File name: Pandora119s1_Athens-NOA_20190613_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162451.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190613_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190613T030811.0Z 7103.130683 258 1 32.01 2 89.75 60.26 120.40 286.14 0.00 1 0.00 1 0 15 5.447e-02 5.508e-02 5.412e-02 5.350e-02 1.026316e+04 4.023608e+03 7.808102e+02 -6.000000e+00 3.199365e+03 287.53 -2.00 20.00 -2.00 505.33 0.00e+00 3.566899e-03 1.514610e-03 1.813178e-04 -6.000000e+00 1.572128e-03 287.53 -2.00 20.00 -2.00 500.28 0.00e+00 2.479749e+00 1.096716e+00 4.140624e-02 -6.000000e+00 1.109649e+00 232.64 -2.00 3.45 -2.00 501.90 0.00e+00 19.979 0.136 489.00 513.00 1 9.2173e+00 8.4248e-02 3.4653e-02 -6.0000e+00 8.5268e-02 7.7849e-02 2.0919e-02 2.2020e-03 -6.0000e+00 2.2049e-02 9.0690e-06 1.8735e-02 5.7435e-03 1.0496e-04 -6.0000e+00 6.2786e-03 9.9116e-02 -1.0072e-03 12 8 8 10 0 0 62.44 21.36 3.26 0.09912 0.22907 8 2 1 4 0 4000.000 26.51 20.00 21.36 900000 -3509 6866 -6529 1538 -63 -4482 6855 -1527 713 -4979 2414 7276 13 5267 -9326 3323 3828 1738 4817 -4836 250 -5031 8079 -1780 7368 319 -2377 -4698 -95 -1475 -2164 -7484 8403 5881 977 -7928 6102 -4063 136 -3265 172 8278 1347 8308 5526 59 -2011 -4189 -393 5028 -2178 6656 4618 5283 -921 -16955 -5619 7244 -1997 7597 6926 -4515 1443 -8093 -3153 -4950 -3448 -6714 8604 5673 123 -1151 -2411 7262 8261 9881 -1604 1213 -8017 6538 -190 1272 6785 -2037 386 -3456 6813 1498 -7283 -19 1996 6608 4391 -4977 -1283 -1420 5880 -3274 -1102 1341 84 -1124 4674 5146 -11427 -2686 3629 -10546 6825 14280 -2297 -4449 1222 -11704 2809 1215 1084 2420 4815 8104 -2716 10531 -1407 3999 -9773 -1637 628 2920 3173 1309 3606 3044 -4314 -2272 -1715 5955 -3945 9140 -2795 29 -8463 -5928 7760 -4388 4055 7963 4380 -5527 410 900000 -3460 6298 -7060 1574 -67 -5031 6893 -1660 749 -5452 2420 6864 13 5034 -10418 3332 3902 1839 4982 -5529 272 -5651 8212 -1952 7550 339 -2546 -5025 -95 -1490 -2231 -8347 8209 5983 1045 -9205 6101 -4467 143 -3580 184 8276 1459 8441 5762 64 -2205 -4593 -405 4791 -2201 6172 4449 5190 -985 -21059 -6265 7291 -2151 7646 6860 -5010 1499 -9141 -3338 -5253 -3555 -7063 7699 5218 121 -1149 -2452 6679 7425 8596 -1544 1127 -8151 5765 -181 1198 6099 -2013 373 -3460 6132 1421 -7576 -18 1925 6078 4073 -4829 -1195 -1288 4838 -2904 -953 1147 73 -1027 4152 4618 -12109 -2592 3275 -11013 6063 11938 -2293 -4578 1196 -13135 2751 1216 1085 2366 4530 7272 -2694 9154 -1385 3747 -10293 -1630 611 2770 2981 1208 3218 2716 -4156 -2171 -1660 5439 -4042 8326 -2898 30 -9409 -6443 7340 -4649 3891 7224 4067 -5655 399 SO 20190613T031235.0Z 7103.133738 262 1 32.01 2 88.99 60.93 121.20 286.92 0.00 1 0.00 1 0 22 3.230e-02 3.219e-02 2.667e-02 2.648e-02 1.565387e+04 2.110546e+03 1.075404e+03 -6.000000e+00 1.897489e+03 287.53 -2.00 20.00 -2.00 505.41 0.00e+00 2.583128e-03 7.592210e-04 8.764484e-05 -6.000000e+00 9.313604e-04 287.53 -2.00 20.00 -2.00 500.49 0.00e+00 2.080929e+00 5.388888e-01 8.286752e-02 -6.000000e+00 6.537083e-01 232.64 -2.00 3.45 -2.00 502.09 0.00e+00 18.527 0.109 489.00 513.00 1 8.7262e+00 4.1504e-02 3.1270e-02 -6.0000e+00 5.0320e-02 3.9906e-02 1.0147e-02 2.7751e-03 -6.0000e+00 1.2863e-02 1.8859e-05 3.1119e-03 2.7279e-03 7.9809e-05 -6.0000e+00 3.7125e-03 3.7191e-02 -2.8583e-04 12 9 8 11 8 0 5.50 21.36 1.28 0.03719 0.05878 8 2 1 4 0 4000.000 26.51 19.99 21.36 -11847 4639 -7104 -975 1046 -2623 -284 -114 1998 635 838 -651 -1817 938 -3555 457 -3751 6803 1 4247 733 3674 2229 -1457 4267 -3917 2927 22 38 -3897 -1385 2709 1680 3038 -336 1799 -5717 -5022 2883 -2977 3553 739 1411 898 1897 -1026 -881 2548 -1795 2581 -2772 4164 -395 -1501 3491 -742 2307 -5410 369 1655 -255 6368 246 3340 3036 3524 -3014 596 -916 -4009 5129 -489 2487 313 4122 -2739 -736 1839 -3930 -942 -6166 1620 -1356 96 2890 -2502 4342 -4961 3444 -497 4734 1262 130 6810 -2680 5471 -1315 802 -446 1771 544 -4933 3941 -6304 3636 -1378 3607 -1563 2753 5024 -5440 467 1211 1789 1455 -2796 -1316 -3361 873 -717 2012 -100 173 3519 -2044 2236 -4397 5668 -7281 -697 141 -569 5602 -2631 -1212 -1499 2760 2485 -3063 978 -827 841 -4291 2573 -3468 3549 586 -5034 2473 -888 -11965 4025 -7127 -951 1028 -2739 -294 -119 2047 654 850 -662 -1843 917 -3621 450 -3908 6517 1 4321 777 3796 2286 -1558 4329 -4317 2998 23 39 -4035 -1380 2602 1664 3055 -357 1891 -6456 -5587 2938 -3204 3590 774 1487 963 2030 -1133 -967 2669 -1929 2592 -2864 3938 -388 -1509 3420 -759 2336 -5978 386 1710 -269 6315 259 3412 3083 3514 -3161 594 -916 -4092 4756 -481 2394 311 3946 -2785 -722 1732 -3878 -897 -6193 1513 -1315 93 2740 -2516 4075 -5090 3237 -486 4422 1201 125 6206 -2555 4764 -1158 672 -380 1466 449 -4422 3369 -6227 3349 -1351 3362 -1528 2576 4634 -5636 461 1194 1762 1447 -2930 -1374 -3521 894 -736 1978 -99 166 3350 -2020 2128 -4484 5229 -7636 -681 135 -544 5000 -2553 -1172 -1480 2663 2447 -3240 1008 -877 884 -4766 2669 -3802 3589 602 -5392 2443 -912 SO 20190613T031649.0Z 7103.136678 266 1 32.01 2 88.26 61.57 121.97 287.68 0.00 1 0.00 1 0 15 1.061e-02 1.062e-02 1.126e-02 1.120e-02 1.739529e+04 8.909921e+02 1.080965e+03 -6.000000e+00 6.235824e+02 287.53 -2.00 20.00 -2.00 505.42 0.00e+00 3.229380e-03 3.199879e-04 1.903468e-04 -6.000000e+00 3.060931e-04 287.53 -2.00 20.00 -2.00 500.64 0.00e+00 1.688350e+00 2.261765e-01 1.188199e-01 -6.000000e+00 2.148872e-01 232.64 -2.00 3.45 -2.00 502.21 0.00e+00 16.670 0.079 489.00 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