File name: Pandora119s1_Athens-NOA_20190713_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T162600.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190713_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190713T031902.0Z 7133.138218 273 1 32.01 2 89.74 62.02 124.23 272.66 0.00 1 0.00 1 0 22 1.022e-01 9.793e-02 8.249e-02 8.049e-02 3.107463e+03 5.475802e+03 4.401586e+02 -6.000000e+00 6.069245e+03 290.26 -2.00 20.00 -2.00 505.30 0.00e+00 2.833898e-03 2.313222e-03 1.507552e-04 -6.000000e+00 2.967297e-03 290.26 -2.00 20.00 -2.00 500.23 0.00e+00 3.402757e+00 1.643036e+00 3.226237e-02 -6.000000e+00 2.058859e+00 232.57 -2.00 3.45 -2.00 501.84 0.00e+00 19.899 0.135 489.00 513.00 1 9.5977e+00 1.2676e-01 3.4262e-02 -6.0000e+00 1.5876e-01 7.9759e-02 3.1798e-02 1.9299e-03 -6.0000e+00 4.0364e-02 5.9183e-06 -4.5995e-03 8.8031e-03 8.2300e-05 -6.0000e+00 1.1749e-02 -1.7873e-02 3.1815e-04 12 9 8 11 8 0 16.21 21.11 4.37 -0.01787 -0.04978 8 2 1 4 0 4000.000 26.32 19.99 21.11 -7752 12416 -2059 -4039 8811 9029 5769 -5945 11111 -6462 -1403 -1465 -11144 5489 -6684 11259 1271 -1317 5188 -11147 17162 -2894 13741 174 19464 -6696 1454 13074 -8279 11603 961 6056 -9024 -5203 -7859 5071 3260 -9117 20355 -5556 -79 -2055 7584 -802 -3578 9016 2460 6504 740 -2422 -17922 -19239 7355 -3147 15895 -8365 2731 3195 -391 4034 -1496 13674 -3546 8603 -431 -10576 472 742 18929 9020 13154 -10285 -5027 -6727 -10179 27644 -897 -5489 1145 -2930 3637 -16 8359 -3466 8200 -18551 -328 4229 153 59 -4822 9706 -2423 11073 16 16967 -4454 -5699 6893 -6006 19997 -21622 16828 -9882 -7286 17166 -12747 17477 -10912 15787 -1434 -2418 -4115 6631 9783 -12291 11260 -1277 11900 -7990 10700 7817 1515 16517 8344 3162 9728 19696 -7688 -17547 27846 -8295 7846 -6417 -7645 6108 1326 1287 -21419 3574 5133 10874 -5091 -6469 11272 11213 16276 -18154 13701 6473 -7998 10560 -2076 -4287 8470 8872 5964 -6983 11014 -7376 -1543 -1590 -12791 5417 -7214 10464 1287 -1396 5266 -13511 15779 -3262 13147 192 17734 -7936 1581 12509 -9605 10765 975 5844 -10301 -5875 -9330 5346 3491 -10956 18040 -6343 -86 -2282 7729 -875 -4052 9263 2617 6736 777 -2562 -21565 -22954 6838 -3188 13954 -9355 2789 3282 -418 4119 -1615 12720 -3923 8403 -457 -12233 481 743 15580 8099 11253 -11127 -5194 -7128 -11198 20684 -880 -5550 1072 -2844 3310 -15 7336 -3362 7313 -21178 -312 3943 145 56 -4849 8536 -2427 9694 16 13616 -4330 -5473 5708 -5578 14680 -23832 12974 -10229 -7470 13809 -13723 13784 -11403 12731 -1394 -2412 -4235 6197 8931 -13736 10235 -1282 10652 -8407 9451 7044 1416 13678 7351 2944 8496 15961 -7986 -20049 20534 -8457 6732 -6320 -7662 5417 1258 1243 -26328 3459 4927 9915 -5474 -7069 10278 10116 13713 -20692 11518 5865 SO 20190713T032323.0Z 7133.141238 277 1 32.01 2 88.98 62.68 125.06 273.33 0.00 1 0.00 1 0 15 5.866e-02 5.844e-02 5.402e-02 5.327e-02 9.350062e+03 4.010921e+03 7.699478e+02 -6.000000e+00 3.482438e+03 290.26 -2.00 20.00 -2.00 505.30 0.00e+00 3.060020e-03 1.529342e-03 1.526623e-04 -6.000000e+00 1.704283e-03 290.26 -2.00 20.00 -2.00 500.17 0.00e+00 2.472069e+00 1.098171e+00 2.991238e-02 -6.000000e+00 1.187067e+00 232.57 -2.00 3.45 -2.00 501.80 0.00e+00 18.449 0.107 489.00 513.00 1 9.4323e+00 8.4438e-02 3.0525e-02 -6.0000e+00 9.1451e-02 8.0181e-02 2.1225e-02 1.9067e-03 -6.0000e+00 2.3396e-02 9.1176e-06 -1.8380e-04 5.7168e-03 9.7811e-05 -6.0000e+00 6.7403e-03 -1.5698e-02 -8.8346e-05 12 8 8 10 0 0 71.65 21.11 3.29 -0.01570 -0.01697 8 2 1 4 0 4000.000 26.32 20.00 21.11 11932 6142 -7235 -6208 -1764 6945 4781 -2694 10478 4017 -7843 -1686 2797 -7483 9155 -947 -2639 3996 -7171 -3801 -10009 8823 -737 9954 2682 310 988 -4029 8536 430 2053 3077 1090 11535 -9046 3626 2869 4264 -6280 6274 -3582 -7389 4546 -5187 -1376 635 1696 -2724 -396 992 -15226 4536 3854 2522 -2904 -2981 6488 -10316 4170 -1305 3864 2863 -1032 -10796 4385 8308 273 5737 -336 2835 6630 5094 1388 -175 8998 -10570 856 7971 -3808 -2782 -715 6819 3208 2018 -2732 2039 -8052 1089 3559 -7958 12581 11071 6412 -133 -1191 4284 -8397 6361 -3462 2672 342 -3580 4809 5078 -1245 -2478 6006 -8978 10378 -291 -4625 -6062 -4442 1144 -7707 825 1736 -886 684 2549 -789 -8065 4271 -2700 4450 -525 6080 -751 -5836 -1443 394 14878 -6407 -1113 -6227 809 8826 -8357 14328 -2909 2418 6756 -5888 -1413 998 7302 -7427 7281 454 3487 10284 5484 -7552 -6616 -1854 6859 4918 -3024 10333 4198 -9113 -1816 2839 -8315 8550 -979 -2806 4051 -8303 -4322 -11894 8943 -803 10035 2846 338 1066 -4523 8293 442 2036 3010 1103 10790 -10666 3819 3045 4428 -7177 6280 -3954 -8524 4703 -5983 -1543 701 1847 -3070 -429 1036 -18217 4352 3678 2447 -3031 -3195 6469 -12021 4331 -1396 3928 2947 -1107 -12749 4417 7946 278 5457 -335 2704 6038 4706 1338 -173 8148 -11585 826 7041 -3737 -2682 -675 5988 2939 1885 -2699 1932 -8447 1040 3307 -8297 10735 9678 5915 -131 -1137 3874 -8177 5328 -3126 2235 293 -3154 4116 4383 -1176 -2398 5329 -9188 8719 -273 -4593 -6189 -4512 1108 -8211 813 1708 -899 681 2463 -776 -8418 3915 -2656 4095 -510 5541 -733 -5846 -1379 367 12121 -6234 -1022 -6043 742 7612 -8713 12090 -2953 2350 6330 -6292 -1447 994 6769 -7854 6533 431 3211 SO 20190713T032737.0Z 7133.144178 281 1 32.01 2 88.24 63.33 125.86 273.98 0.00 1 0.00 1 0 15 3.096e-02 3.054e-02 3.181e-02 3.159e-02 1.135325e+04 2.429378e+03 8.142133e+02 -6.000000e+00 1.837880e+03 290.27 -2.00 20.00 -2.00 505.35 0.00e+00 4.893540e-03 9.087474e-04 2.444048e-04 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