File name: Pandora119s1_Athens-NOA_20190101_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T141743.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190101_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190101 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190101T054715.0Z 6940.241146 376 1 32.01 2 89.75 119.98 51.97 163.16 0.00 1 0.00 1 0 99 8.039e-01 4.465e-01 6.329e-01 4.590e-01 -3.133926e+04 2.763629e+04 3.041776e+02 -6.000000e+00 4.574688e+04 277.98 -2.00 20.00 -2.00 505.09 0.00e+00 8.351765e-03 1.274741e-02 2.598801e-04 -6.000000e+00 2.271927e-02 277.98 -2.00 20.00 -2.00 500.17 0.00e+00 5.896402e+00 1.014031e+01 1.312526e-01 -6.000000e+00 1.632091e+01 223.66 -2.00 3.45 -2.00 501.73 0.00e+00 20.258 0.142 489.00 513.00 1 1.1163e+01 7.7182e-01 3.6758e-02 -6.0000e+00 1.2512e+00 1.1196e-01 2.0064e-01 3.0066e-03 -6.0000e+00 3.2092e-01 7.9356e-07 -4.6243e-02 3.5190e-02 1.6220e-04 -6.0000e+00 9.3601e-02 -5.4219e-02 4.2116e-04 12 8 8 10 0 0 -7.19 18.90 17.19 -0.05422 -0.37498 8 2 1 4 0 4000.000 24.46 19.99 18.90 61553 -5259 58472 -12247 -15028 18480 256753 -8037 -11082 54695 109785 126794 -34304 33902 -7476 31974 2080 231916 13789 56224 -563 -18683 56973 -22226 55747 -4819 36296 43638 52472 61447 -16887 16148 -43096 17127 -18351 95312 -11089 -31153 10405 73097 62971 33436 1982 157965 -25163 -25193 -24620 6348 -29955 166543 113979 16345 45954 -2927 350943 35717 50826 24859 -17785 63906 19990 -27354 -19412 220489 122534 -21597 -23019 -46588 5853 97275 -8040 13846 5857 39451 73489 900000 34691 31687 108645 -8427 -4479 79641 192113 -22210 17367 -41579 30348 26193 50670 98804 -34024 3761 20007 12740 49877 43324 7587 -28243 641 -3417 130521 31846 81196 59460 -12541 -5367 -37841 -20864 10429 17020 143503 127400 261055 37476 48066 -11366 63474 48874 -22789 64547 -3207 43313 -20449 8492 64592 -62557 56593 -2937 -8088 81150 -2436 52886 71471 190093 76064 900000 -10187 71087 32260 -22243 59910 104 117622 97444 33529 -44168 69870 -10177 283017 8085 39739 -6207 36402 -15005 -18788 17449 115442 -10224 -14827 40356 49362 57009 -57557 28962 -9264 26955 2281 104274 13795 38243 -655 -26430 39065 -32121 38851 -6024 31007 34826 38338 40751 -22960 15760 -72433 15965 -23967 43953 -14126 -49358 11182 42726 40346 27867 2261 71024 -37444 -38027 -37427 7135 -47296 74881 51247 16311 33261 -3291 157791 27418 34000 22081 -24180 40945 19046 -40900 -26794 99136 55094 -30487 -32735 -82814 6203 43737 -9467 12895 5831 28554 38824 900000 25997 24424 48849 -9252 -4683 38494 86378 -27869 15059 -62032 23067 20750 32228 44424 -47632 3736 17562 11989 34172 32930 8409 -45600 800 -4470 58685 28637 45411 39465 -16019 -6252 -59163 -26438 9488 14059 64522 57282 117376 26646 32932 -14054 40091 35262 -31878 39387 -3572 30344 -26329 8244 38031 -121680 36097 -3332 -9670 41699 -2763 35392 40551 85470 39900 900000 -11555 37289 24624 -28447 35707 108 52885 43813 25354 -69937 37990 -11694 127250 7518 SO 20190101T055133.0Z 6940.244132 380 1 32.01 2 89.02 120.64 51.75 164.44 0.00 1 0.00 1 0 78 6.177e-01 3.965e-01 6.594e-01 4.940e-01 -2.162226e+04 2.890878e+04 2.345248e+03 -6.000000e+00 3.507011e+04 277.98 -2.00 20.00 -2.00 505.35 0.00e+00 3.043195e-03 1.401645e-02 2.483637e-04 -6.000000e+00 1.770132e-02 277.98 -2.00 20.00 -2.00 500.17 0.00e+00 9.286710e+00 9.843056e+00 4.129836e-01 -6.000000e+00 1.259538e+01 223.66 -2.00 3.45 -2.00 501.85 0.00e+00 18.807 0.114 489.00 513.00 1 1.1239e+01 7.6443e-01 4.2800e-02 -6.0000e+00 9.6634e-01 -2.2289e-02 1.7766e-01 4.8982e-03 -6.0000e+00 2.4967e-01 7.3759e-07 1.0780e-01 5.3048e-02 5.6140e-04 -6.0000e+00 7.1475e-02 -9.8320e-02 1.8143e-03 12 12 8 10 0 0 51.67 18.90 18.38 -0.09832 0.64944 8 2 1 4 0 4000.000 24.56 19.99 18.90 22117 -34867 22160 4858 118057 -7373 14956 8657 110157 9029 124804 901 5199 -4596 -40795 1197 19762 15362 25143 -18299 691 28482 81227 40776 50358 47567 45304 48605 50495 -60640 144649 17882 29393 143887 20122 -22645 -197 5370 65341 133597 -3819 -10963 9598 47590 -6899 5286 73723 -14145 -9139 47860 7104 66649 -38541 94543 142068 -3213 32472 29613 -36215 26143 49040 -13097 12186 24343 64454 -10647 -22008 16727 900000 96422 -28949 -23722 89278 19028 45806 69326 -36238 9299 31314 -31677 78932 30406 -34471 16245 64582 -9077 60024 98074 196291 60566 15451 -51339 20102 39734 115534 -29358 34425 54572 29046 18017 1468 18177 900000 -15848 21714 -2314 72088 104943 -25291 57912 63847 -14600 900000 19110 139810 90748 -22643 103044 -12231 75653 11295 -27416 20983 -7955 170523 3485 80483 -9660 -14283 -39327 89529 18468 101102 70709 -3690 148111 -5317 97320 100702 18475 166090 15690 -5091 -52450 28931 -15004 18163 72982 900000 900000 21396 -57948 21155 5442 57105 -8870 14659 9036 53283 9654 60368 1062 5932 -5814 -72518 1440 20375 16195 24644 -26781 823 25741 43538 31661 35897 35724 35754 37741 38566 -129489 69967 17965 26247 69599 19966 -33957 -239 6327 43250 64621 -4665 -14053 10000 33924 -7926 5508 40352 -18131 -11383 35022 7645 41570 -63657 45731 68719 -3808 27386 25342 -55970 22373 32845 -15680 11200 20229 36920 -12360 -28041 14766 900000 46640 -37909 -29386 43184 15877 30110 36113 -51730 8658 23477 -43725 39185 23532 -50429 14930 38447 -11030 39457 47439 94947 39550 15130 -93419 18475 29790 55884 -41587 26642 33656 22480 15252 1420 15011 900000 -18982 18957 -2648 40972 50762 -36118 37116 37832 -17824 900000 17134 67627 43895 -31032 49843 -15213 41168 11187 -39167 19309 -9437 82483 3572 39903 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