File name: Pandora119s1_Athens-NOA_20190116_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T144054.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190116_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190116T054543.0Z 6955.240081 435 1 32.01 2 89.74 117.26 129.91 356.90 0.00 1 0.00 1 0 22 4.763e-02 4.646e-02 4.892e-02 4.821e-02 1.615551e+03 3.027378e+03 1.195350e+02 -6.000000e+00 2.685508e+03 277.15 -2.00 20.00 -2.00 505.28 0.00e+00 -1.606492e-03 1.344336e-03 4.969896e-05 -6.000000e+00 1.339512e-03 277.15 -2.00 20.00 -2.00 500.08 0.00e+00 3.235409e+00 9.929304e-01 1.871150e-02 -6.000000e+00 9.584341e-01 224.01 -2.00 3.45 -2.00 501.74 0.00e+00 20.256 0.142 489.00 513.00 1 9.1775e+00 7.6168e-02 3.4914e-02 -6.0000e+00 7.3574e-02 1.0099e-01 1.9463e-02 1.9290e-03 -6.0000e+00 1.8794e-02 9.4721e-06 -2.7069e-02 5.1961e-03 3.3077e-05 -6.0000e+00 5.4704e-03 2.8132e-02 -1.0595e-04 12 8 8 10 0 0 -22.01 18.22 4.52 0.02813 -0.15963 8 2 1 4 0 4000.000 23.93 20.01 18.22 5339 -4751 -4416 -3875 3030 -5418 -5602 9374 -5130 1628 -6686 4544 3288 3297 2343 -6589 10088 -6645 4550 1542 -2483 2967 -4613 2419 -3708 434 -980 6805 -5162 1029 7621 -4722 11786 -171 3050 2059 4706 -1009 -4092 8723 3784 169 -4266 -3286 -2307 -4977 -455 247 -1509 -592 -2583 2246 -7380 3750 -5739 3098 -367 5844 8594 -2089 -1270 -1205 -335 6997 -145 3054 -5816 -54 5732 -164 6031 9287 -711 -2859 1272 -1455 3313 -5562 6137 -743 6779 2596 -4845 1695 1326 7788 401 -436 -200 -4245 114 -1595 5175 -1966 427 -231 -5630 3870 -6779 7954 -401 2050 -246 3514 12266 -2990 6629 -8900 5576 -1912 -1001 5601 -2851 -334 -3422 1467 -5017 -93 -3687 4006 3472 -8294 5818 -2057 4653 509 -4476 -5437 -339 5960 -2751 -1343 4885 6790 2692 -6744 9077 -3777 -6350 3408 10746 -4157 -8156 -302 -3903 3801 -1324 4303 -2151 1140 4991 -4807 -4452 -3960 2975 -5967 -6344 9334 -5994 1789 -7962 4790 3466 3431 2432 -7420 9618 -7372 4722 1646 -2812 3217 -5420 2654 -4334 488 -1119 7154 -6058 1115 7551 -5181 10892 -180 3185 2230 5044 -1148 -4762 8833 3983 184 -4841 -3713 -2602 -5805 -508 273 -1680 -642 -2790 2250 -7730 3543 -5801 2983 -366 5590 8109 -2203 -1327 -1257 -346 6734 -150 3033 -6236 -54 5307 -159 5420 8006 -676 -2792 1203 -1424 3087 -5596 5406 -693 5820 2324 -4698 1551 1229 6833 382 -421 -193 -4171 108 -1540 4711 -1939 412 -223 -5649 3460 -6584 6516 -351 1743 -217 3056 10090 -2935 5965 -9311 4991 -1828 -948 5007 -2809 -325 -3466 1425 -5225 -93 -3807 3808 3280 -8488 5235 -1944 4214 471 -4360 -5351 -317 5222 -2624 -1255 4242 5712 2341 -6447 7493 -3615 -6363 3150 9355 -4241 -8723 -300 -4047 3650 -1329 4026 -2107 1064 SO 20190116T055003.0Z 6955.243090 439 1 32.01 2 88.98 117.93 129.93 358.22 0.00 1 0.00 1 0 22 3.259e-02 3.183e-02 3.033e-02 3.006e-02 4.517372e+03 2.009201e+03 2.493805e+02 -6.000000e+00 1.837678e+03 277.15 -2.00 20.00 -2.00 505.29 0.00e+00 7.815445e-04 8.341306e-04 4.791932e-05 -6.000000e+00 9.169278e-04 277.15 -2.00 20.00 -2.00 500.16 0.00e+00 2.113244e+00 6.182021e-01 4.723441e-02 -6.000000e+00 6.566179e-01 224.01 -2.00 3.45 -2.00 501.81 0.00e+00 18.731 0.112 489.00 513.00 1 8.9435e+00 4.7442e-02 3.1038e-02 -6.0000e+00 5.0396e-02 9.8726e-02 1.1969e-02 1.9373e-03 -6.0000e+00 1.2892e-02 1.5500e-05 -4.2620e-03 3.3006e-03 2.3240e-05 -6.0000e+00 3.7425e-03 1.2965e-02 -1.0731e-04 12 8 8 10 0 0 -68.98 18.23 0.78 0.01297 -0.01660 8 2 1 4 0 4000.000 23.93 20.00 18.23 2062 -5438 -1134 -1422 1480 3754 356 1415 -1834 -2457 -2760 3213 -3052 2088 -1794 -2547 -1668 -4955 2055 -2091 1550 -559 2096 502 -2037 1365 -1725 4795 -345 560 326 -549 4629 -4640 2151 2647 461 5004 -3803 1694 -3158 1749 -2952 3226 624 11 4093 215 -1378 -859 287 1384 -3892 1717 -974 3634 -2912 5336 442 -1504 969 -1235 592 2475 3996 -2755 7276 -1399 -3039 218 -10405 5628 -730 272 3715 6442 3724 -5849 4713 -3341 600 -653 -2722 406 -3602 3796 750 -643 1197 4403 843 -2277 1618 926 5090 -5115 -1575 -763 6152 2394 -2094 1212 -3420 7719 271 1118 -724 -5950 9790 -2295 110 -3180 1082 472 -1335 7 -2043 2079 -4100 1118 3574 2045 1410 -4317 2598 -4649 -1287 -3476 3495 1753 -5179 6418 -4592 -505 -1446 1975 -328 1078 1444 -4667 4809 -2753 7774 123 -1315 254 -2404 388 -3863 628 1962 -5454 -1114 -1443 1503 3822 382 1523 -2046 -2743 -3054 3302 -3294 2115 -1876 -2686 -1762 -5517 2180 -2352 1696 -626 2292 560 -2277 1514 -1917 5067 -367 576 330 -558 4527 -5109 2270 2819 502 5163 -4240 1773 -3460 1832 -3268 3390 679 12 4298 232 -1486 -900 290 1349 -3944 1649 -978 3576 -3126 5344 467 -1619 1017 -1297 611 2504 3953 -2880 6774 -1399 -3048 209 -11011 5070 -706 263 3486 5859 3436 -5845 4188 -3200 552 -613 -2625 383 -3566 3515 719 -625 1141 4075 813 -2288 1578 910 4746 -5058 -1504 -705 5180 2060 -1881 1068 -3171 6777 256 1057 -694 -5955 8322 -2209 105 -3163 1043 462 -1340 7 -2088 2041 -4259 1089 3349 1921 1326 -4305 2427 -4683 -1254 -3462 3240 1648 -5059 5645 -4350 -456 -1322 1768 -306 1011 1370 -4764 4503 -2799 7152 123 -1326 250 -2390 368 -3774 585 SO 20190116T055410.0Z 6955.245949 443 1 32.01 2 88.27 118.57 129.94 359.47 0.00 1 0.00 1 0 15 1.596e-02 1.590e-02 1.877e-02 1.865e-02 1.785622e+03 1.156184e+03 1.861238e+02 -6.000000e+00 9.000289e+02 277.15 -2.00 20.00 -2.00 505.28 0.00e+00 1.925811e-03 5.151349e-04 1.173979e-04 -6.000000e+00 4.490910e-04 277.15 -2.00 20.00 -2.00 500.24 0.00e+00 1.898196e+00 3.817300e-01 1.825975e-02 -6.000000e+00 3.216500e-01 224.01 -2.00 3.45 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