File name: Pandora119s1_Athens-NOA_20190114_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T143943.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190114_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190114T054622.0Z 6953.240532 486 1 32.01 2 89.74 117.74 134.55 28.68 0.00 1 0.00 1 0 15 8.777e-02 8.565e-02 8.913e-02 8.690e-02 -6.674177e+03 5.192165e+03 2.187679e+02 -6.000000e+00 4.949961e+03 277.25 -2.00 20.00 -2.00 505.26 0.00e+00 1.023960e-03 2.416902e-03 6.691238e-05 -6.000000e+00 2.468169e-03 277.25 -2.00 20.00 -2.00 499.97 0.00e+00 5.504223e+00 1.807622e+00 1.082182e-01 -6.000000e+00 1.763363e+00 223.96 -2.00 3.45 -2.00 501.64 0.00e+00 20.259 0.142 489.00 513.00 1 9.5980e+00 1.3882e-01 3.5905e-02 -6.0000e+00 1.3540e-01 8.6215e-02 3.5071e-02 2.7242e-03 -6.0000e+00 3.4530e-02 5.1111e-06 -3.2455e-03 9.5731e-03 2.0396e-05 -6.0000e+00 1.0075e-02 5.5738e-02 -1.6931e-04 12 8 8 10 0 0 -115.97 19.01 4.96 0.05574 0.03323 8 2 1 4 0 4000.000 24.56 20.01 19.01 -7188 5371 694 -9328 13480 -3737 5698 3494 4585 2317 -1843 -3627 -3757 -3386 -4462 -3797 -11037 9245 -1566 -4279 -3256 12972 12072 -6599 2158 -1618 7703 -6592 -10079 1479 4941 10403 18254 8945 6589 486 -2666 16514 9237 -10938 -890 4343 -5440 325 -4693 -2019 10271 -2639 -12264 -2848 327 3681 4089 -10041 10837 -3598 3267 -17666 7455 13967 1263 -5797 9402 5978 4916 -10903 -2474 -1280 7155 29274 10584 -12422 -7850 5275 1452 -6077 -5427 6991 4543 -10141 8049 8321 9135 12602 -5643 9242 4528 -11334 1967 9632 5654 -639 5219 12565 -7624 6162 -2352 -3095 797 8971 5528 -6000 7483 -28202 -24 15734 -2145 16092 -5896 6762 -20752 -14458 8329 24925 13727 5944 18051 -4012 -2727 2018 13281 2222 -902 543 -6227 4146 -9033 16361 5911 1056 -5033 -2884 1457 -6803 -7189 5715 3201 1399 -8054 -3728 -429 -5088 -502 550 -2394 11819 8178 840 -3639 -575 -7609 5067 705 -10797 12780 -4309 6084 3851 5001 2565 -2099 -4148 -4245 -3772 -4869 -4135 -13107 9403 -1765 -5024 -3809 12934 12172 -8044 2417 -1882 8112 -7902 -12241 1561 4960 9907 16360 9039 6968 551 -3106 15726 9355 -13455 -989 4603 -6411 365 -5430 -2335 10425 -2926 -14673 -3022 336 3571 3912 -10851 9956 -3810 3288 -22100 7259 12715 1305 -6430 8949 5860 4819 -12331 -2528 -1271 6436 21383 9012 -13316 -8089 4802 1376 -6156 -5379 6029 3978 -10251 6800 7048 7718 10344 -5593 7929 4083 -11701 1829 8348 5148 -612 4777 11055 -8017 5614 -2303 -2991 725 7390 4695 -5773 6403 -34998 -22 12492 -2004 12366 -5623 5729 -23544 -15726 7358 18941 11775 5529 14832 -4073 -2699 1881 10969 2043 -859 512 -6155 3702 -9210 13268 5192 972 -4881 -2701 1289 -6485 -6897 4889 2865 1299 -8329 -3724 -417 -5209 -494 538 -2406 10185 7167 776 -3476 -534 SO 20190114T055033.0Z 6953.243438 490 1 32.01 2 89.01 118.39 134.15 29.97 0.00 1 0.00 1 0 22 4.705e-02 4.660e-02 5.277e-02 5.203e-02 1.260054e+03 3.221988e+03 2.455367e+02 -6.000000e+00 2.653500e+03 277.25 -2.00 20.00 -2.00 505.26 0.00e+00 5.019928e-03 1.429498e-03 3.010055e-04 -6.000000e+00 1.323902e-03 277.25 -2.00 20.00 -2.00 500.02 0.00e+00 3.264058e+00 1.070598e+00 5.281634e-02 -6.000000e+00 9.480342e-01 223.96 -2.00 3.45 -2.00 501.66 0.00e+00 18.808 0.114 489.00 513.00 1 9.3635e+00 8.2121e-02 3.2021e-02 -6.0000e+00 7.2760e-02 1.0390e-01 2.0789e-02 1.7694e-03 -6.0000e+00 1.8623e-02 8.7462e-06 5.6626e-03 5.7562e-03 1.2851e-04 -6.0000e+00 5.4023e-03 3.1386e-02 -2.5694e-04 12 9 8 11 8 0 -109.67 19.01 3.69 0.03139 0.07066 8 2 1 4 0 4000.000 24.56 20.00 19.01 531 -5352 -1612 881 2832 351 4432 239 5137 -2866 -960 -696 -5693 2354 -3444 -2213 4850 -6689 4689 -1552 -3619 -1087 1225 -5103 2010 5695 -77 5824 -1786 7890 -3061 6317 3847 -6252 -5527 -2541 4999 4071 5099 -1543 1393 2355 1871 -862 -5182 4678 -5317 2731 2953 -2735 4528 5114 1822 101 4950 -4573 -439 6940 -458 1800 -5013 7046 -10536 -4597 -1839 -12026 6292 -3685 683 -2816 3533 -2122 1538 2174 -1501 5274 -4654 3613 8006 2334 9132 2030 4452 1487 2098 2275 3106 1374 -9 -4155 -3840 1879 -6565 13148 1866 2483 7763 -9416 3633 -10254 9880 72 3020 1017 -9306 -734 -693 -518 -4828 3577 927 2103 -6862 2105 1877 -2134 2032 3512 -2648 2057 -5001 1205 8217 2235 -4645 5446 6396 -4249 2581 -5345 -3276 -5317 -2859 9299 4787 1188 -7510 10057 -6721 1346 5255 -598 -6718 801 4541 -514 -2652 -214 5244 -1417 515 -5586 -1668 918 2971 386 4745 269 5472 -3268 -1057 -752 -6378 2407 -3715 -2370 4906 -7745 4932 -1710 -4087 -1199 1324 -5903 2175 5941 -84 5938 -1919 7509 -3209 6061 3862 -7134 -6386 -2867 5201 4235 5206 -1678 1477 2497 2017 -967 -6117 5008 -6249 2920 3088 -2953 4433 4887 1791 102 4885 -4959 -465 7058 -490 1881 -5616 7013 -12502 -5114 -1968 -14039 6014 -3832 670 -2828 3309 -2107 1482 2095 -1500 4873 -4674 3292 6918 2126 7786 1865 4011 1387 1954 2119 2866 1287 -9 -4131 -3842 1799 -6735 11361 1744 2269 6748 -9249 3139 -9792 7908 63 2624 920 -9419 -679 -635 -469 -4575 3153 854 1951 -7074 2008 1809 -2152 1968 3337 -2647 1937 -4993 1124 7152 2076 -4533 4936 5750 -4146 2407 -5242 -3113 -5086 -2638 7747 4097 1070 -7511 8570 -6853 1276 4816 -584 -6997 774 4200 -493 -2546 -197 4532 -1316 SO 20190114T055439.0Z 6953.246285 494 1 32.01 2 88.31 119.03 133.74 31.21 0.00 1 0.00 1 0 15 2.969e-02 2.958e-02 2.890e-02 2.872e-02 5.530360e+03 1.941083e+03 4.289083e+02 -6.000000e+00 1.674266e+03 277.25 -2.00 20.00 -2.00 505.34 0.00e+00 2.016401e-03 7.970156e-04 7.297308e-05 -6.000000e+00 8.355382e-04 277.25 -2.00 20.00 -2.00 500.36 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