File name: Pandora119s1_Athens-NOA_20190206_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T144117.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190206_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190206T053110.0Z 6976.229977 461 1 32.01 2 89.72 110.31 100.96 99.56 0.00 1 0.00 1 0 22 1.701e-01 1.440e-01 1.206e-01 1.137e-01 3.364367e+03 7.438377e+03 4.820781e+02 -6.000000e+00 9.585512e+03 277.02 -2.00 20.00 -2.00 505.24 0.00e+00 2.517447e-03 3.137525e-03 1.916576e-04 -6.000000e+00 4.787839e-03 277.02 -2.00 20.00 -2.00 500.07 0.00e+00 3.208404e+00 2.337055e+00 4.604575e-02 -6.000000e+00 3.451731e+00 224.70 -2.00 3.45 -2.00 501.69 0.00e+00 20.237 0.142 489.00 513.00 1 9.9857e+00 1.7917e-01 3.5255e-02 -6.0000e+00 2.6446e-01 1.0226e-01 4.5604e-02 1.9843e-03 -6.0000e+00 6.8434e-02 3.8701e-06 4.4245e-03 1.2470e-02 1.0477e-04 -6.0000e+00 1.9588e-02 3.9684e-02 -6.1605e-04 12 9 8 11 8 0 -472.69 19.30 13.55 0.03968 0.07037 8 2 1 4 0 4000.000 24.86 20.00 19.30 900000 16114 10204 -13781 17601 -14041 23578 -1831 17297 793 -9803 21699 -5807 26900 -10805 18572 -12750 709 627 -11332 31976 -7181 26150 -9775 98 -3844 3025 4920 -19841 12498 -6605 30493 -740 17395 2975 -4401 12312 -4116 17497 -390 3625 614 -25553 8485 -7144 1220 -3794 8399 2700 -3169 28690 -8121 28609 -3754 -151 -18572 9725 6228 -15638 17697 -9312 43211 -855 10981 5217 -9154 11794 -24768 41377 860 24409 -19902 -659 13427 -5048 595 -13625 31511 854 1788 -356 -13211 24792 3172 33375 -12534 28798 -3553 -12880 14549 -17325 30079 3524 7922 -11806 -3615 40954 -10359 34306 -18168 1865 -15643 4725 26520 -8197 24775 -13865 5970 -4424 2610 -2313 97 3835 -1121 -1713 -6975 11371 -8022 -11695 16942 -17436 53235 1580 30333 -7 1493 33291 -11424 12649 -12320 17297 5574 7188 -5496 -598 28975 -11521 50257 -9262 13101 17423 -428 -174 -5941 8062 -18681 34977 632 -5680 -7644 900000 13857 9275 -16425 15787 -17706 20792 -2105 16450 883 -11979 19070 -6623 21860 -12715 16322 -15504 768 695 -13981 26465 -8586 23060 -12060 110 -4495 3289 5331 -26282 11999 -7336 23954 -785 16230 3199 -5159 12195 -4764 16152 -427 3814 669 -36543 8728 -8667 1366 -4448 8615 2880 -3502 22449 -8972 21631 -3939 -156 -23015 9519 6388 -19514 16232 -10902 30771 -923 10780 5244 -10481 11060 -32108 28010 840 19170 -23697 -651 11617 -5275 585 -15212 22624 803 1654 -336 -14259 18406 2944 23669 -13779 20969 -3571 -14197 12214 -20134 21987 3391 7306 -12818 -3643 25844 -10648 22041 -18916 1625 -16027 4155 19310 -8398 18817 -15016 5252 -4299 2376 -2241 93 3598 -1118 -1731 -7477 10193 -8732 -13122 14102 -20194 30858 1491 21534 -7 1426 23171 -12436 10811 -13151 13965 4997 6264 -5401 -561 20490 -12142 29802 -9861 11562 14843 -428 -175 -6325 7445 -22325 24636 601 -5677 -7786 SO 20190206T053524.0Z 6976.232917 465 1 32.01 2 88.94 110.97 100.15 100.16 0.00 1 0.00 1 0 71 1.169e-01 1.132e-01 9.155e-02 8.882e-02 -2.097714e+03 5.175092e+03 2.304830e+02 -6.000000e+00 6.592235e+03 277.02 -2.00 20.00 -2.00 505.22 0.00e+00 6.153898e-03 2.437574e-03 3.559898e-04 -6.000000e+00 3.288220e-03 277.02 -2.00 20.00 -2.00 500.17 0.00e+00 4.411357e-01 1.810687e+00 5.699773e-02 -6.000000e+00 2.355884e+00 224.70 -2.00 3.45 -2.00 501.79 0.00e+00 18.637 0.111 489.00 513.00 1 1.0128e+01 1.3961e-01 3.1948e-02 -6.0000e+00 1.8083e-01 1.5624e-01 3.5024e-02 1.7372e-03 -6.0000e+00 4.6195e-02 5.0175e-06 1.7893e-02 9.8747e-03 1.5991e-04 -6.0000e+00 1.3429e-02 -2.1040e-02 1.9440e-04 12 9 8 11 8 0 98.88 19.31 3.82 -0.02104 0.10307 8 2 1 4 0 4000.000 24.86 20.00 19.31 10757 -6675 13064 -16763 10149 -4428 6584 -7265 1127 3608 -14160 13364 -11622 6633 4650 428 16451 -8925 1892 -527 3487 5920 6317 -7483 -13271 11948 -11210 7817 -4074 11757 4227 -1346 3358 -12618 4813 -6334 4451 11525 -3509 13013 -4836 10284 -5192 17424 4186 -2106 14405 1170 10993 -3838 10352 -10163 11253 18814 -15391 14469 -2381 20122 -12989 13995 7864 -6392 -2918 -8357 5920 -10116 18502 -3081 394 7504 -19898 11574 -17101 19345 1288 3349 -83 7986 14209 -24941 25347 -4260 9170 3598 -5132 6040 -12461 29308 125 29162 -109 12470 8000 -13419 18475 -22252 19903 -6974 18345 12633 -1612 15882 -22593 12991 -462 11519 6012 728 -4210 -9495 22991 -18274 7039 1742 6306 6181 -7749 2194 -8223 5741 -7973 12685 2183 -330 22331 -10721 5593 -18275 9109 -3033 3007 13922 1952 27919 1067 6184 -1194 -2416 23558 554 11954 -541 -585 -10595 4392 -5919 -1389 5593 -22320 48 9589 -7270 12046 -21410 10121 -5187 6954 -8784 1238 3802 -17058 12353 -13613 6428 4605 447 14897 -10323 1984 -569 3617 6007 6409 -8757 -16473 11466 -13376 7537 -4311 10447 4056 -1390 3399 -15316 4949 -7254 4536 10849 -3825 12070 -5416 10034 -5993 16201 4458 -2378 13625 1240 10323 -4079 9365 -10931 10129 16072 -18512 13520 -2593 18019 -15797 13023 7809 -7332 -3223 -9660 5853 -11558 15648 -3191 390 6866 -23977 10253 -20340 16016 1267 3184 -81 7093 11827 -30008 19005 -4316 8165 3405 -5314 5593 -13528 21517 120 21801 -108 11354 7485 -15532 15790 -27402 16122 -7041 14492 10515 -1523 12820 -27233 11023 -445 9724 5310 678 -4167 -10102 18058 -21567 6708 1766 6133 6011 -8388 2177 -8710 5359 -8276 10984 2109 -320 17734 -11560 5117 -21181 8186 -2968 2726 11419 1744 19742 974 5448 -1148 -2375 17952 533 10276 -528 -571 -11357 3990 -5830 -1280 4749 -25111 44 SO 20190206T053935.1Z 6976.235823 469 1 32.20 2 88.17 111.62 99.36 100.76 0.00 1 0.00 1 0 15 6.507e-02 6.365e-02 6.373e-02 6.284e-02 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