File name: Pandora119s1_Athens-NOA_20190627_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162534.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190627_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190627T031033.0Z 7117.132326 249 1 32.01 2 89.76 60.05 48.95 123.96 0.00 1 0.00 1 0 36 1.065e-01 1.007e-01 9.659e-02 9.358e-02 5.448698e+03 6.724579e+03 5.648766e+02 -6.000000e+00 6.289857e+03 288.81 -2.00 20.00 -2.00 505.25 0.00e+00 3.371874e-03 2.666425e-03 1.991291e-04 -6.000000e+00 3.082611e-03 288.81 -2.00 20.00 -2.00 499.96 0.00e+00 1.703374e+00 1.955817e+00 5.552701e-02 -6.000000e+00 2.155157e+00 232.68 -2.00 3.45 -2.00 501.61 0.00e+00 19.960 0.136 489.00 513.00 1 9.8597e+00 1.5139e-01 3.4650e-02 -6.0000e+00 1.6598e-01 1.4091e-01 3.7469e-02 1.9177e-03 -6.0000e+00 4.2411e-02 5.0611e-06 1.9478e-02 1.0214e-02 1.0690e-04 -6.0000e+00 1.2242e-02 -3.3206e-02 1.2736e-04 12 8 8 10 0 0 49.44 21.82 15.85 -0.03321 0.10190 8 2 1 4 0 4000.000 26.83 20.00 21.82 9065 2959 -9833 509 988 -210 -10477 3519 3495 6455 22241 12345 6794 13093 1994 4857 1348 -3115 -21311 -12844 4214 -8955 -2290 1106 2040 -2778 3366 -1933 -8577 24131 -964 21480 -1136 8250 1458 -1683 10158 -12965 3132 6010 12550 -3605 -3105 -11458 2932 900 -6242 6639 1195 -2091 -265 5475 14676 -4936 10639 -2595 866 -11600 -1299 -1874 8620 10176 6534 3546 11806 -6976 -15896 -15681 17334 -9617 20462 5135 2973 1785 17973 -1427 -21176 8585 7815 -1837 8882 -8741 -7567 -11494 24948 -1769 13355 18019 23619 504 -14639 24030 -9909 17839 -5570 3939 -721 11572 -6634 2523 -3181 -12941 21858 -7545 22147 9232 -15111 14473 -2013 24892 -7259 8707 9876 -12327 7602 -11296 -3945 -12586 7291 -1933 5462 -11670 -15819 5751 -3210 -5664 6712 3702 9896 11283 6653 -3615 3376 19543 5230 -10142 16435 -7250 -7812 7936 13287 9018 -7585 13135 2576 -11477 -4926 -5059 9660 -626 8266 2940 -11452 550 1087 -238 -13267 3872 3810 6734 19511 11777 6768 12167 2075 4971 1456 -3495 -29052 -16177 4484 -10889 -2613 1225 2240 -3184 3581 -2123 -9809 19563 -1005 18192 -1239 8380 1601 -1900 10097 -16079 3287 6134 12082 -4123 -3573 -14088 3212 1001 -7176 6760 1255 -2210 -269 5205 12819 -5222 10139 -2806 915 -13908 -1405 -2040 8471 9856 6544 3627 10963 -7692 -18873 -18322 14385 -10377 16356 4817 2872 1750 14873 -1412 -25141 7488 6834 -1770 7726 -9124 -7863 -12198 18945 -1755 11366 14614 18157 480 -16375 18869 -10630 14679 -5528 3467 -648 9222 -6097 2117 -2873 -13259 16701 -7678 16803 7914 -16383 11645 -1924 18430 -7521 7784 8806 -13817 7023 -12352 -4105 -13819 6634 -1901 4933 -12161 -17228 5193 -3101 -5611 6015 3328 8529 9491 5639 -3355 2907 14738 4503 -10365 13084 -7409 -8106 7081 11291 8026 -7972 11162 2402 -12089 -4770 -4853 8014 -582 SO 20190627T031450.0Z 7117.135301 253 1 32.01 2 89.03 60.70 48.26 125.00 0.00 1 0.00 1 0 22 7.040e-02 6.916e-02 5.852e-02 5.733e-02 9.604245e+03 4.390094e+03 6.049268e+02 -6.000000e+00 4.157495e+03 288.81 -2.00 20.00 -2.00 505.25 0.00e+00 1.034788e-03 1.626941e-03 1.210239e-04 -6.000000e+00 2.036266e-03 288.81 -2.00 20.00 -2.00 500.00 0.00e+00 2.695501e+00 1.199433e+00 7.524348e-02 -6.000000e+00 1.420637e+00 232.68 -2.00 3.45 -2.00 501.64 0.00e+00 18.577 0.110 489.00 513.00 1 9.5044e+00 9.2367e-02 3.1221e-02 -6.0000e+00 1.0946e-01 9.9089e-02 2.3019e-02 2.3372e-03 -6.0000e+00 2.7875e-02 8.4358e-06 -4.7416e-03 6.0871e-03 6.2902e-05 -6.0000e+00 8.0932e-03 -2.1502e-02 2.7343e-04 12 8 8 10 0 0 -440.74 21.82 2.66 -0.02150 -0.05439 8 2 1 4 0 4000.000 26.83 20.00 21.82 -2802 -1301 8162 -2091 7048 1446 -9598 6679 -4177 11852 -7981 2285 -1714 10118 3489 2571 14866 748 7533 -6905 2495 2392 -9145 -785 -10178 3513 -9791 15647 3609 -11446 -4081 4425 6114 -6712 2277 -1111 -1172 9261 13612 1189 -4700 1079 -297 6876 -3015 -912 1421 1629 -3874 5361 1811 12253 7276 -1073 -3719 -6012 -2531 -1172 2047 -9234 7114 521 6836 -10205 -3932 -10226 6655 1736 2223 7806 -2627 12366 -9360 164 394 -973 6787 6055 6251 -7877 5891 -13035 7199 -3621 5938 -1706 -8675 6588 415 -5251 -12001 4918 2792 -5812 6137 -1312 4856 -3975 13195 -6984 -5814 9781 -9372 4253 -6295 3248 -3212 7743 1133 7294 2318 -8420 3980 3846 4524 -4850 7387 10621 -13242 6897 2611 8435 -3591 438 522 12347 12153 -3127 13058 -1307 -10141 -4496 -5081 -3799 -12112 10993 -254 15390 3798 10314 9429 -90 5750 -8344 8583 2623 -9593 -7900 -5024 3685 -2800 -1289 7529 -2204 6980 1552 -11719 7010 -4896 11756 -9532 2429 -1869 9692 3549 2645 13690 809 7784 -8370 2773 2670 -11183 -885 -12651 3810 -12072 15173 3768 -13552 -4409 4385 6050 -7754 2462 -1258 -1325 9351 13018 1278 -5348 1164 -328 7130 -3478 -1033 1564 1766 -4358 5367 1829 10889 6717 -1082 -3926 -6659 -2763 -1276 2164 -10646 7141 545 6902 -11880 -4263 -11647 6299 1699 2135 7005 -2598 10523 -9963 160 385 -958 6091 5382 5477 -7898 5146 -13821 6278 -3549 5337 -1665 -9088 5912 395 -5294 -13011 4537 2642 -5958 5481 -1228 4153 -3612 9876 -6316 -5209 7651 -8963 3775 -6218 2946 -3098 6640 1034 6286 2122 -8675 3653 3557 4177 -4950 6720 9386 -14786 6218 2418 7269 -3468 406 487 10251 10124 -3033 10752 -1237 -10145 -4197 -4838 -3475 -12117 9082 -234 12630 3469 8939 8323 -88 5329 -8917 7714 2476 -10072 -8019 -4905 3302 SO 20190627T031853.0Z 7117.138113 257 1 32.01 2 88.33 61.32 47.61 126.01 0.00 1 0.00 1 0 15 3.915e-02 3.833e-02 3.662e-02 3.627e-02 9.015684e+03 2.697983e+03 6.655862e+02 -6.000000e+00 2.311914e+03 288.81 -2.00 20.00 -2.00 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