File name: Pandora119s1_Athens-NOA_20190619_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162531.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190619_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190619T030835.0Z 7109.130961 197 1 32.01 2 89.75 59.95 76.22 225.45 0.00 1 0.00 1 0 22 1.707e-01 1.606e-01 1.757e-01 1.647e-01 3.056857e+04 1.469424e+04 1.741906e+03 -6.000000e+00 1.005160e+04 288.08 -2.00 20.00 -2.00 505.18 0.00e+00 4.594565e-03 4.634427e-03 2.160676e-04 -6.000000e+00 4.926105e-03 288.08 -2.00 20.00 -2.00 499.82 0.00e+00 -6.393646e+00 3.488041e+00 1.696998e-01 -6.000000e+00 3.440794e+00 232.74 -2.00 3.45 -2.00 501.47 0.00e+00 19.961 0.136 489.00 513.00 1 1.0985e+01 2.6750e-01 3.7331e-02 -6.0000e+00 2.6510e-01 3.0803e-01 6.6357e-02 4.3918e-03 -6.0000e+00 6.7413e-02 2.7686e-06 1.2402e-02 1.5320e-02 1.0420e-04 -6.0000e+00 1.9609e-02 2.9163e-02 7.4455e-05 12 8 8 10 0 0 73.56 21.45 11.13 0.02916 0.11519 8 2 1 4 0 4000.000 26.51 20.00 21.45 16113 -6695 -1106 -11786 4676 13076 -26044 15840 10277 827 -20407 4053 -7717 -5946 20397 -3466 13392 -22237 -21266 19082 16724 -11121 -7054 316 19401 2714 8718 4648 -9631 16259 11428 37087 30503 12352 11427 -1385 6231 -8176 6523 -9517 -23910 22199 13184 862 23334 12354 -7456 18595 14402 -4459 -2716 34373 -1877 5204 7494 37401 11689 7033 -1119 35644 -5835 -2564 1508 8850 -4625 -39292 -20291 23088 25777 8807 3036 -5737 -11475 -14329 11847 13539 52420 29663 -1300 -3120 33219 15265 2710 12261 3030 1886 35677 22017 -13546 -13975 -738 -13633 -6390 14544 3217 -5026 15107 -3133 13019 -9465 -1330 5236 24507 9035 -8319 7144 -7703 33327 2488 -19660 9139 11182 10821 -7699 -11782 -23072 -135 12880 13901 19593 -9104 11239 17866 23919 13915 12828 1917 34718 -877 31281 17687 -28125 -31445 -21738 15051 -2379 -2655 37453 -9785 -4502 13205 29826 -25621 1198 -5713 12567 9404 13305 -5006 -13622 14664 -7833 -1259 -15322 5262 13717 -39533 16190 10965 952 -27773 4360 -8953 -6718 18196 -3855 13148 -30844 -29498 18221 16344 -13971 -8522 355 18025 2959 8822 4785 -11132 14255 10518 27599 24888 12015 11314 -1552 6414 -9629 6601 -11333 -32293 19657 12939 967 20967 12340 -8740 16951 13380 -4881 -2867 24889 -1973 5221 7551 28550 11675 7198 -1245 28296 -6865 -2930 1652 8945 -5283 -60975 -26370 19219 21250 8341 3056 -6359 -13598 -17526 11070 12248 32468 22173 -1314 -3207 23843 13226 2693 11196 3050 1914 25607 17954 -15303 -15903 -739 -15458 -6585 11983 2829 -4589 10908 -2661 9344 -8382 -1152 4470 18215 7964 -8916 6592 -8224 24204 2410 -23919 8358 9995 9673 -8283 -13311 -28857 -139 11619 12196 15811 -9531 9441 13973 17618 11344 10564 1753 22700 -809 20582 13101 -31773 -36666 -23155 11522 -2141 -2421 23713 -9791 -4305 10602 20735 -29978 1058 -5324 9583 7285 9824 -4443 -13300 SO 20190619T031259.0Z 7109.134016 201 1 32.01 2 88.99 60.62 76.82 226.25 0.00 1 0.00 1 0 22 1.197e-01 1.171e-01 1.054e-01 1.017e-01 6.213081e+03 7.474357e+03 5.789643e+02 -6.000000e+00 7.047479e+03 288.09 -2.00 20.00 -2.00 505.23 0.00e+00 -1.337998e-04 2.877252e-03 2.045334e-05 -6.000000e+00 3.454982e-03 288.09 -2.00 20.00 -2.00 499.98 0.00e+00 1.362853e+00 2.150436e+00 1.270811e-02 -6.000000e+00 2.417269e+00 232.74 -2.00 3.45 -2.00 501.62 0.00e+00 18.517 0.108 489.00 513.00 1 1.0225e+01 1.6548e-01 3.0342e-02 -6.0000e+00 1.8618e-01 1.3748e-01 4.1821e-02 1.7498e-03 -6.0000e+00 4.7457e-02 4.6245e-06 -1.5804e-02 1.0909e-02 5.7623e-05 -6.0000e+00 1.3758e-02 -1.0820e-02 1.6787e-04 12 8 8 10 0 0 30.07 21.46 7.81 -0.01082 -0.12044 8 2 1 4 0 4000.000 26.51 20.00 21.46 7517 -3034 -3900 9585 -5431 -1292 -8804 16575 -478 7182 2540 -18814 28934 -7301 11388 7394 2408 22400 17711 215 -16465 10099 -408 10931 -11175 10304 10596 -2676 5053 -11132 14690 3805 7140 -1314 -281 11746 -19079 4296 -21780 -241 2218 6418 -4189 15197 4134 -10065 20471 2596 8894 3983 -6653 2329 9 26278 -30018 14852 388 -12512 23133 -667 3164 -2162 20062 -5910 3773 5849 -8093 3074 -17390 6526 -5087 7549 -2692 4808 7318 -12692 -448 12551 -9295 1484 2561 17623 -9833 -6003 -9735 20673 -237 21704 24942 9440 22983 -21029 2043 2878 -196 -4032 -2623 24705 -5164 11121 -16993 12588 8923 10210 -5311 -17282 12167 -11964 3976 16521 1579 17883 2658 -14799 -15522 6940 -4735 19598 649 3578 6116 -5536 3436 -21226 -4339 541 13012 15974 -6326 7412 -881 17751 -4187 174 17071 5520 11313 -7236 -3607 -1762 -7349 9229 8123 20349 -14755 6789 19316 19342 -10037 -11603 7004 -3112 -4085 9008 -6113 -1433 -10763 15979 -551 7659 2811 -24763 23920 -8552 10947 7367 2535 19604 16597 238 -21844 10606 -464 11120 -14211 10590 10835 -3101 5339 -13514 13443 3831 6983 -1427 -310 11734 -26112 4629 -30152 -266 2373 6579 -4799 14464 4433 -12509 18732 2817 8931 4115 -7449 2321 9 20050 -39570 13123 406 -14768 19773 -706 3217 -2319 17727 -6598 3807 5723 -8973 3000 -20525 5986 -5185 6750 -2675 4471 6693 -14202 -440 10645 -9664 1373 2336 13867 -10249 -6073 -10321 16320 -232 17078 18988 8393 17908 -24985 1993 2794 -190 -3987 -2496 17861 -4785 8808 -17227 9808 7386 8634 -5279 -19715 10365 -12873 3615 13209 1475 14343 2509 -16772 -17823 6396 -4930 16060 642 3404 5591 -5598 3141 -24140 -4280 510 10825 12892 -6210 6480 -832 13751 -3887 157 12969 4744 9327 -7139 -3489 -1696 -7554 8096 7244 16121 -16602 6121 15161 14900 -10195 -11871 SO 20190619T031715.0Z 7109.136979 205 1 32.01 2 88.26 61.27 77.41 227.02 0.00 1 0.00 1 0 22 7.096e-02 6.886e-02 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