File name: Pandora119s1_Athens-NOA_20190703_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162509.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190703_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190703T031310.0Z 7123.134144 338 1 32.01 2 89.75 60.53 94.37 57.98 0.00 1 0.00 1 0 15 5.884e-02 5.741e-02 4.847e-02 4.792e-02 9.922941e+03 3.625447e+03 7.579744e+02 -6.000000e+00 3.481189e+03 289.36 -2.00 20.00 -2.00 505.38 0.00e+00 5.194607e-03 1.371197e-03 2.598465e-04 -6.000000e+00 1.705450e-03 289.36 -2.00 20.00 -2.00 500.45 0.00e+00 2.442592e+00 9.776682e-01 5.723905e-02 -6.000000e+00 1.191357e+00 232.64 -2.00 3.45 -2.00 502.04 0.00e+00 19.931 0.135 489.00 513.00 1 9.0843e+00 7.5376e-02 3.4975e-02 -6.0000e+00 9.1748e-02 5.9392e-02 1.8569e-02 2.3108e-03 -6.0000e+00 2.3479e-02 1.0194e-05 2.6837e-03 5.2068e-03 1.1680e-04 -6.0000e+00 6.7628e-03 1.1941e-02 -2.4851e-04 12 8 8 10 0 0 -256.19 21.40 5.15 0.01194 0.03056 8 2 1 4 0 4000.000 26.51 19.99 21.40 -11707 4735 -4365 7813 -971 1469 4384 -4136 3230 -4052 -4987 1339 914 7384 -3504 5495 -3677 6958 784 1325 7458 -5563 -2451 -6244 -1223 -12719 1974 -5980 1334 2154 5289 19805 -28 11033 -2013 -3945 235 861 3428 -1970 -3805 -4197 10688 5510 16 2040 -561 -1175 2902 12735 2483 5554 984 -8929 7994 -6755 2873 -7053 9869 -2490 -2296 6398 -6702 6820 -1199 2320 -6827 2681 -296 65 7377 -10274 6056 -2698 -1211 -1990 -5493 -5357 -7294 12670 5348 7839 4517 -8687 639 -966 6629 2128 8416 3029 -1508 -1732 -7747 13624 -2763 651 3608 6291 1879 -844 -3573 -10146 2776 -2389 6379 3977 -10229 1418 4986 10961 -6156 -4063 -2584 3542 201 1386 2016 -4254 7711 2426 3173 -2627 1440 -6547 -1984 9441 2872 -3247 -1197 -1064 3881 -10238 7669 3494 263 -7434 6979 -1348 786 -2448 6031 9809 -4583 6352 -9919 -5005 -832 -1501 10177 -3874 -11962 4142 -4293 7028 -982 1487 4387 -4553 3305 -4421 -5416 1345 909 6806 -3581 5147 -3821 6628 811 1346 7362 -6114 -2620 -6968 -1306 -15282 2042 -6623 1346 2103 4922 15951 -28 10148 -2162 -4370 249 901 3467 -2094 -4131 -4618 10268 5652 17 2200 -619 -1291 3012 11713 2469 5249 965 -9506 7535 -7390 2917 -8006 9499 -2715 -2504 6421 -7686 6820 -1289 2377 -7549 2656 -298 64 6754 -11228 5658 -2774 -1231 -2026 -5707 -5470 -7508 10618 4821 6919 4146 -9166 618 -955 6069 2031 7518 2859 -1463 -1702 -8144 11817 -2711 602 3153 5208 1590 -724 -3150 -9725 2413 -2262 5669 3653 -10800 1325 4494 9389 -6352 -4169 -2646 3443 203 1400 2041 -4494 7373 2417 3092 -2617 1371 -6777 -1974 8422 2745 -3303 -1192 -1055 3631 -10895 6755 3199 250 -7754 6421 -1371 794 -2587 5906 9310 -5046 6278 -11487 -5461 -856 -1530 9147 -4019 SO 20190703T031731.0Z 7123.137164 342 1 32.01 2 89.00 61.19 93.67 58.65 0.00 1 0.00 1 0 15 2.549e-02 2.535e-02 2.271e-02 2.260e-02 1.033179e+04 1.691375e+03 7.259362e+02 -6.000000e+00 1.508159e+03 289.36 -2.00 20.00 -2.00 505.39 0.00e+00 4.959061e-03 6.456319e-04 2.582588e-04 -6.000000e+00 7.388904e-04 289.36 -2.00 20.00 -2.00 500.57 0.00e+00 1.563401e+00 4.570554e-01 6.773466e-02 -6.000000e+00 5.163617e-01 232.64 -2.00 3.45 -2.00 502.14 0.00e+00 18.505 0.108 489.00 513.00 1 8.5724e+00 3.5159e-02 3.1471e-02 -6.0000e+00 3.9761e-02 4.9185e-02 8.7029e-03 2.2573e-03 -6.0000e+00 1.0182e-02 2.2345e-05 6.8623e-03 2.4626e-03 1.1625e-04 -6.0000e+00 2.9295e-03 3.3021e-02 -4.1656e-04 12 9 8 11 8 0 -145.25 21.40 1.91 0.03302 0.08062 8 2 1 4 0 4000.000 26.51 20.00 21.40 -2495 -4135 1140 -3025 1588 4367 524 2498 -2836 791 -2016 -1092 -6378 -597 3249 -3649 -1103 -1521 -280 770 453 2343 -1928 207 -485 3847 -1545 2952 -757 -986 2863 -6220 6981 -1588 2650 2710 -2616 1623 2657 -572 4079 295 -1734 -1848 2766 -440 5295 -1811 3621 -1509 1380 -857 -1259 1249 171 1329 -931 1584 -1516 -3205 -2465 -1176 409 -830 2373 752 1308 1648 235 -1386 1173 -530 -1708 368 1838 265 872 -2713 4655 -3187 1817 -2868 703 -78 2259 -1609 -2801 5215 -1147 3777 2353 -3774 3591 869 -783 52 2442 1627 2034 -2794 -1318 -504 -926 2975 -2269 -3229 5033 -4861 3753 -1421 1050 -2190 406 -2214 -222 1671 -1415 5374 -175 3405 -1027 69 944 677 -564 -2183 2609 -1815 -1121 -3911 -1931 2592 187 838 -2223 -233 4087 310 1829 2314 2161 -2740 422 -5609 -2349 3592 -2748 -1271 -3222 4800 -2289 -3908 1051 -3004 1550 4243 538 2535 -3031 808 -2086 -1104 -6701 -586 3055 -3694 -1104 -1522 -283 778 461 2349 -2024 214 -507 3862 -1629 2939 -766 -976 2690 -6430 6455 -1646 2692 2776 -2817 1662 2673 -593 4054 308 -1872 -1975 2922 -470 5451 -1930 3591 -1540 1336 -833 -1223 1197 170 1340 -980 1644 -1629 -3508 -2685 -1271 436 -894 2453 780 1329 1646 235 -1395 1145 -527 -1734 369 1821 265 852 -2710 4277 -3154 1713 -2848 678 -75 2129 -1583 -2786 4772 -1116 3508 2235 -3853 3426 847 -762 49 2180 1427 1740 -2483 -1159 -450 -858 2742 -2253 -3260 4661 -4944 3507 -1413 1034 -2208 404 -2280 -226 1683 -1482 5273 -181 3345 -1039 69 924 666 -566 -2235 2553 -1858 -1138 -4065 -1948 2469 181 803 -2216 -232 3960 317 1869 2380 2194 -2939 440 -6217 -2506 3570 -2860 -1283 -3294 4552 SO 20190703T032145.0Z 7123.140104 346 1 32.01 2 88.27 61.83 92.99 59.29 0.00 1 0.00 1 0 22 1.128e-02 1.117e-02 9.365e-03 9.326e-03 1.294468e+04 7.105672e+02 8.452348e+02 -6.000000e+00 6.670269e+02 289.36 -2.00 20.00 -2.00 505.42 0.00e+00 5.111311e-03 2.672979e-04 2.829998e-04 -6.000000e+00 3.267835e-04 289.36 -2.00 20.00 -2.00 500.74 0.00e+00 1.302876e+00 1.876094e-01 9.141840e-02 -6.000000e+00 2.283094e-01 232.64 -2.00 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