264 -257 1999 1232 -1814 -2314 -7033 190 1990 1843 3395 -796 982 -4166 -682 -6212 1093 271 SO 20180913T041843.0Z 6830.179664 405 1 32.01 2 88.09 86.64 130.44 66.26 0.00 1 0.00 1 0 15 1.176e-02 1.174e-02 1.019e-02 1.015e-02 1.212435e+04 7.691387e+02 7.148465e+02 -6.000000e+00 6.952335e+02 289.27 -2.00 20.00 -2.00 505.39 0.00e+00 3.320563e-03 2.915311e-04 1.687346e-04 -6.000000e+00 3.409809e-04 289.27 -2.00 20.00 -2.00 500.57 0.00e+00 2.065268e+00 2.035789e-01 9.475853e-02 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