File name: Pandora119s1_Athens-NOA_20181225_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T141805.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20181225_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20181225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181225T054520.0Z 6933.239815 282 1 32.01 2 89.74 120.48 66.24 275.82 0.00 1 0.00 1 0 60 1.154e+00 8.032e-01 8.416e-01 6.330e-01 -7.512359e+04 4.727548e+04 4.825696e+03 -6.000000e+00 9.356150e+04 278.37 -2.00 20.00 -2.00 505.47 0.00e+00 -1.382286e-02 2.251663e-02 6.541743e-04 -6.000000e+00 4.128137e-02 278.37 -2.00 20.00 -2.00 500.35 0.00e+00 4.181985e+01 1.688944e+01 4.638237e-01 -6.000000e+00 3.059430e+01 223.50 -2.00 3.45 -2.00 502.11 0.00e+00 20.247 0.142 489.00 513.00 1 9.3450e+00 1.3337e+00 5.2652e-02 -6.0000e+00 2.3779e+00 -7.8750e-01 3.0062e-01 1.2554e-02 -6.0000e+00 5.9379e-01 2.7863e-07 -9.7823e-03 4.2310e-02 1.4398e-03 -6.0000e+00 1.6653e-01 4.5999e-02 -9.3357e-04 12 9 8 11 8 0 78.72 19.68 48.44 0.04600 -0.02185 8 2 1 4 0 4000.000 25.17 19.99 19.68 900000 15249 900000 900000 32331 900000 -38421 900000 -1608 900000 69909 57925 213616 -59532 900000 249222 900000 56681 224364 64821 -60759 82787 -41554 61100 5736 29843 39472 -7247 900000 -10966 201547 33672 321127 -47577 -17403 47700 -37148 123298 -9627 278060 79064 42895 -33083 56198 239743 -29440 900000 900000 900000 156783 900000 241744 -16976 900000 -2309 900000 44188 -3666 87585 -36734 151398 -12318 900000 900000 190821 13797 -57581 900000 900000 17057 -16546 900000 900000 -2165 900000 -102953 18638 -9311 900000 280763 900000 900000 -16760 59976 -7572 900000 900000 900000 26122 180858 183799 -44210 900000 82251 13792 900000 -29283 900000 -32128 900000 900000 36688 116280 900000 900000 -11051 900000 -26185 900000 900000 100792 29638 900000 900000 42443 900000 -69911 206984 -5531 37503 48291 -6624 -382 360401 900000 900000 50213 139038 69064 900000 205828 900000 900000 900000 88530 197651 900000 118504 900000 -9527 136932 900000 6227 68082 72092 900000 -54445 99600 17 900000 900000 9353 900000 900000 19830 900000 -44257 900000 -1405 900000 42879 35528 131023 -93894 900000 152861 900000 34766 137615 39758 -113534 50778 -68572 38413 6178 25448 30706 -8784 900000 -13612 123620 26698 196965 -82795 -23636 35679 -63056 75626 -12653 170549 48494 32727 -50965 36992 147047 -43253 900000 900000 900000 96164 900000 148275 -19089 900000 -2158 900000 27103 -3587 53721 -48730 92860 -12772 900000 900000 117041 10477 -83477 900000 900000 11458 -15222 900000 900000 -1675 900000 -204876 11704 -7614 900000 172207 900000 900000 -14344 36786 -5941 900000 900000 900000 16022 110930 112734 -55465 900000 50449 11214 900000 -41909 900000 -52988 900000 900000 29829 71321 900000 900000 -11708 900000 -27742 900000 900000 61821 18179 900000 900000 27243 900000 -137031 126955 -5552 24072 29620 -6556 -373 221053 900000 900000 34380 85280 42361 900000 126245 900000 900000 900000 54300 121230 900000 72685 900000 -13974 83988 900000 8220 52198 55272 900000 -143317 61090 26 900000 SO 20181225T054934.0Z 6933.242755 286 1 32.01 2 89.03 121.14 67.05 276.40 0.00 1 0.00 1 0 105 1.130e+00 7.950e-01 8.523e-01 6.374e-01 5.215180e+04 7.330965e+04 3.358671e+02 -6.000000e+00 6.801089e+04 278.37 -2.00 20.00 -2.00 505.42 0.00e+00 3.576994e-02 2.196850e-02 2.635649e-03 -6.000000e+00 3.684314e-02 278.37 -2.00 20.00 -2.00 500.99 0.00e+00 1.046968e-01 1.516568e+01 9.098436e-01 -6.000000e+00 2.586930e+01 223.50 -2.00 3.45 -2.00 502.52 0.00e+00 18.830 0.114 489.00 513.00 1 1.1672e+01 1.1772e+00 9.7027e-02 -6.0000e+00 1.9752e+00 -2.6805e-02 2.4642e-01 1.4266e-02 -6.0000e+00 5.1676e-01 2.9997e-07 1.6692e-01 5.4197e-02 7.6623e-04 -6.0000e+00 1.5444e-01 1.1320e-01 -6.1768e-04 12 13 12 11 8 0 3.85 19.67 58.34 0.11320 1.27104 8 2 1 4 0 4000.000 25.17 19.99 19.67 13536 900000 -52771 900000 34213 110871 261273 180703 117838 -73856 900000 -6391 182341 147104 900000 900000 35062 900000 -65943 900000 -17073 332159 22305 -231 137838 -44000 70621 81139 900000 -38599 81892 100911 -60093 316743 36757 900000 900000 23071 900000 -26900 136888 -33017 900000 900000 91895 900000 -5880 173265 136427 900000 -8578 900000 49401 202012 900000 -37801 900000 7600 900000 159477 80513 131854 -66691 900000 2470 52551 57246 900000 104341 143024 900000 44047 900000 -49444 900000 6818 900000 31213 146508 900000 -17559 900000 -17721 83744 900000 -23911 43851 60983 900000 6958 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24130 -44444 22583 -119396 42288 24225 17269 40080 45980 161178 -85883 64556 -32910 166001 52449 89986 48865 26645 122797 -62893 900000 85306 900000 900000 -166793 72231 -15572 900000 29728 900000 31212 20148 159805 -45568 900000 151940 900000 31599 900000 12439 -63281 900000 -44095 900000 6873 900000 39279 58049 900000 38585 900000 -48562 78512 -54068 150196 58792 -25812 900000 61950 SO 20181225T055346.1Z 6933.245672 290 1 32.20 2 88.32 121.80 67.85 276.98 0.00 1 0.00 1 0 125 8.946e-01 6.872e-01 8.506e-01 6.817e-01 7.913373e+04 6.675971e+04 3.178776e+03 -6.000000e+00 5.315589e+04 278.37 -2.00 20.00 -2.00 505.21 0.00e+00 3.823372e-03 2.046106e-02 7.208818e-04 -6.000000e+00 2.665926e-02 278.37 -2.00 20.00 -2.00 500.66 0.00e+00 -2.181355e+00 1.517174e+01 9.781083e-01 -6.000000e+00 1.929593e+01 223.50 -2.00 3.45 -2.00 502.02 0.00e+00 16.994 0.084 489.00 513.00 1 1.2561e+01 1.1421e+00 8.1906e-02 -6.0000e+00 1.4662e+00 -3.2731e-02 2.9309e-01 1.8469e-02 -6.0000e+00 3.9477e-01 3.9981e-07 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