File name: Pandora119s1_Athens-NOA_20190422_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T153209.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190422_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190422T034632.0Z 7051.157315 212 1 32.01 2 89.72 74.83 70.94 225.60 0.00 1 0.00 1 0 15 1.083e-01 1.008e-01 1.142e-01 1.115e-01 6.328074e+03 7.825228e+03 2.871123e+02 -6.000000e+00 6.235604e+03 282.33 -2.00 20.00 -2.00 505.30 0.00e+00 -1.473518e-03 3.120743e-03 9.640087e-05 -6.000000e+00 3.087348e-03 282.33 -2.00 20.00 -2.00 500.39 0.00e+00 2.031927e+00 2.294015e+00 1.708458e-01 -6.000000e+00 2.204205e+00 229.36 -2.00 3.45 -2.00 502.01 0.00e+00 20.114 0.139 489.00 513.00 1 1.0082e+01 1.7657e-01 3.6961e-02 -6.0000e+00 1.6910e-01 7.6839e-02 4.4468e-02 3.1110e-03 -6.0000e+00 4.3752e-02 4.1323e-06 -9.2966e-03 1.2003e-02 1.1577e-04 -6.0000e+00 1.2481e-02 7.9551e-02 -8.7171e-04 12 8 8 10 0 0 68.08 19.18 10.01 0.07955 0.01507 8 2 1 4 0 4000.000 24.75 20.00 19.18 900000 -6024 -556 1138 -19352 -5235 -6653 12948 3752 15169 -3662 20028 11180 -620 15564 5807 10504 4328 8125 -3972 16885 8225 -7960 5103 -7944 210 -16424 584 -10868 -9772 12969 -2465 -13949 3169 -3114 2127 -16750 -679 -2106 13813 10037 15432 -988 1973 -8737 8539 6042 11464 16261 1854 5421 20939 -5442 -12288 3200 19791 17511 -4570 16513 -4928 2569 6630 133 3867 10329 -17364 -4285 -13483 8994 6516 372 -8295 -10137 7477 -3320 -5635 18516 -12434 3253 -1912 -8512 -2221 -2921 -3963 -4821 23216 2220 -3920 -9147 -1213 1145 6538 8331 -10184 -1814 -10818 -7955 3533 9040 2176 2802 32914 -2368 -5458 -8868 -5171 22692 -3584 -7356 7609 13644 -7410 4527 3130 6903 12481 -2384 23902 12907 20134 -3509 13891 -12456 -6847 2877 407 6059 981 -21251 -2037 -7441 40142 -6388 98 -5193 10487 3974 24218 -7174 -8781 5437 -4810 6082 4534 10014 334 -17359 373 7220 1747 900000 -5867 -519 1071 -23071 -5577 -7362 11998 3853 13922 -4031 17199 10360 -639 13504 5535 9609 4279 7913 -4466 15646 8374 -9309 5391 -9335 234 -21048 644 -12929 -11259 11941 -2543 -16193 3159 -3400 2255 -21658 -745 -2324 12860 9633 14012 -1061 2075 -10318 8538 6198 11067 14764 1907 5249 16906 -5598 -13416 3016 16150 14994 -4977 14709 -5452 2636 6534 140 3933 9824 -21050 -4499 -15288 8244 6048 354 -8569 -10699 6678 -3337 -5821 15322 -13471 2969 -1820 -8627 -2120 -2829 -3917 -4859 17874 2126 -4006 -9860 -1209 1119 6096 7697 -11376 -1854 -11605 -8308 3204 7568 1913 2424 21194 -2221 -5334 -9296 -5349 18360 -3659 -7731 6854 11620 -7868 4312 3050 6520 11208 -2499 19378 11697 16872 -3678 12058 -13907 -7196 2749 400 5640 961 -25354 -2052 -7880 26188 -6556 93 -5075 9046 3721 18907 -7623 -9635 5242 -5188 5928 4516 9468 347 -21311 377 6711 1698 SO 20190422T035053.0Z 7051.160336 216 1 32.01 2 88.89 75.49 71.55 226.44 0.00 1 0.00 1 0 15 6.110e-02 6.007e-02 4.989e-02 4.940e-02 4.105082e+03 3.265166e+03 1.349517e+02 -6.000000e+00 3.518380e+03 282.33 -2.00 20.00 -2.00 505.39 0.00e+00 3.654575e-03 1.389806e-03 1.553006e-04 -6.000000e+00 1.740464e-03 282.33 -2.00 20.00 -2.00 500.69 0.00e+00 1.898231e+00 9.846725e-01 7.339947e-02 -6.000000e+00 1.236554e+00 229.36 -2.00 3.45 -2.00 502.26 0.00e+00 18.424 0.107 489.00 513.00 1 9.4197e+00 7.5657e-02 3.0933e-02 -6.0000e+00 9.5013e-02 4.0210e-02 1.8795e-02 2.0681e-03 -6.0000e+00 2.4327e-02 9.6743e-06 6.1600e-03 5.5993e-03 5.9733e-05 -6.0000e+00 7.0169e-03 -3.9825e-02 1.2350e-04 12 9 8 11 8 0 -201.76 19.21 3.07 -0.03983 0.00290 8 2 1 4 0 4000.000 24.75 20.00 19.21 1062 -4919 -1273 3491 -11963 7619 -6396 1015 -6906 -626 -2608 7511 6318 -7711 4524 -7419 9069 -339 18912 -1736 1930 9749 -2604 2497 4027 8755 358 -3324 4705 -9128 6433 -2666 5344 -330 -5047 1202 -8196 3633 -5990 -3762 -909 10669 -7068 -1969 5593 -304 2967 -7256 15849 7676 867 3844 -7424 1924 -3085 14393 -2093 96 2565 -5233 10527 -9184 6114 -6569 -1973 -3619 5466 6550 -3961 3293 -5519 13878 5741 -422 -2335 -2038 3925 -1096 6962 7275 188 -3916 -5331 6419 -11479 4564 -7535 705 5461 916 -411 -2910 2231 -10656 6471 1063 -364 5809 -4158 3322 -8278 5180 8003 5485 -2073 4487 2287 -10462 8200 -612 -2963 -708 -1457 2967 -3834 3815 -10057 10624 7128 7086 2142 -2319 -1869 -6567 4896 -800 7160 1826 1398 7323 -9861 -1005 -3495 9134 -2346 2692 6287 -6200 5900 -7733 6831 -59 -1490 -1269 -4771 4104 -6800 9018 -4980 198 927 -4617 -1185 3202 -13181 7065 -6941 1031 -7591 -640 -2685 6888 5786 -8044 4160 -7730 8133 -341 16019 -1831 1974 9251 -2734 2504 3999 8301 367 -3494 4467 -9719 5788 -2640 4988 -336 -5500 1242 -9267 3621 -6520 -3992 -941 9930 -7956 -2133 5671 -328 3082 -8249 14044 7212 851 3597 -7739 1848 -3114 12844 -2191 99 2598 -5737 9885 -10547 6037 -7344 -2089 -3845 5225 6110 -4055 3104 -5656 11755 5322 -419 -2373 -2049 3666 -1063 6175 6417 179 -3900 -5426 5857 -12318 4296 -7819 690 5102 900 -403 -2964 2178 -11825 5982 1018 -345 5061 -3922 2875 -8072 4500 6963 5031 -2083 4227 2187 -11289 7347 -605 -3050 -725 -1524 3001 -4187 3887 -11543 10146 6993 6868 2154 -2363 -1895 -7016 4689 -814 6741 1814 1394 6852 -10853 -1000 -3528 8105 -2352 2609 5992 -6809 5821 -8832 6794 -64 -1628 -1384 -5366 4171 -7570 8429 -5314 201 SO 20190422T035505.0Z 7051.163252 220 1 32.01 2 88.09 76.13 72.14 227.25 0.00 1 0.00 1 0 15 9.923e-03 9.790e-03 7.224e-03 7.165e-03 5.253300e+03 4.644439e+02 3.377901e+02 -6.000000e+00 5.712722e+02 282.33 -2.00 20.00 -2.00 505.46 0.00e+00 4.697487e-03 2.025149e-04 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