File name: Pandora119s1_Athens-NOA_20190201_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T144121.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190201_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190201T053543.0Z 6971.233137 411 1 32.01 2 89.74 112.22 68.04 145.79 0.00 1 0.00 1 0 15 5.599e-02 5.469e-02 6.567e-02 6.481e-02 1.017019e+03 3.944322e+03 1.714815e+02 -6.000000e+00 3.156279e+03 277.05 -2.00 20.00 -2.00 505.25 0.00e+00 7.476769e-03 1.797811e-03 3.915591e-04 -6.000000e+00 1.573600e-03 277.05 -2.00 20.00 -2.00 500.19 0.00e+00 2.286810e+00 1.341095e+00 5.839881e-02 -6.000000e+00 1.124501e+00 224.54 -2.00 3.45 -2.00 501.80 0.00e+00 20.262 0.142 489.00 513.00 1 9.4204e+00 1.0332e-01 3.6408e-02 -6.0000e+00 8.6353e-02 1.2668e-01 2.5920e-02 1.9831e-03 -6.0000e+00 2.1985e-02 6.9924e-06 7.9313e-04 7.1743e-03 1.7042e-04 -6.0000e+00 6.4246e-03 1.8350e-02 1.6860e-04 12 8 8 10 0 0 89.47 19.24 4.59 0.01835 0.02385 8 2 1 4 0 4000.000 24.75 19.99 19.24 2930 3890 -6642 -501 -11212 15546 -4739 9920 -7588 2688 497 -8491 3325 -761 2477 2806 687 -1608 -2807 1409 4883 5710 -1500 7598 -3829 2844 2947 2913 1739 2950 -2410 -5639 -2954 3718 3780 -1373 4410 -5060 -6637 -8555 -591 -1170 -2110 -5094 8914 5100 7748 4944 2962 -3784 -7793 5536 4555 10771 7551 4902 1587 -7411 -4958 -4735 5555 -7786 10366 2093 2500 -1770 -9247 507 -4327 3534 -6872 2600 -1123 406 68 14177 5559 -8842 1350 4196 2962 -9744 412 5995 1318 5286 5203 -227 -4952 -2940 -1464 4667 3395 -4251 -887 590 -1944 3083 4436 3024 -8082 -1278 -3044 -3519 6707 -917 -4769 17926 692 6292 -114 4780 2503 4106 2988 -3349 -6440 -5748 -6623 -7351 3577 -2580 -235 998 -5588 6286 1587 2199 5527 935 -2543 15961 1016 9439 3273 -965 1160 -7021 2824 -4863 -1454 2642 -6316 -291 -1776 14274 -6069 3575 -6085 0 2801 3746 -7127 -521 -13340 14445 -5464 9914 -8978 2830 525 -9663 3312 -780 2451 2781 705 -1720 -3086 1498 5027 5840 -1655 7695 -4371 3038 3122 3038 1790 2928 -2497 -6079 -3170 3833 3967 -1484 4473 -5594 -7403 -9723 -624 -1260 -2326 -5864 8999 5356 7873 5096 3053 -4073 -8528 5220 4332 9769 7254 4957 1688 -8689 -5683 -5420 5753 -9011 10262 2239 2634 -1869 -10350 520 -4479 3429 -7179 2476 -1118 400 68 12327 5057 -9166 1254 3777 2704 -10133 388 5368 1240 4783 4700 -215 -4938 -2889 -1434 4364 3250 -4400 -881 568 -1877 2760 3831 2612 -7802 -1169 -2895 -3420 5910 -845 -4521 13803 621 5418 -107 4354 2372 3879 2879 -3455 -6853 -6036 -6935 -7651 3302 -2522 -225 949 -5703 5716 1514 2084 5060 891 -2477 12731 930 7909 2935 -916 1096 -7123 2686 -4904 -1423 2489 -6523 -282 -1734 11676 -5956 3130 -5833 0 SO 20190201T053948.0Z 6971.235972 415 1 32.01 2 89.00 112.86 67.61 146.68 0.00 1 0.00 1 0 15 4.487e-02 4.385e-02 4.351e-02 4.307e-02 4.480196e+03 2.862975e+03 2.305401e+02 -6.000000e+00 2.529780e+03 277.05 -2.00 20.00 -2.00 505.31 0.00e+00 2.857987e-03 1.186431e-03 1.334710e-04 -6.000000e+00 1.261378e-03 277.05 -2.00 20.00 -2.00 500.26 0.00e+00 1.966602e+00 8.775249e-01 5.506332e-02 -6.000000e+00 9.021966e-01 224.54 -2.00 3.45 -2.00 501.88 0.00e+00 18.771 0.113 489.00 513.00 1 9.2881e+00 6.7315e-02 3.1368e-02 -6.0000e+00 6.9269e-02 9.6487e-02 1.6895e-02 1.9844e-03 -6.0000e+00 1.7658e-02 1.0701e-05 7.9169e-04 4.7400e-03 5.5049e-05 -6.0000e+00 5.1512e-03 8.3882e-03 1.5024e-04 12 8 8 10 0 0 -0.03 19.23 4.81 0.00839 0.01388 8 2 1 4 0 4000.000 24.75 19.99 19.23 2866 5058 7043 -7194 3407 -7201 -824 -3909 499 -2677 4508 -1531 1001 1169 -4390 2 -4128 2017 10704 -237 7094 -1238 -677 -5868 2 2942 -153 4929 -2272 224 -7425 -2427 3644 4262 1800 4651 -632 -7415 147 3703 -852 2968 -2326 -1897 -2325 3618 4546 2222 2276 -1041 -85 158 6064 5353 -3614 -2443 -5566 -2641 2532 6405 -4401 -1400 130 -2172 4948 -3456 1828 1256 3542 -9181 2855 7183 -5439 3801 -3398 4417 -319 1052 -1011 854 4123 -727 5989 -5734 1373 214 -4123 1498 -4031 10695 -4609 10826 2013 -2273 -1455 -6192 11609 -4692 -5051 4357 6775 -1723 -4603 562 3249 6815 -2056 -5597 -1757 -4615 -3958 -323 -2616 -2825 4765 1395 3706 1577 -3020 10526 -2302 7805 1348 3056 1099 -2608 6186 -1927 5001 -1445 -5733 -5551 568 5321 3523 2307 -9594 2732 2523 -8827 -1396 -781 3325 -2198 6618 -5137 1823 -5372 2268 8067 2649 4640 6516 -7918 3466 -8325 -908 -4471 544 -2985 4611 -1639 1031 1189 -4584 2 -4391 2060 10217 -256 7132 -1355 -739 -6775 2 3120 -166 5014 -2427 228 -8059 -2521 3639 4350 1920 4852 -692 -8602 156 3795 -917 3099 -2590 -2073 -2571 3868 4781 2300 2308 -1064 -84 153 5509 4959 -3752 -2570 -6148 -2857 2605 6339 -4862 -1505 138 -2344 4923 -3686 1821 1240 3375 -9832 2699 6525 -5653 3629 -3488 4152 -310 994 -966 800 3746 -697 5409 -5725 1286 204 -4096 1405 -3996 9193 -4659 9483 1938 -2274 -1423 -6215 9512 -4414 -4674 3633 5545 -1568 -4445 529 3020 6110 -1998 -5594 -1692 -4618 -3993 -319 -2610 -2850 4596 1367 3560 1544 -3065 9427 -2258 6863 1264 2829 1041 -2571 5588 -1886 4558 -1396 -5720 -5456 520 4636 3150 2123 -10132 2592 2429 -9606 -1419 -794 3254 -2272 6225 -5234 1740 -5293 2106 7110 SO 20190201T054343.0Z 6971.238692 419 1 32.04 2 88.29 113.46 67.20 147.53 0.00 1 0.00 1 0 15 3.231e-02 3.234e-02 2.714e-02 2.693e-02 6.718162e+03 1.880689e+03 3.738561e+02 -6.000000e+00 1.821255e+03 277.05 -2.00 20.00 -2.00 505.32 0.00e+00 2.590806e-03 7.491967e-04 1.368298e-04 -6.000000e+00 9.084500e-04 277.05 -2.00 20.00 -2.00 500.27 0.00e+00 1.516601e+00 5.519797e-01 6.752624e-02 -6.000000e+00 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