File name: Pandora119s1_Athens-NOA_20190704_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162538.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190704_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190704 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190704T031339.0Z 7124.134479 338 1 32.01 2 89.75 60.63 104.38 48.70 0.00 1 0.00 1 0 15 4.931e-02 4.885e-02 4.336e-02 4.300e-02 4.909877e+03 3.013507e+03 2.239687e+02 -6.000000e+00 2.918250e+03 289.45 -2.00 20.00 -2.00 505.37 0.00e+00 3.040821e-03 1.233744e-03 1.183691e-04 -6.000000e+00 1.429178e-03 289.45 -2.00 20.00 -2.00 500.43 0.00e+00 3.140920e+00 8.714732e-01 6.142738e-02 -6.000000e+00 9.972304e-01 232.63 -2.00 3.45 -2.00 502.05 0.00e+00 19.932 0.135 489.00 513.00 1 8.9591e+00 6.7315e-02 3.4542e-02 -6.0000e+00 7.6820e-02 5.1765e-02 1.6586e-02 2.1794e-03 -6.0000e+00 1.9630e-02 1.1430e-05 3.3911e-03 4.7418e-03 4.0199e-05 -6.0000e+00 5.6693e-03 3.7177e-02 -3.0431e-04 12 8 8 10 0 0 61.18 21.71 5.58 0.03718 0.06070 8 2 1 4 0 4000.000 26.73 20.00 21.71 -518 -3849 -4357 -6136 -3450 -3811 -2374 -1973 6203 -5803 -3379 -1512 -3362 1416 5048 4532 -8207 4954 2420 3526 -645 -1135 3852 -839 5984 -5338 -2224 3676 -6144 12927 -2849 -5360 -9055 10862 476 -49 6653 5175 1968 2694 1989 1373 -4996 6322 7288 -3685 -2596 4248 -3184 1996 -2204 9841 4394 2564 3673 -7125 3891 3097 208 236 1304 1727 746 6001 -2452 8387 -9328 -748 5525 -7947 -2243 1971 3079 8902 5026 1354 -7748 -1482 -2760 -4418 488 -1727 -378 4102 1300 784 4734 6434 -1016 -7553 3348 4042 6793 -1070 -5319 1147 403 6177 -2002 -3311 3317 -1234 3032 5723 3175 -7789 3318 13069 -2231 -6932 -4325 5224 -9077 4368 -4015 -265 1666 -5260 6943 1822 5397 -5541 4326 8084 -3160 2842 -2755 8827 -1369 -6229 -1294 -883 -83 -4875 5223 3836 -1129 1851 9462 -233 4430 6190 -8409 -6819 -1756 -4103 -2641 180 573 -6935 -475 -3695 -4323 -6401 -3606 -4094 -2558 -2137 6189 -6472 -3630 -1572 -3515 1397 4784 4341 -8830 4899 2441 3565 -684 -1214 3932 -902 6037 -6037 -2426 3733 -6736 11436 -2911 -5639 -10084 10196 507 -53 6698 5243 2040 2761 2058 1441 -5656 6468 7447 -4106 -2846 4405 -3404 1978 -2221 8844 4040 2425 3516 -7797 3889 3151 219 248 1357 1795 784 5966 -2629 7959 -10404 -755 5168 -8412 -2230 1883 2931 8063 4743 1315 -8120 -1437 -2686 -4355 459 -1669 -363 3798 1217 741 4305 5889 -977 -7784 3120 3783 6233 -1060 -5427 1075 371 5243 -1806 -2990 2812 -1116 2707 5122 2965 -8139 3082 10931 -2173 -7144 -4408 4917 -9751 4246 -4176 -267 1657 -5609 6504 1774 5007 -5685 4018 7265 -3195 2717 -2791 7969 -1368 -6510 -1276 -856 -79 -4861 4741 3590 -1133 1834 8817 -242 4425 6115 -9441 -7549 -1885 -4354 -2714 181 570 -7290 SO 20190704T031801.0Z 7124.137512 342 1 32.01 2 89.00 61.30 103.77 49.47 0.00 1 0.00 1 0 15 2.128e-02 2.113e-02 2.090e-02 2.081e-02 8.700353e+03 1.520319e+03 5.388042e+02 -6.000000e+00 1.259324e+03 289.45 -2.00 20.00 -2.00 505.39 0.00e+00 3.061619e-03 5.950443e-04 1.803337e-04 -6.000000e+00 6.168980e-04 289.45 -2.00 20.00 -2.00 500.58 0.00e+00 1.834048e+00 4.205383e-01 6.910393e-02 -6.000000e+00 4.309220e-01 232.63 -2.00 3.45 -2.00 502.17 0.00e+00 18.502 0.108 489.00 513.00 1 8.4959e+00 3.2373e-02 3.1142e-02 -6.0000e+00 3.3185e-02 4.3091e-02 8.0405e-03 2.2174e-03 -6.0000e+00 8.4958e-03 2.4375e-05 2.4071e-03 2.2576e-03 8.0415e-05 -6.0000e+00 2.4460e-03 4.2256e-02 -4.5521e-04 12 8 8 10 0 0 -168.56 21.72 4.71 0.04226 0.05895 8 2 1 4 0 4000.000 26.83 20.01 21.72 -1852 307 2079 -1053 6361 -3880 457 -3460 740 160 -2171 -560 232 1757 2149 -619 -2749 -1413 1303 -2817 18 32 -377 -513 453 2542 573 -2208 -2838 714 -2504 -1246 1892 -1576 859 -2477 2932 325 5500 2502 275 3437 -483 3385 -1509 -537 548 1142 135 -1582 1373 -488 1394 -111 -1803 -2199 137 327 151 2473 31 1903 -2096 2238 -234 -1599 765 3754 -2094 -1406 2043 -3353 4363 2618 -479 465 -2873 -3633 278 203 359 -35 -1481 -527 -776 -797 -44 257 -884 1907 -1623 -1053 -1948 4353 4422 -2991 -536 -988 2498 -51 1227 -454 -1695 952 -2234 4384 -1757 3572 -1422 782 -2142 -569 4046 -891 793 -194 3402 -1901 -58 4870 -1328 -1792 -1437 -1200 368 -1035 2074 -1 -839 -163 -88 -3525 2456 2316 -3163 1665 3066 647 -5502 -1154 588 1962 1332 -1194 1471 -1587 -1320 -2536 3606 -698 -1689 276 1888 -1019 5889 -4078 469 -3638 766 161 -2212 -554 224 1699 2007 -597 -2742 -1419 1302 -2977 19 33 -394 -540 474 2613 599 -2347 -2975 706 -2513 -1236 1850 -1641 895 -2701 3024 342 5441 2537 286 3486 -503 3434 -1624 -575 578 1185 139 -1622 1333 -473 1315 -107 -1808 -2273 142 341 158 2539 32 1976 -2272 2320 -247 -1690 778 3653 -2134 -1407 1963 -3406 4135 2549 -483 462 -2843 -3569 260 189 334 -32 -1422 -506 -753 -778 -43 249 -864 1815 -1612 -1051 -1977 4135 4136 -2943 -501 -904 2161 -45 1064 -408 -1592 902 -2241 4154 -1724 3381 -1379 748 -2136 -566 3894 -909 801 -199 3404 -2012 -60 4743 -1356 -1816 -1445 -1208 366 -1049 2044 -1 -852 -163 -88 -3588 2331 2194 -3184 1622 3002 661 -5930 -1205 609 2020 1387 -1278 1528 -1683 -1374 -2628 3481 -705 SO 20190704T032215.0Z 7124.140451 346 1 32.01 2 88.27 61.94 103.16 50.21 0.00 1 0.00 1 0 22 1.115e-02 1.114e-02 8.203e-03 8.175e-03 1.004751e+04 5.989014e+02 6.544737e+02 -6.000000e+00 6.598436e+02 289.45 -2.00 20.00 -2.00 505.40 0.00e+00 2.268597e-03 2.340060e-04 1.248484e-04 -6.000000e+00 3.232309e-04 289.45 -2.00 20.00 -2.00 500.70 0.00e+00 1.885624e+00 1.630949e-01 6.890415e-02 -6.000000e+00 2.257311e-01 232.63 -2.00 3.45 -2.00 502.26 0.00e+00 16.652 0.079 489.00 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