File name: Pandora119s1_Athens-NOA_20190403_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T153040.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190403_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190403 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190403T041336.0Z 7032.176111 384 1 32.01 2 89.71 83.64 82.68 107.32 0.00 1 0.00 1 0 15 1.242e-01 1.135e-01 1.018e-01 9.857e-02 9.486692e+03 7.137196e+03 7.543848e+02 -6.000000e+00 7.094326e+03 280.42 -2.00 20.00 -2.00 505.38 0.00e+00 3.983112e-03 2.792102e-03 2.157438e-04 -6.000000e+00 3.524795e-03 280.42 -2.00 20.00 -2.00 500.41 0.00e+00 1.554258e+00 2.032435e+00 4.164365e-02 -6.000000e+00 2.529149e+00 227.89 -2.00 3.45 -2.00 502.03 0.00e+00 20.147 0.140 489.00 513.00 1 9.9107e+00 1.5584e-01 3.5264e-02 -6.0000e+00 1.9387e-01 8.1668e-02 3.9736e-02 2.1876e-03 -6.0000e+00 5.0279e-02 4.6434e-06 -9.4338e-03 1.0752e-02 1.1548e-04 -6.0000e+00 1.4308e-02 2.7466e-02 -6.9061e-04 12 8 8 10 0 0 83.51 19.57 11.11 0.02747 -0.03797 8 2 1 4 0 4000.000 25.07 20.00 19.57 900000 12583 -472 -488 17030 -7318 -2679 -15785 20228 -822 1351 8033 4428 4064 -6289 23874 -10092 9334 -12076 -7954 -122 -17395 9548 -9188 18842 235 -2319 7887 7360 4373 9087 28372 -14532 3909 3523 -12690 20377 -9090 5052 2932 -7939 1550 -8356 7786 -11216 12224 -1151 2546 -3078 2066 -864 -16994 21944 -13428 21524 -13182 8164 7051 3415 22478 -6958 12526 13969 15855 1902 -645 476 -18937 3607 3316 4212 5066 6401 3925 -4540 18562 -9352 13544 -6244 16418 698 -4148 18656 -21960 22304 -15285 18458 -9995 -10246 -5190 -4149 13461 1676 32347 4332 15132 -1274 -7508 10142 -17291 35513 4449 -167 5710 -1430 22046 -1340 5618 -2088 7692 -938 10486 9502 -13524 14003 -5886 27033 -8836 253 -5243 -15373 12495 -1697 11076 -13503 -1608 -7560 -18980 -77 -15398 9779 133 -9681 957 -1979 -5603 7922 44416 4135 10134 1832 4631 -3134 -8795 6173 3029 23112 1409 11569 -12316 900000 10246 -441 -467 14134 -7983 -2860 -19569 17685 -888 1418 7778 4380 3978 -6746 18817 -11194 8624 -13718 -8853 -131 -21749 9395 -10647 17014 250 -2540 7776 7220 4334 8383 21770 -16654 3785 3518 -15285 17865 -10695 5122 3010 -9039 1607 -9640 7736 -13652 11898 -1287 2736 -3465 2174 -916 -20113 17677 -14862 17339 -14949 7883 7042 3492 19592 -7942 11786 13005 14525 2001 -691 499 -23726 3554 3235 4026 4766 5943 3761 -4778 15581 -10327 11737 -6493 13456 665 -4149 14920 -25871 17451 -17122 15219 -10963 -10957 -5262 -4167 11699 1656 23707 4089 12964 -1224 -7467 8437 -18033 22071 3768 -147 4880 -1360 17468 -1323 5168 -2062 6871 -920 9290 8625 -15639 12407 -6408 21341 -10068 265 -5772 -18067 11221 -1733 9894 -15075 -1602 -8031 -22664 -76 -17734 8947 130 -10283 904 -1915 -5649 7072 28737 3974 9309 1851 4592 -3381 -10088 6107 3082 19052 1420 10354 -13837 SO 20190403T041756.0Z 7032.179120 388 1 32.01 2 88.86 84.31 81.88 108.00 0.00 1 0.00 1 0 15 5.887e-02 5.779e-02 4.663e-02 4.619e-02 5.499142e+03 3.088837e+03 1.558340e+02 -6.000000e+00 3.363214e+03 280.42 -2.00 20.00 -2.00 505.33 0.00e+00 7.529173e-04 1.292589e-03 6.125341e-05 -6.000000e+00 1.670402e-03 280.42 -2.00 20.00 -2.00 500.55 0.00e+00 9.983085e-02 9.290458e-01 8.779510e-02 -6.000000e+00 1.197426e+00 227.89 -2.00 3.45 -2.00 502.14 0.00e+00 18.383 0.106 489.00 513.00 1 9.5429e+00 7.1151e-02 3.0822e-02 -6.0000e+00 9.1811e-02 9.0932e-02 1.8106e-02 2.2376e-03 -6.0000e+00 2.3767e-02 1.0254e-05 1.8790e-03 5.1292e-03 2.0256e-05 -6.0000e+00 6.7814e-03 5.1816e-02 -7.2510e-04 12 8 8 10 0 0 -32.67 19.58 4.35 0.05182 0.06485 8 2 1 4 0 4000.000 25.07 20.00 19.58 900000 8146 3403 -9576 6711 4466 -4478 -3694 -2074 2329 -7939 4473 -3742 3361 -8845 7380 2755 -470 8153 -11900 8116 -1162 4132 -1529 -3635 2228 -3883 3220 -8319 5542 -1005 -5798 -2699 1148 9902 -3680 2812 2339 3776 13455 -1633 2157 -3682 7875 -3855 1011 -4936 4323 -508 -2784 11368 -2876 2871 1495 -1460 -659 -5035 7794 -4947 6162 -3541 3728 2480 -4522 10403 -1929 7118 1238 8453 -2658 -4358 11468 -2116 3996 -8883 -4626 2007 -6493 6090 -3575 16774 -6334 2275 -5444 1164 -3030 1291 2839 -8221 4961 -5031 6452 -5439 10130 3109 -12788 9374 -4274 5392 -2577 2055 1115 -1622 10087 -863 3463 1136 -461 4493 -6506 3240 -5394 6074 2956 4184 -2762 -6271 6291 -7482 9068 -1559 7786 -299 12505 -160 -8445 6629 -9494 3385 1276 11886 -11531 -556 4229 -6020 2685 -996 1830 -2937 2526 -1230 -6576 6902 -6429 1230 -3184 8728 69 -1494 870 900000 6829 3055 -10091 6193 4323 -4837 -4011 -2225 2379 -8887 4362 -3908 3230 -9533 6767 2673 -480 7815 -13821 7992 -1228 4152 -1631 -3973 2301 -4249 3251 -9257 5241 -995 -5994 -2741 1151 9340 -4039 2897 2405 3789 12161 -1712 2188 -3994 7693 -4277 1074 -5549 4389 -533 -2923 10104 -2879 2678 1417 -1415 -651 -5320 7353 -5333 5953 -3773 3707 2505 -4901 9662 -2006 6667 1213 7611 -2646 -4383 9847 -2097 3766 -9597 -4783 1920 -6670 5456 -3510 13454 -6441 2142 -5592 1131 -3098 1270 2756 -8701 4616 -5208 6017 -5769 9212 3006 -14226 8163 -4160 4660 -2375 1803 1002 -1541 8828 -866 3367 1129 -462 4255 -6894 3147 -5786 5880 2978 4193 -2914 -6891 6263 -8311 8647 -1591 7312 -296 11124 -158 -9099 6150 -10341 3234 1241 10322 -12498 -533 3836 -6058 2506 -982 1787 -3054 2517 -1284 -7291 6722 -7176 1269 -3406 8163 69 -1497 848 SO 20190403T042208.0Z 7032.182037 392 1 32.01 2 88.04 84.95 81.11 108.66 0.00 1 0.00 1 0 15 1.270e-02 1.263e-02 1.249e-02 1.244e-02 3.449029e+03 7.934718e+02 1.639807e+02 -6.000000e+00 7.256508e+02 280.42 -2.00 20.00 -2.00 505.40 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