File name: Pandora119s1_Athens-NOA_20190417_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T153226.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190417_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190417T035317.0Z 7046.162002 235 1 32.01 2 89.72 77.04 102.39 286.93 0.00 1 0.00 1 0 15 8.726e-02 8.122e-02 8.229e-02 8.051e-02 1.514197e+04 6.339033e+03 9.028287e+02 -6.000000e+00 5.013434e+03 281.81 -2.00 20.00 -2.00 505.31 0.00e+00 -3.957824e-04 2.248119e-03 7.343467e-05 -6.000000e+00 2.480635e-03 281.81 -2.00 20.00 -2.00 500.19 0.00e+00 8.249346e-01 1.662272e+00 1.128901e-01 -6.000000e+00 1.762025e+00 228.98 -2.00 3.45 -2.00 501.82 0.00e+00 20.126 0.139 489.00 513.00 1 9.8086e+00 1.2761e-01 3.5945e-02 -6.0000e+00 1.3541e-01 1.1438e-01 3.1713e-02 3.1768e-03 -6.0000e+00 3.4597e-02 5.7706e-06 -7.4703e-06 8.1329e-03 6.1464e-05 -6.0000e+00 1.0028e-02 8.3108e-02 -4.6269e-04 12 8 8 10 0 0 -327.21 19.37 5.68 0.08311 0.08306 8 2 1 4 0 4000.000 24.86 20.00 19.37 12044 10964 6246 -4126 -2916 2384 -8618 7539 -1181 3708 -7879 -289 11777 8950 12887 -15861 14955 -5479 -4444 -4345 -5 12254 -1217 12933 -10718 -1721 -4542 576 12794 -7759 -3825 1949 6185 -3090 -7193 14802 -9314 11776 -5679 371 -7274 5396 -544 588 10743 -932 14168 -7980 -6178 -2854 3187 11770 -3751 14071 -5489 8439 -1803 479 -3659 5619 2333 -7097 815 -6358 2583 17352 -289 -1884 -12564 1375 -9773 2105 3426 16 24268 -12500 20663 -3783 -3244 -1652 -7791 2594 1820 -604 -11168 -3858 3145 7399 -2694 -12093 17186 4693 -3521 671 -1227 -403 6989 -116 -12786 15549 4779 17085 -11584 -5003 -3472 -4112 12982 -5416 1014 -2738 7764 9097 -6424 -1048 8531 18032 -4815 23896 -6705 8375 22197 -12642 179 -4765 -2471 -6292 -110 3898 -6835 -5293 -6364 -2424 -3001 20027 10239 -7336 13730 3900 5259 -5037 -4903 7146 -4670 11041 -3613 2292 -4038 11131 -6073 1431 10194 9491 5820 -4398 -3159 2506 -10019 7731 -1322 3921 -8996 -302 11048 8548 11787 -18932 13678 -6119 -5019 -4970 -6 11982 -1364 12619 -13283 -1947 -5252 624 12005 -8730 -4082 1971 6112 -3445 -8541 14227 -11350 11514 -6543 400 -8240 5556 -599 630 10750 -1022 13618 -9200 -6860 -2990 3062 10433 -3755 12210 -5773 7920 -1911 501 -3997 5592 2402 -8053 855 -7150 2634 15057 -294 -1925 -14104 1329 -10517 2018 3270 16 19046 -14058 16426 -3780 -3189 -1590 -7990 2413 1723 -578 -12004 -3880 2952 6639 -2667 -13165 14391 4369 -3555 640 -1161 -366 5692 -98 -12104 11291 3808 12399 -11697 -4944 -3485 -4208 11188 -5575 976 -2748 7074 8234 -6649 -1056 7841 15185 -5021 19274 -7134 7746 17554 -13597 168 -4703 -2392 -6343 -104 3547 -6904 -5235 -6294 -2276 -2812 14912 8491 -7382 11412 3639 4917 -5292 -5198 6764 -4996 10090 -3803 2249 -4057 9702 -6091 1368 SO 20190417T035738.0Z 7046.165023 239 1 32.01 2 88.88 77.71 103.18 287.61 0.00 1 0.00 1 0 15 5.437e-02 5.392e-02 4.630e-02 4.578e-02 3.151310e+03 3.010247e+03 4.035434e+02 -6.000000e+00 3.124191e+03 281.81 -2.00 20.00 -2.00 505.33 0.00e+00 2.466779e-03 1.276321e-03 1.355968e-04 -6.000000e+00 1.546833e-03 281.81 -2.00 20.00 -2.00 500.25 0.00e+00 2.996025e+00 9.345371e-01 2.624018e-02 -6.000000e+00 1.100991e+00 228.98 -2.00 3.45 -2.00 501.88 0.00e+00 18.409 0.107 489.00 513.00 1 9.2842e+00 7.1741e-02 3.0342e-02 -6.0000e+00 8.4567e-02 6.6250e-02 1.8108e-02 1.6766e-03 -6.0000e+00 2.1681e-02 1.0423e-05 -5.2484e-05 5.0765e-03 7.9634e-05 -6.0000e+00 6.2432e-03 1.0308e-02 -2.5669e-04 12 8 8 10 0 0 54.24 19.37 7.33 0.01031 0.00994 8 2 1 4 0 4000.000 24.86 20.00 19.37 -6066 5694 -9053 9809 2621 1192 -2942 -5600 6347 1197 2762 1232 3073 1647 -667 5417 -2684 9447 -5161 -1665 753 -4468 3325 -5384 1513 -8662 6813 4557 -2583 3259 -9786 8122 -2142 1485 3265 -948 -436 -4417 688 -2586 3080 -845 6319 1712 -2561 6779 5024 506 -3491 -894 -1398 3426 4725 -7439 3831 -6998 4992 833 2453 7070 -10137 2979 -7845 2562 -433 358 4410 -10193 8794 -3584 2855 -5476 4818 1426 -471 2425 -4373 2991 -5964 2743 4257 4853 2170 5494 9806 -6140 5732 -3537 -3135 -1760 -9650 8899 2974 10178 1677 3514 7598 -8201 4004 -10241 8860 -2613 1280 1337 5289 4314 -7846 5711 -6324 3226 -2046 -5369 223 -1794 3909 -9532 1634 -1949 6129 8112 -5032 10111 -7901 10922 -4901 3990 -6318 4010 6028 -5006 4491 -8827 6495 -2937 3075 -2058 -2687 1470 -2618 6976 -9548 1284 -4432 912 5909 -6757 11307 522 5668 1695 -6036 5062 -9544 8835 2615 1236 -3244 -6419 6473 1277 2866 1280 3091 1660 -683 5231 -2842 9033 -5686 -1801 801 -5026 3469 -6150 1620 -10292 6912 4680 -2796 3247 -10896 7539 -2234 1534 3399 -1044 -477 -4994 732 -2823 3174 -911 6403 1837 -2896 7009 5270 550 -3878 -946 -1449 3306 4446 -7734 3626 -7573 4899 864 2511 6914 -11778 3043 -8947 2629 -454 368 4288 -11293 7949 -3621 2683 -5588 4463 1379 -466 2322 -4424 2767 -5966 2501 3824 4354 2013 4966 8556 -6167 5251 -3468 -3060 -1699 -10147 7857 2814 8987 1600 3237 6575 -8112 3426 -9938 7076 -2370 1146 1232 4780 3960 -8087 5092 -6331 2950 -1999 -5510 220 -1824 3785 -10374 1638 -1977 5841 7491 -5105 8939 -8135 9572 -4936 3691 -6491 3718 5473 -5063 4101 -9097 5675 -2801 2769 -1976 -2646 1415 -2664 6527 -10626 1290 -4743 928 5712 -7347 10096 509 5188 1613 SO 20190417T040151.0Z 7046.167951 243 1 32.01 2 88.07 78.35 103.95 288.28 0.00 1 0.00 1 0 15 2.802e-02 2.809e-02 2.528e-02 2.517e-02 5.815389e+03 1.719143e+03 3.363136e+02 -6.000000e+00 1.609997e+03 281.81 -2.00 20.00 -2.00 505.33 0.00e+00 2.946135e-03 7.065469e-04 1.477422e-04 -6.000000e+00 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