File name: Pandora119s1_Athens-NOA_20181221_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T141800.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20181221_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20181221 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181221T054327.0Z 6929.238507 326 1 32.01 2 89.75 120.53 108.85 311.56 0.00 1 0.00 1 0 15 9.810e-02 9.448e-02 8.946e-02 8.746e-02 3.644437e+03 5.741846e+03 6.582419e+02 -6.000000e+00 5.559943e+03 278.59 -2.00 20.00 -2.00 505.35 0.00e+00 -2.022920e-03 2.437130e-03 1.856908e-04 -6.000000e+00 2.769625e-03 278.59 -2.00 20.00 -2.00 500.24 0.00e+00 1.178909e+00 1.776873e+00 5.116817e-02 -6.000000e+00 1.974810e+00 223.41 -2.00 3.45 -2.00 501.90 0.00e+00 20.259 0.142 489.00 513.00 1 9.9380e+00 1.3623e-01 3.5366e-02 -6.0000e+00 1.5163e-01 1.1529e-01 3.4662e-02 1.9327e-03 -6.0000e+00 3.8835e-02 5.0935e-06 -5.8917e-03 9.5915e-03 1.3121e-04 -6.0000e+00 1.1268e-02 1.1340e-01 -8.1936e-04 12 8 8 10 0 0 84.45 18.86 7.04 0.11340 0.07253 8 2 1 4 0 4000.000 24.46 20.00 18.86 -2282 -7502 3229 -2334 -3353 -12120 -4874 7376 -5313 2045 -8815 8589 2458 12692 3510 3362 -4593 -8539 -5976 1010 4375 8535 5658 -5587 13675 6742 -2033 21814 -10839 -13240 -1357 3446 3039 -7111 6853 -3854 5982 3934 -1128 1405 7948 -5166 -16943 6750 2094 4515 3081 -7119 20997 1485 1258 -17063 7095 -2642 5251 28519 -5105 9083 -8225 602 -3040 89 12773 4816 -4915 -802 17109 -7914 2815 -3522 -1367 12682 -1839 25198 -4776 15950 404 1452 12710 11894 7864 -4951 11748 -9595 -5952 -13283 -11290 12572 3438 13854 -6607 11427 1031 2911 18560 4999 16900 -6204 6245 -6683 -2835 10496 9006 18739 -14790 5231 -1783 -4438 14581 -4514 3176 -2211 21044 -15516 15346 -13382 -7689 5575 -2882 7532 576 -1183 -9548 5545 18043 809 -25225 -14689 889 1014 5057 5488 -14018 8487 -14729 2786 9172 18916 97 10765 6266 -7594 13302 -11780 7540 -4211 -7237 8475 -1059 8320 -2215 -7680 3029 -2384 -3565 -14429 -5509 7483 -6153 2193 -10158 8435 2534 11671 3512 3372 -4909 -9686 -6766 1087 4598 8642 5907 -6539 13230 6994 -2292 19185 -12980 -15854 -1414 3404 3050 -8098 6970 -4433 6246 4161 -1241 1492 7869 -5837 -21108 6866 2248 4745 3273 -8072 18135 1524 1259 -19496 6432 -2572 4926 21738 -5429 8502 -9199 616 -3226 91 11620 4741 -5303 -822 14436 -8451 2666 -3513 -1325 10673 -1802 19046 -4911 13318 389 1366 10556 9905 6825 -4917 9964 -9929 -6006 -14571 -12214 11023 3226 12055 -6922 10087 1018 2825 15660 4627 13925 -6127 5325 -6385 -2599 8545 7660 14975 -16984 4976 -1815 -4592 12370 -4632 3041 -2259 17222 -17999 13480 -15356 -8373 5459 -2982 7117 561 -1157 -10078 5030 14844 773 -31266 -16364 845 960 4567 4875 -14943 7166 -15701 2521 7937 15142 95 9630 5920 -8301 11872 -13567 7155 -4462 -7790 7653 -1036 7373 SO 20181221T054731.0Z 6929.241331 330 1 32.01 2 89.07 121.16 109.42 312.34 0.00 1 0.00 1 0 29 6.642e-02 6.435e-02 6.089e-02 6.006e-02 8.586289e+03 4.302363e+03 1.050433e+02 -6.000000e+00 3.765492e+03 278.59 -2.00 20.00 -2.00 505.31 0.00e+00 -6.061878e-04 1.676391e-03 9.907851e-05 -6.000000e+00 1.875391e-03 278.59 -2.00 20.00 -2.00 500.24 0.00e+00 1.654996e+00 1.224293e+00 1.554224e-01 -6.000000e+00 1.335662e+00 223.41 -2.00 3.45 -2.00 501.88 0.00e+00 18.919 0.116 489.00 513.00 1 9.6770e+00 9.3956e-02 3.3557e-02 -6.0000e+00 1.0258e-01 8.8599e-02 2.3456e-02 3.0698e-03 -6.0000e+00 2.6219e-02 7.5296e-06 -1.4729e-03 6.3818e-03 4.7927e-05 -6.0000e+00 7.6272e-03 2.1649e-03 -2.8618e-05 12 9 8 11 8 0 60.47 18.86 0.86 0.00216 -0.00805 8 2 1 4 0 4000.000 24.46 19.99 18.86 -5100 6998 -9787 6446 3840 -4358 1316 -7989 2057 -4092 3139 -2739 -1867 -3407 -2931 6716 380 4328 5686 6385 -5514 4719 2904 4311 1042 -2527 8556 1065 4025 -3514 4015 -878 -6415 1114 -4249 9209 -12443 -2180 4131 -6345 4911 757 4324 -3349 4671 1290 4785 9415 -10620 12734 -229 -8079 -410 -7380 -1529 -5080 22219 -3537 9947 -1442 -3096 -1437 11955 -624 1932 5012 -8761 1737 5155 3264 2340 7199 19248 -9452 -6287 -527 -3114 1965 5935 1009 -5814 14079 -2636 -9765 1013 -14032 5731 -1247 2195 -9677 3006 2003 -8465 2962 -8170 11550 -9609 11580 -4019 5748 5595 -3554 3443 -1123 7262 7073 44 1649 -7844 -2497 2936 15111 -8144 -1061 4580 -2371 6352 8206 7590 11075 416 4181 -8687 1659 3533 10326 -4123 6295 -8613 129 -3856 -1412 2206 -5979 3031 -3873 -6841 -1176 7713 6106 -6394 5603 -4961 -4496 -6390 -8910 12565 5563 7935 -886 -5119 6266 -10336 6130 3758 -4744 1379 -9304 2172 -4569 3223 -2944 -1963 -3598 -3063 6396 390 4369 5794 6566 -6439 4992 3135 4599 1152 -2896 8732 1157 4163 -3826 3986 -915 -6998 1158 -4776 9157 -15339 -2404 4232 -7162 4942 797 4430 -3739 4849 1388 4946 9178 -12419 11509 -230 -8557 -398 -7717 -1539 -5434 18472 -3848 9485 -1541 -3364 -1540 11220 -663 1985 4931 -9499 1714 4854 3097 2228 6539 15625 -10067 -6521 -514 -3069 1813 5204 925 -5713 11413 -2547 -10243 965 -15648 5261 -1228 2086 -10379 2856 1939 -9141 2837 -8594 9720 -9712 9217 -3660 4693 4593 -3268 3060 -1086 6634 6385 42 1555 -8094 -2452 2756 12688 -8697 -1061 4351 -2429 6008 7644 7081 9855 406 3871 -9089 1567 3286 8996 -4154 5710 -9049 124 -3813 -1345 2008 -5887 2745 -3728 -6920 -1145 6981 5689 -6818 5339 -5283 -4775 -6894 -9763 10933 5105 7038 -859 SO 20181221T055127.0Z 6929.244063 334 1 32.01 2 88.41 121.77 109.95 313.10 0.00 1 0.00 1 0 15 3.753e-02 3.717e-02 4.375e-02 4.345e-02 4.682693e+03 2.888025e+03 4.076123e+02 -6.000000e+00 2.128175e+03 278.59 -2.00 20.00 -2.00 505.33 0.00e+00 2.115401e-03 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