File name: Pandora119s1_Athens-NOA_20190705_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162547.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190705_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190705T031412.0Z 7125.134861 343 1 32.01 2 89.75 60.76 114.20 38.70 0.00 1 0.00 1 0 15 7.352e-02 7.103e-02 7.129e-02 7.009e-02 4.428517e+03 4.965574e+03 5.255481e+02 -6.000000e+00 4.351770e+03 289.54 -2.00 20.00 -2.00 505.35 0.00e+00 5.404241e-03 2.012304e-03 1.899259e-04 -6.000000e+00 2.132650e-03 289.54 -2.00 20.00 -2.00 500.28 0.00e+00 4.640052e+00 1.431012e+00 4.232022e-02 -6.000000e+00 1.494322e+00 232.63 -2.00 3.45 -2.00 501.89 0.00e+00 19.923 0.135 489.00 513.00 1 9.3217e+00 1.1034e-01 3.4496e-02 -6.0000e+00 1.1495e-01 4.3059e-02 2.7113e-02 1.9380e-03 -6.0000e+00 2.9650e-02 6.8711e-06 2.6814e-02 7.6888e-03 9.8535e-05 -6.0000e+00 8.4766e-03 2.9780e-02 -4.8508e-04 12 8 8 10 0 0 82.94 22.06 9.68 0.02978 0.21577 8 2 1 4 0 4000.000 27.05 19.99 22.06 900000 -16274 4266 1590 6450 -3571 -6831 14389 5287 -2105 2208 -3733 5765 -7003 -201 -5706 -935 133 970 5144 9960 -1990 13141 -5003 6249 4904 -13 -3891 6512 10787 3822 -3262 6846 -4655 4140 4583 -4674 708 -7966 -6771 1354 -1608 3102 -12490 1132 -7604 -1974 -1455 -1722 7611 3145 -796 -4201 9943 -1840 4056 8263 -1288 -2876 -7809 7163 652 10520 -7100 -5946 -10393 11148 -2739 -138 2973 4924 20849 6968 -5530 -362 -3711 5930 7258 17019 -15619 -4919 17261 3222 -4049 14503 3060 -2186 -1809 -6557 -98 -9165 5408 7919 2940 2817 -13595 14845 2086 10394 -2347 -7084 8444 -13145 5800 -2525 910 1561 -4333 13181 -1772 -152 -2937 2926 1390 -1908 4748 -8065 16270 -10512 -13532 7920 -1745 11475 -4213 11065 -8575 5725 -2269 6149 9736 -6681 3998 -2664 10961 4507 2536 11671 -7540 -2122 -9030 5507 -1651 7381 -7883 -5624 2260 -4002 8368 1519 664 900000 -18349 4156 1638 6476 -3923 -7813 13645 5292 -2236 2214 -3919 5448 -7491 -202 -6144 -980 141 1029 5261 9736 -2201 12560 -5768 6447 5104 -14 -4267 6283 9843 3757 -3513 6852 -5204 4384 4811 -5200 740 -9060 -7641 1424 -1764 3288 -15612 1237 -9023 -2186 -1573 -1822 7155 3034 -795 -4386 9225 -1970 4170 8220 -1413 -3205 -9156 7251 705 10260 -8175 -6669 -11685 10206 -2840 -138 2858 4647 16885 6526 -5724 -352 -3676 5387 6440 13633 -16918 -4805 13918 2931 -3982 11875 2805 -2105 -1733 -6607 -93 -9675 4975 7096 2736 2573 -14282 11442 1787 8082 -2075 -6676 7001 -13876 5137 -2432 841 1422 -4093 10838 -1679 -145 -2912 2769 1347 -1927 4509 -8698 13651 -11390 -14934 7003 -1701 9858 -4261 9654 -9133 5292 -2272 5643 8543 -6825 3636 -2583 9344 4166 2437 10418 -8074 -2176 -9994 5302 -1717 7023 -8698 -5994 2187 -4056 7442 1455 651 SO 20190705T031839.0Z 7125.137951 347 1 32.01 2 88.98 61.44 113.68 39.64 0.00 1 0.00 1 0 22 5.331e-02 5.226e-02 3.912e-02 3.875e-02 1.130538e+04 2.944327e+03 8.367421e+02 -6.000000e+00 3.155690e+03 289.54 -2.00 20.00 -2.00 505.36 0.00e+00 4.389859e-03 1.109934e-03 2.034337e-04 -6.000000e+00 1.545696e-03 289.54 -2.00 20.00 -2.00 500.40 0.00e+00 1.790078e+00 7.875958e-01 5.922008e-02 -6.000000e+00 1.079390e+00 232.63 -2.00 3.45 -2.00 502.00 0.00e+00 18.453 0.107 489.00 513.00 1 9.1284e+00 6.0663e-02 3.1019e-02 -6.0000e+00 8.3126e-02 6.2094e-02 1.4970e-02 2.2484e-03 -6.0000e+00 2.1280e-02 1.2732e-05 1.0962e-02 4.1676e-03 9.9336e-05 -6.0000e+00 6.1259e-03 2.4785e-02 -3.5151e-04 12 9 8 11 8 0 71.47 22.06 2.22 0.02478 0.10082 8 2 1 4 0 4000.000 27.05 19.99 22.06 -4005 2449 -4100 7765 -8267 2874 -4540 -419 6620 -8491 8629 -2692 6475 -1964 797 -4064 -7646 -54 -789 6674 -4051 6012 2442 2785 -2312 -2153 4191 -1926 -1395 -127 128 -4192 -6248 7003 445 10911 -860 5000 -2897 -1049 3881 -1866 5515 -2911 6150 -4808 -1721 1092 -3117 1921 -6469 394 5804 10136 -4629 6773 9216 -2456 2397 -3160 649 42 -746 -3070 -5538 9843 -9167 7442 -2471 4233 1143 -2616 5451 -2610 680 -4840 10801 -1196 -5045 -1161 241 10553 -4427 5078 2597 2766 2965 -8626 4697 -5681 10454 -9019 12960 912 1380 5286 -2648 1366 -8102 3902 -4387 1423 6374 -4736 9546 -10381 5555 -1256 5214 -1978 -5355 3750 -7805 1965 968 10308 -1643 2106 -3444 -2252 8846 -5841 4645 -2768 3219 619 1178 4342 219 1108 -9280 4324 2730 -5944 -214 -4466 9967 -2178 -890 -762 5083 -3307 -8264 5084 -4848 6891 4810 8192 -4214 -6192 -3850 2246 -4137 7184 -9226 2931 -4932 -451 6614 -9506 8233 -2762 6139 -1956 771 -4154 -8232 -55 -825 6543 -4441 5975 2525 2885 -2532 -2354 4272 -2055 -1446 -127 127 -4366 -6799 6865 475 10537 -929 5052 -3145 -1116 3952 -1984 5659 -3208 6240 -5449 -1879 1144 -3337 1909 -6827 382 5327 9043 -4911 6576 8887 -2683 2501 -3488 691 46 -810 -3398 -6218 9342 -10363 7028 -2545 4038 1121 -2674 5184 -2710 683 -4957 9544 -1147 -4980 -1098 225 9175 -4395 4622 2441 2602 2778 -9041 4302 -5792 9148 -9680 11185 878 1293 4631 -2440 1179 -7547 3201 -3948 1241 5489 -4709 8389 -10913 5077 -1223 4775 -1922 -5461 3535 -8339 1919 961 9411 -1703 2105 -3611 -2300 7964 -6029 4312 -2780 3061 607 1150 4106 215 1074 -9865 3963 2525 -6002 -206 -4569 8992 -2255 -922 -797 5054 -3512 -9252 4973 -5200 6486 4544 7377 -4278 -6461 SO 20190705T032254.0Z 7125.140903 351 1 32.01 2 88.24 62.08 113.18 40.53 0.00 1 0.00 1 0 15 2.245e-02 2.231e-02 1.841e-02 1.833e-02 1.218391e+04 1.386481e+03 7.640128e+02 -6.000000e+00 1.328782e+03 289.54 -2.00 20.00 -2.00 505.40 0.00e+00 2.429293e-03 5.250839e-04 1.095263e-04 -6.000000e+00 6.506657e-04 289.54 -2.00 20.00 -2.00 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