File name: Pandora119s1_Athens-NOA_20190325_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T150715.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190325_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190325 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190325T042717.0Z 7023.185613 229 1 32.01 2 89.71 88.09 64.04 218.31 0.00 1 0.00 1 0 15 5.509e-02 5.408e-02 6.223e-02 6.155e-02 6.728737e+03 4.295247e+03 2.556225e+02 -6.000000e+00 3.137397e+03 279.53 -2.00 20.00 -2.00 505.31 0.00e+00 2.509645e-03 1.707504e-03 1.534996e-04 -6.000000e+00 1.559523e-03 279.53 -2.00 20.00 -2.00 500.33 0.00e+00 2.857623e+00 1.259580e+00 9.689810e-02 -6.000000e+00 1.118002e+00 227.19 -2.00 3.45 -2.00 501.93 0.00e+00 20.163 0.140 489.00 513.00 1 9.3681e+00 9.6389e-02 3.5693e-02 -6.0000e+00 8.5741e-02 7.2207e-02 2.4146e-02 2.5798e-03 -6.0000e+00 2.2125e-02 7.5578e-06 6.5724e-03 6.6964e-03 6.3464e-05 -6.0000e+00 6.3460e-03 -3.8439e-02 4.4380e-06 12 8 8 10 0 0 44.95 19.19 1.74 -0.03844 0.00715 8 2 1 4 0 4000.000 24.75 20.00 19.19 900000 662 -3166 193 -4067 747 -62 -1755 6493 -4442 9726 -1706 -1529 -4723 1995 4728 -3495 -4363 998 -8213 1522 -666 10970 6161 2097 -7491 -622 4054 1934 5320 -4248 3125 8920 13218 -3807 997 6054 -2163 2747 -2479 7779 -4855 -3627 4879 751 7150 -4283 1073 -6160 1273 1484 -5595 -6070 -4614 673 -9655 244 -5977 3605 4663 -1541 3572 -5712 5363 1320 7781 -2510 2990 -3244 -3319 7424 2800 -1327 -3511 2267 1019 1263 5990 -1773 841 -5973 8273 -1183 -3328 -669 -3113 4187 -4603 3074 5311 -2198 9077 -4857 -634 -11761 -2629 1008 -1097 13005 -6567 5292 -7626 4124 -3217 705 -7928 3891 -5090 -11467 942 8984 5289 4847 -3317 6916 -6114 13141 -5077 5087 1234 1196 8741 2523 12070 624 242 -1363 -7111 2789 8639 3374 728 1338 4473 2620 -3979 -3043 9436 9623 6254 -5073 -7736 -3230 2075 -4038 -6636 8759 -11834 8497 -2848 900000 627 -3115 190 -4292 769 -66 -1905 6492 -4913 9214 -1787 -1578 -4977 1956 4532 -3688 -4743 1050 -9605 1625 -730 10724 6345 2260 -8892 -686 4213 2010 5218 -4517 3095 8493 12397 -4220 1063 6122 -2354 2820 -2668 7566 -5398 -4027 5032 814 7286 -4868 1142 -6915 1295 1469 -5823 -6298 -4758 673 -10987 256 -6755 3712 4752 -1673 3695 -6330 5440 1382 7532 -2584 2945 -3272 -3312 6784 2617 -1302 -3551 2171 980 1194 5319 -1684 775 -5898 7122 -1127 -3266 -644 -3088 3863 -4628 2859 4844 -2177 8115 -5024 -626 -12784 -2548 918 -994 10019 -6079 4364 -7300 3625 -3143 659 -8127 3525 -5009 -12009 878 7835 4854 4520 -3385 6418 -6511 11616 -5392 4848 1207 1154 7740 2371 10350 603 236 -1351 -7468 2650 7713 3147 688 1245 4027 2420 -3896 -3010 8591 8874 5890 -5397 -8508 -3413 2082 -4290 -7156 7961 -12998 7552 -2846 SO 20190325T043136.0Z 7023.188611 233 1 32.01 2 88.86 88.75 64.57 219.27 0.00 1 0.00 1 0 22 3.277e-02 3.265e-02 3.859e-02 3.836e-02 3.317925e+03 2.483600e+03 1.283203e+02 -6.000000e+00 1.866832e+03 279.53 -2.00 20.00 -2.00 505.30 0.00e+00 3.324953e-03 1.060559e-03 1.931124e-04 -6.000000e+00 9.266271e-04 279.53 -2.00 20.00 -2.00 500.40 0.00e+00 1.226517e+00 7.786728e-01 5.598364e-02 -6.000000e+00 6.597099e-01 227.19 -2.00 3.45 -2.00 502.00 0.00e+00 18.388 0.106 489.00 513.00 1 9.2416e+00 5.9765e-02 3.0674e-02 -6.0000e+00 5.0689e-02 9.8921e-02 1.5003e-02 1.8736e-03 -6.0000e+00 1.2907e-02 1.2389e-05 1.2402e-03 4.2497e-03 8.0970e-05 -6.0000e+00 3.7625e-03 -3.4768e-02 4.6821e-04 12 8 8 10 0 0 29.39 19.18 5.10 -0.03477 -0.02617 8 2 1 4 0 4000.000 24.75 20.00 19.18 -1807 -3503 -138 -1135 -149 -4231 -935 -2562 -2717 1252 -5756 3047 -1424 7306 1987 1024 5940 1081 -3303 -3045 -1372 -2569 1285 6942 -866 5913 -936 -322 -3939 108 -2010 -633 1201 -4855 1356 2072 4952 1169 2448 4713 -1492 2461 -779 -68 1470 2865 -591 948 4608 -5207 -196 1121 6024 3352 -3981 -6147 -4044 3542 2368 5012 6776 3380 -2153 -6642 -1488 -578 -1740 25 -2992 -15 2551 -127 -2438 7136 -520 563 4172 -1341 8269 -1644 2583 -7939 -403 5529 2365 -4064 -2282 2985 -5700 -1936 5004 -1522 -2 -2733 901 -2840 2476 572 732 2887 -2964 -878 -1857 4455 -4255 -1492 -241 3033 1264 -441 4579 1781 3713 545 611 2597 -4173 1139 2789 950 -4250 -1916 -961 5588 484 -1672 -558 3296 -1452 950 -1805 1399 774 2115 523 372 1979 1547 -889 -167 -3672 -2868 3516 -3650 1772 2514 -5771 -1126 -7592 4800 -1735 -3476 -136 -1167 -156 -4591 -997 -2793 -2957 1295 -6291 3004 -1448 6738 1927 1009 5656 1103 -3587 -3334 -1483 -2818 1360 6972 -943 6018 -1013 -341 -4226 109 -2044 -639 1217 -5376 1439 2194 5069 1232 2524 4737 -1561 2500 -827 -73 1556 2991 -634 988 4538 -5519 -193 1070 5463 3165 -4149 -6712 -4400 3602 2440 5035 6705 3472 -2339 -7514 -1582 -601 -1802 25 -3056 -15 2433 -125 -2477 6639 -522 554 3901 -1277 7273 -1556 2351 -8079 -383 4993 2220 -4083 -2253 2794 -5827 -1917 4670 -1535 -2 -2802 878 -2820 2277 523 656 2507 -2744 -813 -1787 4125 -4346 -1479 -234 2827 1201 -421 4225 1716 3555 544 613 2571 -4429 1142 2720 931 -4332 -1895 -942 5151 472 -1667 -551 3124 -1440 914 -1764 1306 720 1936 491 355 1893 1509 -899 -169 -3781 -2943 3396 -3784 1727 2395 -5857 -1073 -7671 4313 SO 20190325T043545.0Z 7023.191493 237 1 32.01 2 88.04 89.39 65.08 220.17 0.00 1 0.00 1 0 15 2.200e-02 2.191e-02 2.277e-02 2.267e-02 3.794782e+03 1.486066e+03 4.142577e+02 -6.000000e+00 1.252708e+03 279.53 -2.00 20.00 -2.00 505.32 0.00e+00 2.531974e-03 6.285088e-04 1.175150e-04 -6.000000e+00 6.224140e-04 279.53 -2.00 20.00 -2.00 500.37 0.00e+00 1.545901e+00 4.605177e-01 1.716533e-02 -6.000000e+00 4.447128e-01 227.19 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