File name: Pandora119s1_Athens-NOA_20190106_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T141750.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190106_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190106T054738.0Z 6945.241412 490 1 32.01 2 89.74 119.31 91.33 117.29 0.00 1 0.00 1 0 15 5.300e-02 5.229e-02 4.642e-02 4.590e-02 6.453733e+02 2.730980e+03 2.133412e+02 -6.000000e+00 2.994461e+03 277.70 -2.00 20.00 -2.00 505.30 0.00e+00 3.062477e-04 1.274252e-03 3.561191e-05 -6.000000e+00 1.493248e-03 277.70 -2.00 20.00 -2.00 500.19 0.00e+00 3.150212e+00 9.294910e-01 6.256247e-02 -6.000000e+00 1.067831e+00 223.77 -2.00 3.45 -2.00 501.85 0.00e+00 20.254 0.142 489.00 513.00 1 9.1047e+00 7.1581e-02 3.5195e-02 -6.0000e+00 8.1965e-02 8.8897e-02 1.7993e-02 2.0792e-03 -6.0000e+00 2.0985e-02 9.9703e-06 2.6762e-03 5.1212e-03 5.7473e-05 -6.0000e+00 6.0861e-03 4.1119e-02 -3.4429e-04 12 8 8 10 0 0 -129.03 17.98 5.09 0.04112 0.05968 8 2 1 4 0 4000.000 23.72 20.00 17.98 2890 -433 -484 1219 -2789 -217 -7329 1029 -947 1989 1074 -3336 2389 -12259 6646 -4195 4540 -3559 -2663 8313 -7853 8590 -3961 6517 -5044 2095 8109 -6106 5671 -2016 5642 -2451 4829 2604 -5519 176 -5178 9784 -5371 4715 1110 -3560 9598 133 4440 -1836 3412 857 1726 -1548 1300 7339 -6810 11205 -3550 1841 -1138 3872 7723 -4267 1968 -11146 7331 10654 403 -770 -3344 5506 -7247 11490 -176 -8665 3070 -1097 5957 -3016 2542 -7166 6138 -4304 -3192 8328 -3753 10075 -4431 67 -2075 -7385 -519 -725 12775 -3037 -2400 -5031 -1424 10935 -6417 3254 -6705 1498 781 763 6628 -149 3132 -2828 6941 -1565 4315 113 -8360 10569 -6825 8928 2245 2741 6937 -3728 393 -1654 8202 227 5134 -1634 92 -5063 -5003 3399 -7189 1540 -3935 1331 1723 -57 3083 -4411 3696 -4150 8487 -1350 -4050 4587 3082 -2767 -4201 6040 448 -2906 -663 -6488 2655 -416 -477 1219 -2987 -232 -8561 1117 -1049 2123 1143 -3659 2443 -13996 6418 -4538 4568 -3866 -2930 8311 -9291 8647 -4532 6733 -5869 2268 8220 -7041 5689 -2132 5446 -2572 4800 2720 -6396 194 -6013 9692 -6126 4828 1177 -3978 9486 145 4695 -2068 3624 921 1803 -1630 1295 6736 -6960 9885 -3616 1821 -1182 3861 7424 -4620 2003 -12958 7089 9930 412 -786 -3448 5119 -7553 9818 -168 -9021 2865 -1077 5465 -3004 2360 -7227 5369 -4166 -3065 7173 -3676 8665 -4336 65 -2001 -7518 -494 -695 11059 -3039 -2406 -5182 -1403 9368 -6405 2880 -6420 1304 686 682 5744 -141 2927 -2804 6182 -1502 3891 107 -8730 9274 -7224 8158 2209 2697 6560 -3816 383 -1622 7377 214 4720 -1574 87 -5080 -5020 3134 -7359 1440 -3851 1220 1555 -52 2746 -4303 3391 -4195 7671 -1360 -4224 4416 3030 -2892 -4440 5698 439 -2891 -638 -6635 SO 20190106T055151.0Z 6945.244340 494 1 32.01 2 89.02 119.97 90.62 117.92 0.00 1 0.00 1 0 22 2.322e-02 2.289e-02 2.771e-02 2.756e-02 2.389942e+03 1.746644e+03 2.684767e+02 -6.000000e+00 1.311824e+03 277.70 -2.00 20.00 -2.00 505.31 0.00e+00 2.681634e-03 7.647549e-04 1.090883e-04 -6.000000e+00 6.543633e-04 277.70 -2.00 20.00 -2.00 500.30 0.00e+00 2.493495e+00 5.586944e-01 1.796260e-02 -6.000000e+00 4.684373e-01 223.78 -2.00 3.45 -2.00 501.93 0.00e+00 18.818 0.114 489.00 513.00 1 8.7877e+00 4.2927e-02 3.1166e-02 -6.0000e+00 3.5946e-02 7.7067e-02 1.0784e-02 1.7199e-03 -6.0000e+00 9.2205e-03 1.6983e-05 7.0037e-03 3.0832e-03 5.4211e-05 -6.0000e+00 2.6639e-03 1.1699e-03 -2.3530e-04 12 8 8 10 0 0 27.19 17.98 0.67 0.00117 0.04975 8 2 1 4 0 4000.000 23.72 20.00 17.98 -4258 -2052 3080 -1861 -1046 -927 -596 -820 1366 907 657 4611 -885 1610 -1719 -977 1743 -3215 5579 -546 676 -1526 -372 1361 -1854 681 -1552 2811 1152 -1941 1632 608 2820 -2913 2750 -716 -2016 557 -3212 -3199 3816 790 -1520 3218 -2510 -1790 2361 625 -2838 1573 -1374 -1079 -386 -933 3421 3706 1464 -645 1705 431 -3966 2275 2577 -1361 2504 -106 21 -968 -4441 3428 -2024 2870 -350 -717 596 -1139 -1250 -897 2790 -655 1362 -2121 -610 2816 -3484 1036 -686 3057 971 1076 1966 -1965 3998 921 -1320 593 5421 -221 -2560 -1654 -3575 4012 1876 -2975 -1747 1076 631 -87 -2645 480 5813 -172 -1346 -3589 -562 538 293 1015 -3191 -2 2695 -1087 -2385 -726 4941 2394 207 -4215 -1936 1047 -758 5752 1365 -763 -1797 -5410 475 -2740 3863 530 1853 -3018 1142 1486 -805 1840 -773 1554 -947 -988 -4115 -1963 2877 -1885 -1082 -979 -639 -888 1446 956 685 4552 -911 1598 -1757 -996 1754 -3470 5627 -594 730 -1689 -408 1436 -2028 727 -1685 2882 1175 -1992 1594 602 2785 -3132 2857 -776 -2208 589 -3495 -3463 3858 829 -1652 3373 -2809 -1992 2507 667 -3074 1592 -1396 -1072 -378 -928 3332 3693 1521 -674 1745 447 -4302 2325 2629 -1439 2525 -109 21 -967 -4533 3199 -1983 2684 -341 -707 581 -1121 -1213 -856 2541 -616 1257 -2040 -582 2615 -3471 992 -669 2869 931 1036 1892 -1943 3849 893 -1295 561 4898 -202 -2337 -1477 -3259 3449 1693 -2893 -1702 1020 595 -82 -2554 453 5284 -169 -1355 -3736 -571 545 298 1024 -3327 -2 2583 -1074 -2384 -717 4631 2309 199 -4246 -1904 995 -726 5100 1250 -711 -1701 -5395 455 -2758 3689 528 1836 -3157 1152 1496 -826 1815 -768 1482 -917 -961 SO 20190106T055557.0Z 6945.247188 498 1 32.01 2 88.32 120.61 89.93 118.53 0.00 1 0.00 1 0 15 1.458e-02 1.443e-02 1.685e-02 1.678e-02 2.872396e+03 1.065296e+03 2.464794e+02 -6.000000e+00 8.234928e+02 277.69 -2.00 20.00 -2.00 505.32 0.00e+00 1.762152e-03 4.651401e-04 8.293391e-05 -6.000000e+00 4.106674e-04 277.69 -2.00 20.00 -2.00 500.42 0.00e+00 1.801865e+00 3.381947e-01 1.907914e-02 -6.000000e+00 2.937142e-01 223.78 -2.00 3.45 -2.00 502.03 0.00e+00 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