File name: Pandora119s1_Athens-NOA_20180925_L2Fit_fwvt1c5d20180103p1-8.txt File generation date: 20250610T135201.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v5d20180103.txt Level 1 file used: Pandora119s1_Athens-NOA_20180925_L1_smca1c5d20180103p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20180925 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update session 117 for SO2 First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0162 492.1377 492.2591 492.3806 492.5020 492.6234 492.7448 492.8662 492.9876 493.1089 493.2303 493.3516 493.4729 493.5942 493.7154 493.8367 493.9579 494.0791 494.2003 494.3215 494.4427 494.5638 494.6849 494.8061 494.9272 495.0482 495.1693 495.2904 495.4114 495.5324 495.6534 495.7744 495.8954 496.0163 496.1372 496.2582 496.3791 496.4999 496.6208 496.7416 496.8625 496.9833 497.1041 497.2249 497.3456 497.4664 497.5871 497.7078 497.8285 497.9492 498.0699 498.1905 498.3111 498.4318 498.5523 498.6729 498.7935 498.9140 499.0346 499.1551 499.2756 499.3960 499.5165 499.6370 499.7574 499.8778 499.9982 500.1186 500.2389 500.3593 500.4796 500.5999 500.7202 500.8405 500.9607 501.0810 501.2012 501.3214 501.4416 501.5618 501.6819 501.8021 501.9222 502.0423 502.1624 502.2824 502.4025 502.5225 502.6426 502.7626 502.8825 503.0025 503.1225 503.2424 503.3623 503.4822 503.6021 503.7220 503.8418 503.9617 504.0815 504.2013 504.3211 504.4408 504.5606 504.6803 504.8000 504.9197 505.0394 505.1590 505.2787 505.3983 505.5179 505.6375 505.7571 505.8767 505.9962 506.1157 506.2352 506.3547 506.4742 506.5937 506.7131 506.8325 506.9519 507.0713 507.1907 507.3101 507.4294 507.5487 507.6680 507.7873 507.9066 508.0258 508.1451 508.2643 508.3835 508.5027 508.6218 508.7410 508.8601 508.9792 509.0983 509.2174 509.3365 509.4555 509.5745 509.6936 509.8126 509.9315 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180925T042039.0Z 6842.181007 316 1 32.00 2 89.73 91.25 91.61 266.89 0.00 1 0.00 1 0 15 7.980e-02 7.826e-02 5.812e-02 5.717e-02 1.182739e+04 4.353711e+03 5.365834e+02 -6.000000e+00 4.693801e+03 288.02 -2.00 20.00 -2.00 505.34 0.00e+00 2.927025e-03 1.617411e-03 2.071415e-04 -6.000000e+00 2.306559e-03 288.02 -2.00 20.00 -2.00 500.31 0.00e+00 1.299441e+00 1.166324e+00 1.245974e-01 -6.000000e+00 1.609030e+00 228.33 -2.00 3.45 -2.00 501.93 0.00e+00 19.973 0.136 489.00 513.00 1 9.4020e+00 8.9656e-02 3.5884e-02 -6.0000e+00 1.2389e-01 9.5285e-02 2.2294e-02 3.0008e-03 -6.0000e+00 3.1711e-02 8.2543e-06 3.2687e-03 6.1098e-03 7.8603e-05 -6.0000e+00 9.1645e-03 1.6587e-02 -2.0750e-04 12 9 8 11 8 0 51.82 21.34 7.59 0.01659 0.03926 8 2 1 4 0 4000.000 26.51 20.00 21.34 2917 -20 5826 -506 -3326 6809 -19640 6870 -3216 1614 4300 1258 14547 -14884 9650 -15992 2167 -4891 5074 9036 -5770 1019 -1155 4850 -4372 3941 937 3536 1937 -4951 10057 -6418 2248 -400 -1599 790 -1614 5948 -9700 15776 4527 218 8511 -1073 14543 -3840 8105 6151 5997 9912 -3987 14508 -8958 -4902 -4679 7033 -9184 1478 4357 -5739 620 -3339 22924 -3132 2202 -3457 6918 3138 -17294 5118 -7661 6832 -7239 3093 -2129 -6886 10483 -2366 11631 -2985 6188 -1214 1122 19960 -9177 10259 -9932 6329 5271 -1527 5770 -13745 12002 -1923 2188 5005 -6366 931 -11202 8556 -1933 16304 3774 -2386 -724 -2750 -3558 -8979 19298 -9623 3494 14487 -3011 7465 -405 13178 -10630 13783 556 7297 4091 -7420 -7956 -3992 2843 -292 9968 -2270 10401 2281 -7119 5187 -12906 10695 -1642 5374 -373 -5986 6929 -2216 -4593 4185 6693 -5770 -2458 1457 -13059 -1792 -3588 14725 2627 -19 5265 -503 -3501 6635 -25392 6887 -3570 1694 4336 1289 12867 -17466 8806 -18907 2163 -5343 5124 8898 -6635 1098 -1276 5062 -4898 4177 993 3706 1970 -5262 9281 -6803 2222 -417 -1730 845 -1765 5980 -11299 14163 4552 231 8374 -1176 13766 -4384 8184 6264 6012 9340 -4210 12462 -9637 -5098 -4960 6809 -10418 1564 4500 -6398 649 -3652 19822 -3421 2264 -3714 6598 3063 -20441 4780 -8079 6238 -7664 2980 -2171 -7320 9234 -2333 9855 -2909 5503 -1168 1063 15793 -9806 9080 -10766 5815 4879 -1514 5349 -15249 10606 -1942 2080 4500 -6071 822 -10668 6770 -1702 12215 3319 -2262 -694 -2724 -3549 -9397 15187 -10177 3279 12331 -3082 6925 -409 11703 -12084 12335 566 6859 3907 -7836 -8392 -4053 2707 -288 8893 -2289 9223 2185 -7244 4720 -13599 9089 -1551 4802 -360 -6212 6414 -2276 -4876 4097 6419 -6272 -2574 1452 -14805 -1785 -3603 12334 SO 20180925T042451.0Z 6842.183924 320 1 32.00 2 88.91 91.90 92.40 267.53 0.00 1 0.00 1 0 22 2.789e-02 2.759e-02 3.174e-02 3.155e-02 8.927561e+03 2.322075e+03 7.392633e+02 -6.000000e+00 1.640396e+03 288.02 -2.00 20.00 -2.00 505.34 0.00e+00 1.910604e-03 8.978555e-04 9.285148e-05 -6.000000e+00 8.064977e-04 288.02 -2.00 20.00 -2.00 500.41 0.00e+00 2.108833e+00 6.420068e-01 2.874762e-02 -6.000000e+00 5.644430e-01 228.33 -2.00 3.45 -2.00 502.01 0.00e+00 18.333 0.105 489.00 513.00 1 8.9805e+00 4.9314e-02 3.0083e-02 -6.0000e+00 4.3414e-02 5.9861e-02 1.2357e-02 1.9171e-03 -6.0000e+00 1.1194e-02 1.5341e-05 4.9675e-03 3.4107e-03 8.8225e-05 -6.0000e+00 3.2152e-03 -5.2023e-03 -1.6316e-04 12 8 8 10 0 0 78.24 21.33 2.60 -0.00520 0.02925 8 2 1 4 0 4000.000 26.51 19.99 21.33 900000 -1519 5035 1151 -802 2549 158 -792 -4677 2181 1647 3278 -2469 -1573 -4784 -997 -917 3973 2460 284 -1446 -657 869 -2041 357 1181 63 1934 -35 3098 -1454 610 -4183 415 5122 5523 860 -2096 -1467 19 3103 5723 -3763 -1001 1934 -3314 -1951 -511 1200 -59 -2245 -1527 -7421 -3993 -4776 13 1721 1520 4243 850 1020 -190 -3044 229 -1306 3456 1405 3983 -2868 448 1684 3213 1781 3031 -2069 -3802 -1931 -527 3296 4928 -2704 -274 -2759 833 -6797 5587 -2599 3514 3191 31 -1196 4130 -3359 -971 7477 2131 1764 -737 -2321 -186 2176 -1172 -4449 3455 -3339 -2078 -4256 -1746 3485 3333 -1280 386 1052 -2870 -4136 -1137 793 1974 -1332 1723 3484 3198 -2419 -1847 -2856 4408 4936 -2960 80 350 -2937 114 1419 1152 -745 95 -61 5251 1401 1370 -1902 2124 3602 -1053 -1434 -1985 529 -995 -3243 1247 900000 -1445 4599 1100 -804 2535 164 -839 -5166 2235 1676 3236 -2547 -1590 -4966 -1000 -931 3917 2517 301 -1574 -713 930 -2258 388 1273 68 2039 -37 3088 -1491 613 -4367 425 5133 5581 910 -2266 -1561 20 3134 5664 -4137 -1083 2051 -3716 -2149 -549 1245 -61 -2297 -1517 -7741 -4048 -4981 13 1765 1581 4311 894 1072 -203 -3268 243 -1365 3487 1390 3880 -2882 431 1588 2986 1692 2870 -2071 -3852 -1894 -502 2986 4368 -2589 -257 -2677 787 -6994 5113 -2586 3284 2988 30 -1179 3898 -3438 -967 6735 1976 1597 -666 -2086 -162 1849 -1050 -4256 3167 -3283 -2038 -4256 -1691 3193 3076 -1252 376 1029 -2942 -4322 -1162 801 1977 -1373 1703 3333 3028 -2410 -1833 -2877 4145 4628 -3003 79 342 -2941 109 1331 1079 -698 90 -59 4891 1377 1365 -1977 2135 3588 -1101 -1500 -2069 529 -994 -3280 1207 SO 20180925T042857.0Z 6842.186771 324 1 32.01 2 88.10 92.53 93.17 268.15 0.00 1 0.00 1 0 22 1.694e-02 1.694e-02 1.743e-02 1.735e-02 1.018959e+04 1.293341e+03 6.978788e+02 -6.000000e+00 9.963139e+02 288.02 -2.00 20.00 -2.00 505.34 0.00e+00 4.407445e-03 4.949177e-04 2.292087e-04 -6.000000e+00 4.894985e-04 288.02 -2.00 20.00 -2.00 500.42 0.00e+00 1.752767e+00 3.523287e-01 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