File name: Pandora119s1_Athens-NOA_20190603_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T155737.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190603_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190603 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190603T030954.0Z 7093.131875 334 1 32.01 2 89.74 61.50 90.77 66.42 0.00 1 0.00 1 0 43 6.264e-02 6.125e-02 5.594e-02 5.522e-02 8.519254e+03 4.087161e+03 7.016343e+02 -6.000000e+00 3.665845e+03 286.56 -2.00 20.00 -2.00 505.35 0.00e+00 2.224573e-03 1.571020e-03 1.174790e-04 -6.000000e+00 1.802995e-03 286.56 -2.00 20.00 -2.00 500.24 0.00e+00 2.844186e+00 1.141912e+00 3.234247e-02 -6.000000e+00 1.270889e+00 232.12 -2.00 3.45 -2.00 501.88 0.00e+00 20.002 0.137 489.00 513.00 1 9.2419e+00 8.7782e-02 3.4490e-02 -6.0000e+00 9.7740e-02 7.2276e-02 2.1902e-02 2.1347e-03 -6.0000e+00 2.5081e-02 8.7525e-06 1.2807e-03 5.9828e-03 8.2549e-05 -6.0000e+00 7.1920e-03 5.1613e-02 -6.0417e-04 12 8 8 10 0 0 89.40 20.53 5.76 0.05161 0.06050 8 2 1 4 0 4000.000 25.79 20.00 20.53 -7371 -7856 2866 -820 926 8688 -1171 -3571 2379 8641 -2626 3470 -1502 938 -9280 -4368 -1455 -11364 11284 -615 3126 4169 3363 1213 -5621 1503 -4497 8572 4865 2839 -2608 -8235 -1030 -521 869 576 4776 -1458 1847 2602 -9840 9434 -3067 5449 5729 -1942 1777 81 6362 -9213 15727 -8126 -6767 5599 1715 2211 -5504 6976 -3265 1764 2854 2329 2135 -4361 8497 -2934 -719 -1591 -6359 14348 -3094 978 -4048 2752 -7733 9271 -3106 3015 -1543 4363 5658 -5360 9061 6646 3782 11402 -5807 5923 63 9389 799 2984 -59 -11777 11846 -2751 6769 -6953 8221 547 -1474 8667 -5116 7089 -6456 10394 -2614 2532 -4691 -8319 13691 -5433 9103 2818 4190 -1682 -6584 847 -6197 6554 -7866 3067 -6426 2857 -5796 -3689 -6257 -15157 8174 -241 1628 583 2456 7268 -6484 8498 2510 444 -3277 218 12262 -9008 5839 1947 14548 1665 -3749 7072 -11474 -1867 -7357 -7919 2656 -814 931 8288 -1257 -3976 2503 8489 -2853 3498 -1570 946 -10293 -4621 -1512 -13301 10764 -672 3316 4393 3582 1325 -6434 1606 -5085 8642 4994 2828 -2692 -8968 -1059 -547 924 623 4949 -1596 1937 2689 -11508 9148 -3404 5617 5945 -2185 1920 88 6390 -10570 13702 -8782 -7125 5227 1696 2233 -6140 6959 -3533 1863 2981 2391 2201 -4790 8149 -3115 -736 -1616 -6683 12421 -3085 935 -4096 2624 -8232 8289 -3100 2785 -1473 3901 4990 -5300 7807 5916 3494 9824 -5954 5392 60 8242 769 2834 -58 -12713 10207 -2680 5833 -6687 6639 470 -1290 6964 -4746 6185 -6467 8902 -2546 2325 -4612 -8519 11382 -5543 8120 2700 3986 -1710 -7081 849 -6649 6123 -8366 2886 -6607 2681 -5959 -3729 -6506 -16832 7357 -236 1549 540 2265 6359 -6381 7480 2335 429 -3343 218 10963 -10038 5641 1961 12894 1664 -3898 6487 -12520 -1849 SO 20190603T031418.0Z 7093.134931 338 1 32.01 2 88.98 62.17 89.99 67.06 0.00 1 0.00 1 0 22 3.324e-02 3.286e-02 3.399e-02 3.377e-02 9.441595e+03 2.479557e+03 7.770524e+02 -6.000000e+00 1.945416e+03 286.56 -2.00 20.00 -2.00 505.32 0.00e+00 4.090204e-03 9.579966e-04 2.018477e-04 -6.000000e+00 9.564540e-04 286.56 -2.00 20.00 -2.00 500.32 0.00e+00 1.715160e+00 6.914394e-01 4.031317e-02 -6.000000e+00 6.737943e-01 232.12 -2.00 3.45 -2.00 501.93 0.00e+00 18.517 0.108 489.00 513.00 1 8.9973e+00 5.3155e-02 3.0925e-02 -6.0000e+00 5.1830e-02 7.8975e-02 1.3277e-02 2.0049e-03 -6.0000e+00 1.3282e-02 1.4622e-05 6.0388e-03 3.6668e-03 1.0655e-04 -6.0000e+00 3.8193e-03 5.7925e-02 -5.5850e-04 12 8 8 10 0 0 -122.49 20.53 3.93 0.05793 0.09981 8 2 1 4 0 4000.000 25.79 19.99 20.53 -6611 3813 1494 6868 1390 -1945 1560 1376 3173 -3444 897 -7765 1708 456 -3197 5103 -603 3964 330 -4212 -2527 78 -252 -1979 3572 -701 7877 -667 341 4486 -1330 407 -3121 -7 -4180 1756 -2574 2148 6665 -1698 3854 -3699 543 -909 -2257 -1178 -87 1702 -998 1429 -1451 49 -4404 1637 1653 736 5483 -3708 1331 2741 -92 428 -484 3588 -1968 3344 -7944 1997 3710 -2591 -1511 -1946 3922 211 -3604 1312 -3722 -6267 -1548 3904 1978 1244 288 -1848 4974 -681 -3117 -3998 4951 281 4624 737 -199 4827 -943 8453 112 154 -1294 -3886 -7462 -4213 3239 -3483 6115 -2029 -1315 835 -6281 4414 -1957 802 1970 696 3913 2266 2683 1704 1543 143 -2555 -701 -4211 4514 -1954 2392 -3565 -1301 4578 2609 2180 -1018 -2474 1798 2091 -4934 3166 -4594 -6101 -4556 -1062 1573 -1674 4387 1041 1773 7273 -1047 775 374 -6649 3500 1442 6489 1390 -2057 1620 1443 3263 -3746 921 -8564 1690 451 -3271 4827 -613 3925 346 -4671 -2770 83 -272 -2179 3740 -766 7866 -716 355 4365 -1353 409 -3310 -7 -4592 1833 -2795 2207 6489 -1791 3857 -4030 574 -987 -2507 -1297 -95 1791 -1059 1446 -1474 48 -4495 1589 1644 758 5493 -4114 1408 2862 -99 459 -525 3731 -2091 3408 -8706 2002 3609 -2591 -1486 -1927 3691 207 -3693 1270 -3731 -6347 -1481 3519 1820 1159 273 -1802 4564 -664 -3111 -4014 4535 270 4291 718 -197 4515 -918 7300 103 137 -1143 -3481 -6955 -3883 2865 -3407 5552 -1963 -1258 777 -6275 3999 -1917 775 1902 686 3761 2232 2651 1704 1535 142 -2574 -686 -4249 4189 -1944 2288 -3625 -1294 4284 2479 2059 -980 -2394 1663 1942 -4879 3010 -4687 -6408 -4765 -1081 1569 -1732 4270 1042 1741 6643 -1022 737 359 SO 20190603T031832.0Z 7093.137870 342 1 32.01 2 88.24 62.81 89.25 67.67 0.00 1 0.00 1 0 15 2.317e-02 2.315e-02 2.014e-02 2.004e-02 8.540283e+03 1.454800e+03 5.610857e+02 -6.000000e+00 1.356172e+03 286.56 -2.00 20.00 -2.00 505.34 0.00e+00 4.874415e-03 5.670651e-04 2.403111e-04 -6.000000e+00 6.667480e-04 286.56 -2.00 20.00 -2.00 500.42 0.00e+00 1.822365e+00 4.089821e-01 6.846108e-02 -6.000000e+00 4.695034e-01 232.12 -2.00 3.45 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