File name: Pandora119s1_Athens-NOA_20190626_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162528.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190626_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190626T031014.0Z 7116.132107 236 1 32.01 2 89.76 60.01 46.58 139.01 0.00 1 0.00 1 0 22 8.983e-02 8.582e-02 6.048e-02 5.923e-02 7.407993e+03 4.320756e+03 6.706775e+02 -6.000000e+00 5.301706e+03 288.72 -2.00 20.00 -2.00 505.29 0.00e+00 1.262024e-03 1.690903e-03 5.914801e-05 -6.000000e+00 2.598459e-03 288.72 -2.00 20.00 -2.00 500.16 0.00e+00 2.950790e+00 1.219001e+00 2.238153e-02 -6.000000e+00 1.816634e+00 232.69 -2.00 3.45 -2.00 501.79 0.00e+00 19.956 0.136 489.00 513.00 1 9.3226e+00 9.3925e-02 3.4207e-02 -6.0000e+00 1.3991e-01 8.5529e-02 2.3391e-02 2.0331e-03 -6.0000e+00 3.5736e-02 8.1513e-06 6.0971e-03 6.4126e-03 7.9585e-05 -6.0000e+00 1.0326e-02 6.3717e-03 -7.6553e-05 12 8 8 10 0 0 65.55 21.83 4.66 0.00637 0.04866 8 2 1 4 0 4000.000 26.83 20.00 21.83 5400 -8834 -4667 2696 4222 -2427 455 3497 628 13192 -4421 7791 -6132 -11527 3438 -222 2751 -119 14542 -4564 7354 3720 -9248 20589 -14687 5253 -2195 9977 1898 2788 -228 1910 13066 -2747 4346 5065 -1534 -1962 -4663 1826 -12961 12199 3564 2591 -3877 -12216 15372 -7844 26221 -4007 -1344 -13322 -14959 -4227 -3552 10335 -6086 13245 1267 5649 2876 -12450 4397 -8426 23144 -612 10290 10460 4362 12096 -8421 8830 -12388 5296 -5765 -451 8796 -193 14343 -11410 9201 -3767 11788 471 -8203 495 -6503 10009 -10070 11477 -5915 749 11185 -9644 6427 -2844 1160 3970 -2747 2678 -5706 336 -10596 14259 -11727 10625 437 10887 4149 -9529 -3952 3577 23897 2800 -4557 3820 -2222 1104 -8118 -8036 -5101 -903 1478 -4153 2710 10043 15136 -2461 -4352 928 -3510 5127 -6545 16710 -4670 14595 558 7839 106 931 4184 2827 27663 -8685 -1975 -7865 13655 -2510 -19268 12478 4963 -9255 -4825 2673 4236 -2662 493 3701 683 12531 -4943 7603 -6790 -13343 3418 -231 2819 -128 13814 -5311 7637 4017 -11106 18898 -18752 5632 -2453 9980 2012 2861 -232 1918 12312 -3037 4566 5313 -1710 -2175 -5260 1921 -15834 11672 3754 2784 -4471 -15305 14503 -9198 21421 -4317 -1374 -15066 -17118 -4396 -3758 9750 -6883 12437 1343 5725 3000 -14794 4528 -9572 19458 -627 9539 9541 4069 10602 -8797 7789 -13624 4917 -5980 -439 7682 -182 11570 -11869 7809 -3661 9885 447 -8545 475 -6690 8713 -10709 9874 -6102 729 9834 -10354 5763 -2727 1040 3375 -2451 2245 -5248 298 -10604 11771 -12466 9280 409 9123 3717 -9873 -3921 3331 18333 2672 -4709 3655 -2271 1090 -8721 -8508 -5170 -870 1387 -4138 2532 8742 12534 -2428 -4367 879 -3438 4550 -6475 13103 -4472 12023 526 7168 104 913 4007 2762 21692 -9564 -2022 -8433 11604 -2470 -22283 10569 SO 20190626T031432.0Z 7116.135093 240 1 32.01 2 89.02 60.66 46.03 140.26 0.00 1 0.00 1 0 15 3.600e-02 3.552e-02 2.545e-02 2.523e-02 1.373899e+04 1.986773e+03 9.059982e+02 -6.000000e+00 2.124365e+03 288.72 -2.00 20.00 -2.00 505.40 0.00e+00 2.679453e-03 7.250759e-04 1.610898e-04 -6.000000e+00 1.041149e-03 288.72 -2.00 20.00 -2.00 500.46 0.00e+00 2.860853e+00 5.135296e-01 8.527271e-02 -6.000000e+00 7.277769e-01 232.69 -2.00 3.45 -2.00 502.06 0.00e+00 18.562 0.109 489.00 513.00 1 8.6113e+00 3.9587e-02 3.1521e-02 -6.0000e+00 5.6054e-02 3.0374e-02 9.6874e-03 2.6677e-03 -6.0000e+00 1.4313e-02 1.9876e-05 2.9376e-03 2.6472e-03 8.4790e-05 -6.0000e+00 4.1379e-03 2.3574e-02 -1.6071e-04 12 9 8 11 8 0 -157.99 21.83 3.06 0.02357 0.04395 8 2 1 4 0 4000.000 26.83 19.99 21.83 309 4231 -1405 2645 -6979 4490 886 2177 626 -3629 6376 -4253 3549 -5473 1411 2263 -221 -329 -2375 2117 -3695 1657 -467 363 1390 -7026 2170 -4619 6206 3541 -1866 2374 -4157 5335 -350 3081 -1151 1912 -483 -2271 6817 -4162 1506 -5702 5422 1205 1233 3165 -4335 3797 -3784 4801 -4059 7419 2137 1784 759 -3404 247 -5781 -494 2559 -1476 1986 -2918 -10 -1451 811 1728 1923 4091 -1219 2618 -5559 3624 -5636 975 2721 -2682 3081 -3595 4827 -2421 2672 -1707 -1007 -344 -6007 -171 2163 2355 -3382 262 3061 -431 3794 -4961 8931 -6774 -1254 -963 1438 -745 -4693 6252 -2177 4648 1932 2012 -1191 -3057 1334 -2077 5011 304 1132 -785 467 1873 -2739 2252 -5335 7191 1182 -5317 6436 -2717 -441 -3378 4031 2594 2453 -492 -5671 10033 -2539 4299 -2260 4830 -6338 39 736 -3528 2531 -3016 2768 -856 -49 2841 -1521 277 3704 -1339 2499 -7475 4391 915 2238 654 -3920 6151 -4501 3431 -5734 1375 2201 -224 -340 -2564 2214 -4018 1714 -495 383 1461 -8041 2255 -5070 5983 3424 -1881 2305 -4398 5282 -375 3218 -1250 1997 -512 -2442 6711 -4612 1595 -6568 5636 1310 1332 3312 -4799 3782 -3967 4530 -4161 6855 2132 1787 783 -3698 260 -6452 -524 2641 -1588 2058 -3147 -11 -1497 807 1681 1848 3828 -1206 2512 -5839 3479 -5882 937 2531 -2605 2811 -3509 4354 -2366 2505 -1687 -993 -337 -6049 -166 2053 2191 -3360 251 2823 -402 3287 -4546 7102 -6036 -1048 -810 1213 -669 -4555 5586 -2137 4254 1808 1882 -1160 -3072 1297 -2106 4763 305 1136 -812 480 1887 -2787 2197 -5413 6564 1123 -5422 5865 -2721 -432 -3404 3756 2429 2275 -467 -5673 8669 -2534 4088 -2336 4726 -7029 41 775 -3892 2630 -3296 2824 -892 -50 2799 -1575 SO 20190626T031844.0Z 7116.138009 244 1 32.01 2 88.30 61.30 45.50 141.50 0.00 1 0.00 1 0 22 1.215e-02 1.217e-02 9.498e-03 9.450e-03 1.716336e+04 7.523752e+02 1.057610e+03 -6.000000e+00 7.170257e+02 288.72 -2.00 20.00 -2.00 505.45 0.00e+00 2.200656e-03 2.710729e-04 1.310142e-04 -6.000000e+00 3.512910e-04 288.72 -2.00 20.00 -2.00 500.72 0.00e+00 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