File name: Pandora119s1_Athens-NOA_20181230_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T141741.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20181230_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20181230 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181230T054653.0Z 6938.240891 317 1 32.01 2 89.75 120.18 42.23 194.42 0.00 1 0.00 1 0 63 7.314e-01 5.317e-01 7.970e-01 6.218e-01 -2.042093e+04 3.303058e+04 2.207525e+03 -6.000000e+00 4.457864e+04 278.09 -2.00 20.00 -2.00 504.95 0.00e+00 -2.132930e-02 1.762352e-02 6.510560e-04 -6.000000e+00 2.124192e-02 278.09 -2.00 20.00 -2.00 500.63 0.00e+00 -1.048223e+01 1.215747e+01 1.714035e-01 -6.000000e+00 1.564650e+01 223.61 -2.00 3.45 -2.00 502.13 0.00e+00 20.252 0.142 489.00 513.00 1 1.3110e+01 9.1578e-01 4.1994e-02 -6.0000e+00 1.1995e+00 3.9232e-01 2.4720e-01 3.5110e-03 -6.0000e+00 3.0506e-01 5.1941e-07 4.6116e-02 5.6107e-02 5.7269e-04 -6.0000e+00 8.6047e-02 -1.6297e-02 1.5495e-03 12 8 8 10 0 0 -88.52 19.24 43.00 -0.01630 0.30358 8 2 1 4 0 4000.000 24.75 20.00 19.24 13294 67934 33505 44026 -41113 173447 900000 89036 70676 77985 900000 8154 123084 -62861 43230 67633 -2165 91704 82649 172024 -33654 4608 12427 1077 20052 37055 52851 29480 116338 81211 49297 129668 -29422 45043 -5222 -24143 -7491 30734 900000 57139 91152 -11375 40252 -39271 149846 -32387 -53677 98736 -16044 -10647 -43405 61832 -23041 20413 43047 36043 14615 18401 22224 7956 -38052 64811 63894 30837 -34600 236172 52345 900000 94071 36728 96814 -52123 60601 28246 -25686 175100 49717 29373 52320 18919 72048 900000 -31919 82225 215284 -44709 -37381 9176 900000 -19509 17818 -29439 58727 50169 29851 31665 -22246 900000 97885 -23779 49423 34553 -7822 82280 73405 19963 2803 900000 31975 900000 92047 39427 -53144 17748 86234 -31665 83666 47392 91420 29239 900000 124992 15262 201238 52048 73599 -55579 26022 59002 30357 78510 -31880 9487 288090 16214 -21484 900000 -14064 -11199 56842 30130 37867 19556 30261 26632 -55405 -24459 91493 900000 900000 13336 41303 28519 34128 -71418 105453 900000 54132 42970 47414 900000 8585 74833 -138314 35482 44204 -2793 55754 50249 104588 -56512 5330 13084 1245 18733 29288 35346 24481 70732 49375 36715 78836 -45573 33397 -6123 -33551 -8675 24611 900000 35608 55419 -13174 28054 -57985 91104 -42194 -81967 60030 -16722 -10634 -60144 37593 -27684 16346 27449 24586 12059 15008 17467 7025 -51650 39404 38847 21492 -44029 143589 31825 900000 57194 25598 58861 -82826 36844 20853 -31960 106458 30947 22961 33324 17254 43804 900000 -49838 49992 130889 -84635 -66631 10639 900000 -30192 19651 -51254 44206 39724 28701 29997 -35965 900000 59512 -40480 41928 33222 -10916 50025 45692 20136 3369 900000 29838 900000 55963 33448 -106266 17411 52429 -47915 50868 33504 55582 24392 900000 75993 13708 122349 32380 44747 -93864 19417 35872 21461 47733 -40919 8389 175154 13666 -25834 900000 -15771 -12256 34559 22066 25116 15132 20489 18400 -82749 -27429 55626 900000 900000 SO 20181230T055106.0Z 6938.243820 321 1 32.01 2 89.03 120.83 42.46 195.91 0.00 1 0.00 1 0 17 1.316e+00 7.022e-01 7.185e-01 4.828e-01 2.604280e+04 4.352874e+04 3.726803e+03 -6.000000e+00 7.570448e+04 278.09 -2.00 20.00 -2.00 505.53 0.00e+00 3.250984e-04 1.488624e-02 6.090705e-04 -6.000000e+00 3.880149e-02 278.09 -2.00 20.00 -2.00 500.33 0.00e+00 7.695141e+00 1.028107e+01 1.192559e+00 -6.000000e+00 2.806042e+01 223.61 -2.00 3.45 -2.00 502.05 0.00e+00 18.836 0.114 489.00 513.00 1 1.1274e+01 7.8058e-01 9.1471e-02 -6.0000e+00 2.1459e+00 -1.2572e-01 1.9232e-01 1.5717e-02 -6.0000e+00 5.7053e-01 6.4419e-07 -1.2402e-02 4.5086e-02 1.2461e-03 -6.0000e+00 1.5531e-01 2.6067e-02 -1.7099e-03 12 9 8 11 8 0 -271.87 19.25 -2.68 0.02607 -0.05996 8 2 1 4 0 4000.000 24.75 20.00 19.25 900000 900000 5084 54610 -68209 900000 -2608 66455 164918 2557 25042 -56134 277025 -49109 344378 182543 86495 72435 -20173 126869 -12791 97549 -9117 3019 108554 19210 900000 -26905 226079 14247 146171 -14333 -10136 219497 9309 462934 -35176 306984 -11036 12717 2844 40208 102411 17605 153748 -7857 51952 34351 -29059 261263 -46997 217192 32734 22410 -31687 36565 -7447 -31175 900000 12001 45056 172631 203093 46664 1017 76145 -4106 147930 13112 173504 156606 20281 250756 91921 69422 -8824 900000 59221 36772 162405 -35497 900000 775 21163 -6094 65145 46007 -18965 113335 -52394 900000 -23040 67550 24523 -39803 900000 -34611 110481 25152 116615 -34440 21288 42691 29771 439957 13868 900000 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33473 -7186 38557 13663 39917 -3298 43522 -46805 143507 29361 141918 217685 -136723 62755 35907 40377 -43382 154025 45226 -58273 900000 -26422 110727 -97127 40776 146733 6651 91077 -80073 900000 32494 64038 -2610 51293 45488 -69471 SO 20181230T055514.0Z 6938.246690 325 1 32.01 2 88.33 121.47 42.70 197.37 0.00 1 0.00 1 0 37 4.857e-01 3.086e-01 5.087e-01 3.865e-01 1.222036e+04 2.921978e+04 4.021815e+02 -6.000000e+00 2.748762e+04 278.09 -2.00 20.00 -2.00 505.27 0.00e+00 -1.195146e-02 1.050596e-02 7.613095e-04 -6.000000e+00 1.371689e-02 278.09 -2.00 20.00 -2.00 499.88 0.00e+00 -6.630237e+00 7.982408e+00 2.351083e-01 -6.000000e+00 9.842795e+00 223.61 -2.00 3.45 -2.00 501.62 0.00e+00 17.023 0.084 489.00 513.00 1 1.2589e+01 6.0208e-01 3.6990e-02 -6.0000e+00 7.5452e-01 2.8434e-01 1.6009e-01 4.0109e-03 -6.0000e+00 1.9514e-01 1.0030e-06 -7.0742e-03 3.8945e-02 3.5930e-04 -6.0000e+00 5.5965e-02 5.5155e-03 2.8858e-04 12 8 8 10 0 0 16.35 19.25 7.51 0.00552 -0.04355 8 2 1 4 0 4000.000 24.75 20.00 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