File name: Pandora119s1_Athens-NOA_20190407_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T153121.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190407_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190407 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190407T040737.0Z 7036.171956 386 1 32.01 2 89.72 81.71 104.92 65.63 0.00 1 0.00 1 0 15 9.336e-02 8.981e-02 8.012e-02 7.836e-02 2.866339e+03 5.081732e+03 1.070111e+02 -6.000000e+00 5.344351e+03 280.81 -2.00 20.00 -2.00 505.28 0.00e+00 2.973953e-03 2.175283e-03 1.804614e-04 -6.000000e+00 2.648002e-03 280.81 -2.00 20.00 -2.00 500.21 0.00e+00 2.819358e+00 1.611301e+00 6.678306e-02 -6.000000e+00 1.883052e+00 228.20 -2.00 3.45 -2.00 501.84 0.00e+00 20.146 0.140 489.00 513.00 1 9.6100e+00 1.2356e-01 3.5322e-02 -6.0000e+00 1.4470e-01 9.9749e-02 3.1466e-02 2.1912e-03 -6.0000e+00 3.6918e-02 5.9035e-06 -2.1821e-02 8.6515e-03 7.9746e-05 -6.0000e+00 1.0725e-02 -7.5914e-03 1.7182e-04 12 9 8 11 8 0 -600.71 19.50 2.07 -0.00759 -0.15895 8 2 1 4 0 4000.000 24.96 20.00 19.50 4845 -12524 8733 139 4111 928 8010 6971 -6387 7351 -1304 8075 -10383 -5546 -840 4989 3752 -16686 12810 -11991 11229 -6800 -2290 2735 -2599 9753 -13128 8497 1000 13386 6661 -5149 15446 -6979 20851 -5783 1668 -4958 2715 9795 -4253 25368 -14459 174 -5966 5017 8805 837 6635 -5505 9568 2668 3705 6448 -4370 8606 -4284 2886 -9655 3407 7101 -6555 -3311 -11056 14069 -10297 4933 -5015 -1129 17189 -12044 -4888 2040 22108 -2080 -1315 8323 826 13208 -13863 17880 -4857 9160 1498 -9970 442 -10773 6281 -8184 2130 6845 6938 4902 -550 17928 -11934 7052 -10656 1740 -3897 51 10639 -8794 26449 -17264 6746 2629 -11746 15793 -4594 4858 -11636 703 4964 15497 16761 11474 90 -16162 15838 -6976 8475 5395 10922 13721 -4497 14964 -4577 970 -9958 -1799 4115 -9013 -2627 -1841 5976 878 -5029 5101 -362 4162 -7303 7430 -11668 -303 10059 2629 9067 -11089 2917 4524 -13695 7774 138 4052 972 8011 7175 -7394 7627 -1425 8144 -12083 -6062 -865 4948 3677 -20295 11828 -14487 10912 -7969 -2573 2929 -2946 9813 -16630 8635 1083 12549 6514 -5566 13575 -7798 18114 -6719 1820 -5770 2901 9658 -4795 21270 -17704 186 -6859 5214 9072 906 6700 -6166 9241 2621 3523 5903 -4482 7912 -4596 2943 -11290 3507 7046 -7458 -3657 -13212 13045 -12081 4904 -5420 -1156 14449 -13396 -5023 1956 17452 -2109 -1328 7586 800 11129 -14767 14149 -4828 7952 1412 -10352 416 -11414 5618 -8451 1983 6096 6218 4535 -543 14727 -13102 6294 -11106 1563 -3620 45 8392 -8541 18530 -19252 6021 2452 -12558 12701 -4515 4373 -12224 680 4668 13266 14283 10373 89 -18854 13649 -7276 7661 4859 9286 11382 -4496 12357 -4603 923 -10554 -1752 3745 -9231 -2494 -1724 5192 814 -5039 4699 -357 3967 -7863 6943 -12946 -308 9192 2560 8133 -11656 2698 SO 20190407T041155.0Z 7036.174942 390 1 32.01 2 88.88 82.37 104.16 66.35 0.00 1 0.00 1 0 15 4.203e-02 4.173e-02 4.082e-02 4.039e-02 5.876354e+03 2.820795e+03 4.329618e+02 -6.000000e+00 2.405749e+03 280.81 -2.00 20.00 -2.00 505.28 0.00e+00 2.821782e-03 1.127518e-03 1.315484e-04 -6.000000e+00 1.192011e-03 280.81 -2.00 20.00 -2.00 500.17 0.00e+00 2.078513e+00 8.313094e-01 4.244372e-02 -6.000000e+00 8.477276e-01 228.20 -2.00 3.45 -2.00 501.80 0.00e+00 18.413 0.107 489.00 513.00 1 9.2203e+00 6.3907e-02 3.0475e-02 -6.0000e+00 6.5137e-02 9.9175e-02 1.5958e-02 1.9203e-03 -6.0000e+00 1.6624e-02 1.1812e-05 3.5153e-03 4.4189e-03 6.2562e-05 -6.0000e+00 4.8292e-03 6.4636e-02 -2.7413e-04 12 8 8 10 0 0 -57.84 19.50 5.21 0.06464 0.08902 8 2 1 4 0 4000.000 24.96 20.00 19.50 -6327 3574 -4441 647 624 -1764 -959 -1144 6444 -4391 797 -6147 1009 6112 286 9903 -5879 3503 948 2058 4584 238 1622 -5563 -2494 1927 5463 -548 3426 -866 626 -958 -5684 1134 1285 5619 -196 -5391 390 351 8668 -2235 -3281 1605 -1390 -2059 -4968 1608 -3721 1719 -2730 -1089 174 -3309 13515 2260 2366 1634 2227 1741 -7285 6948 -10008 -373 2702 2186 -4911 -339 6104 1556 4399 -8925 11381 -3726 5933 8701 -2386 -118 -2698 3988 1278 5609 261 -1804 -3973 -2388 2091 5252 3752 1391 2176 -4953 -5955 -1388 -4304 6233 -2469 5627 -706 212 1192 -7540 3413 -1476 822 4630 -7353 3700 -1355 5286 -3528 2461 -1488 -495 6818 -1112 2927 -8943 438 -885 578 -2524 -608 3636 2800 3343 -1876 8735 -2029 1421 -3217 1089 3345 -1627 -705 -1799 3349 -350 7001 -3162 -6113 256 -1547 1074 1791 -1175 3298 -2922 3590 -5032 -6509 3386 -4694 671 664 -1964 -1047 -1259 6717 -4914 834 -6799 1025 5842 289 9394 -6466 3582 1013 2196 4791 260 1755 -6491 -2831 2090 5676 -595 3490 -900 634 -995 -6327 1212 1397 5872 -216 -6192 419 376 8575 -2425 -3639 1713 -1539 -2293 -5652 1687 -4035 1721 -2787 -1076 169 -3378 11953 2292 2437 1707 2315 1818 -8346 6921 -11812 -398 2764 2215 -5256 -342 5694 1504 4116 -9580 10054 -3855 5570 7859 -2369 -113 -2565 3625 1197 5060 244 -1736 -3934 -2335 1953 4744 3440 1312 2054 -5072 -6185 -1367 -4291 5462 -2300 4714 -618 182 1023 -7227 3027 -1413 780 4227 -7508 3361 -1296 4780 -3451 2298 -1460 -485 6250 -1110 2818 -9673 427 -862 548 -2444 -578 3323 2591 3083 -1824 7629 -1969 1324 -3103 993 2956 -1510 -654 -1717 3092 -340 6411 -3235 -6334 250 -1545 1044 1716 -1143 3010 -2794 3274 -4918 SO 20190407T041604.0Z 7036.177824 394 1 32.01 2 88.07 83.00 103.43 67.03 0.00 1 0.00 1 0 15 2.373e-02 2.367e-02 1.691e-02 1.681e-02 7.797154e+03 1.194499e+03 4.318971e+02 -6.000000e+00 1.357721e+03 280.81 -2.00 20.00 -2.00 505.32 0.00e+00 2.876331e-03 4.713144e-04 1.588593e-04 -6.000000e+00 6.733022e-04 280.81 -2.00 20.00 -2.00 500.34 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