File name: Pandora119s1_Athens-NOA_20190706_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162548.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190706_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190706T031443.0Z 7126.135220 338 1 32.01 2 89.75 60.88 123.40 27.29 0.00 1 0.00 1 0 15 9.843e-02 9.142e-02 8.915e-02 8.710e-02 2.774020e+03 5.899848e+03 5.294164e+02 -6.000000e+00 5.828363e+03 289.63 -2.00 20.00 -2.00 505.35 0.00e+00 3.362038e-03 2.470451e-03 1.930582e-04 -6.000000e+00 2.851871e-03 289.63 -2.00 20.00 -2.00 500.28 0.00e+00 4.331651e+00 1.773486e+00 4.779852e-02 -6.000000e+00 1.983741e+00 232.62 -2.00 3.45 -2.00 501.90 0.00e+00 19.926 0.135 489.00 513.00 1 9.5989e+00 1.3624e-01 3.4529e-02 -6.0000e+00 1.5291e-01 5.4096e-02 3.4248e-02 1.9083e-03 -6.0000e+00 3.8919e-02 5.4696e-06 -8.7822e-03 9.5136e-03 1.0347e-04 -6.0000e+00 1.1313e-02 6.5746e-02 -2.2996e-04 12 8 8 10 0 0 5.86 21.96 12.23 0.06575 0.00483 8 2 1 4 0 4000.000 26.94 20.00 21.96 -6830 6032 -6936 -4864 -3105 -8655 -1361 310 -2525 -1487 8277 -2241 2735 -3298 659 11278 8702 1841 3569 14396 -3659 -11169 -4387 9509 -3471 8524 10046 -3232 -2275 10309 -6034 13734 -1135 -5149 -6520 2073 4384 8625 2449 -2788 11051 6663 22728 -7404 -9563 -7286 -4951 5061 -12707 19500 -13129 -344 10814 -9321 -2248 -9874 16233 -2265 3315 -9421 16948 -8816 9606 20097 -5406 6672 -10251 -10103 707 1635 5842 1939 10561 2118 13551 -11062 19004 -1610 9609 15006 -8114 11885 17789 3616 -3254 14523 15443 -4255 9330 -20353 -8992 -5833 1941 15434 -399 18691 -1653 6098 -2982 -4940 -5901 -7987 29194 -3666 5149 -6863 -74 -3234 1804 -6751 -1412 524 -1596 -2857 -3154 3509 4924 -4676 -331 -3742 2049 -5526 3512 -2679 5166 -1853 -1775 34964 -13769 14228 -4531 4550 2471 -8106 -3633 -14992 21883 -6320 -1326 10941 10436 9537 14937 20355 1073 5855 -7279 -22178 1172 -3468 -6900 5384 -7215 -5116 -3308 -10001 -1491 339 -2843 -1647 8209 -2434 2788 -3530 674 10379 8310 1868 3639 13385 -4108 -13571 -4995 9461 -3952 8634 9995 -3636 -2488 9701 -6560 12215 -1188 -5759 -7585 2244 4638 8678 2596 -3093 10672 6764 19857 -8619 -11489 -8594 -5688 5342 -15349 17124 -15170 -341 9740 -10036 -2297 -11171 14458 -2459 3416 -11030 15243 -10283 9334 17548 -6046 6527 -11687 -11320 701 1585 5382 1854 9314 2049 11743 -12201 15304 -1568 8264 12150 -8274 9962 14131 3332 -3152 12140 12808 -4185 8208 -23537 -9344 -5936 1847 12876 -388 14756 -1566 5217 -2729 -4532 -5439 -7600 20124 -3519 4614 -6970 -70 -3119 1647 -6756 -1359 503 -1591 -2920 -3263 3422 4759 -4857 -327 -3786 1932 -5568 3224 -2626 4710 -1821 -1748 24469 -15305 11936 -4555 4129 2264 -8201 -3525 -16508 16991 -6631 -1344 9930 9602 8913 13307 17245 1101 5679 -7925 -26859 1137 -3523 SO 20190706T031859.0Z 7126.138183 342 1 32.01 2 89.01 61.53 123.04 28.38 0.00 1 0.00 1 0 15 7.129e-02 6.929e-02 5.883e-02 5.782e-02 1.545821e+04 4.651585e+03 1.018131e+03 -6.000000e+00 4.222596e+03 289.63 -2.00 20.00 -2.00 505.31 0.00e+00 2.695732e-03 1.647597e-03 1.698885e-04 -6.000000e+00 2.066214e-03 289.63 -2.00 20.00 -2.00 500.24 0.00e+00 9.685964e-01 1.192228e+00 9.042785e-02 -6.000000e+00 1.437737e+00 232.62 -2.00 3.45 -2.00 501.85 0.00e+00 18.532 0.109 489.00 513.00 1 9.6110e+00 9.1581e-02 3.1591e-02 -6.0000e+00 1.1082e-01 1.0105e-01 2.2683e-02 2.7616e-03 -6.0000e+00 2.8213e-02 8.3750e-06 6.7389e-04 5.9810e-03 9.5816e-05 -6.0000e+00 8.1955e-03 -2.6270e-02 2.9944e-04 12 9 8 11 8 0 69.70 21.95 6.07 -0.02627 -0.02160 8 2 1 4 0 4000.000 26.94 19.99 21.95 1860 2457 793 1659 -13331 9899 -13244 15328 -1221 -10859 4124 2223 1410 1658 -105 -3775 1664 9600 315 10044 962 8136 -2046 -471 -7291 6264 536 -9785 8359 -6467 -289 -7230 9815 11357 112 -5257 -5298 6552 2784 6651 -2495 1026 3811 1794 8298 -11458 4763 2215 -383 -336 9290 833 -5440 3330 7235 -4282 -6405 -650 267 -9922 5044 -13429 11619 927 -2139 520 768 17249 -10510 -3512 -4949 2500 13124 4444 8839 9316 -2148 -7902 10396 8891 5918 1478 -3886 11951 -7973 5486 -4111 -4 -1236 -8234 -4491 -2641 8919 -3906 694 1841 4738 -3229 -1545 4383 -5352 24465 -15972 -397 6102 -249 4262 -3133 8680 -10360 7127 -6634 -4169 12991 -3881 6872 -796 2667 -2294 3188 1370 -7962 6346 -4382 6663 7468 -6478 8125 10201 -4901 -9026 16664 -1099 1060 9394 -1943 12608 -2826 -6676 -9390 479 -3190 -2775 8798 -1790 -1977 -3066 47 -5106 7606 1722 2289 772 1652 -15861 9549 -16369 14352 -1347 -13065 4212 2280 1438 1669 -107 -4012 1699 9246 339 9943 1048 8272 -2310 -525 -8515 6556 575 -11486 8213 -7008 -291 -7824 9380 10707 121 -6026 -6049 6586 2880 6589 -2714 1087 3969 1929 8426 -14198 4989 2349 -409 -350 8570 821 -5674 3217 6884 -4690 -7122 -706 288 -11565 5202 -16300 11275 973 -2293 535 777 14959 -11581 -3572 -5082 2390 11376 4236 8074 8392 -2136 -8192 8879 7669 5264 1382 -3863 10241 -8413 5082 -4186 -3 -1213 -8676 -4586 -2667 8022 -3939 651 1650 3993 -2867 -1324 3513 -4775 16667 -16575 -367 5430 -239 3892 -3065 7545 -10980 6411 -6911 -4263 11237 -3996 6410 -810 2632 -2364 3066 1317 -8285 5691 -4383 5994 6687 -6677 7230 8866 -4806 -9119 13171 -1029 972 8009 -1843 10784 -2798 -6970 -10197 476 -3305 -2871 8094 -1818 -1987 -3065 45 -5104 6730 SO 20190706T032312.0Z 7126.141111 346 1 32.01 2 88.28 62.17 122.67 29.45 0.00 1 0.00 1 0 15 3.670e-02 3.608e-02 3.627e-02 3.598e-02 1.307211e+04 2.814497e+03 7.549150e+02 -6.000000e+00 2.173245e+03 289.63 -2.00 20.00 -2.00 505.37 0.00e+00 4.209191e-03 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