File name: Pandora119s1_Athens-NOA_20190721_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T165043.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190721_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190721T032448.0Z 7141.142222 200 1 32.01 2 89.74 63.80 54.48 212.09 0.00 1 0.00 1 0 15 5.197e-02 5.110e-02 5.410e-02 5.361e-02 1.230048e+04 4.129495e+03 4.848287e+02 -6.000000e+00 3.089669e+03 290.63 -2.00 20.00 -2.00 505.32 0.00e+00 3.564094e-03 1.542755e-03 1.986672e-04 -6.000000e+00 1.511141e-03 290.63 -2.00 20.00 -2.00 500.41 0.00e+00 6.902741e-01 1.094536e+00 1.380463e-01 -6.000000e+00 1.049940e+00 232.38 -2.00 3.45 -2.00 502.01 0.00e+00 19.883 0.134 489.00 513.00 1 9.3569e+00 8.4481e-02 3.5963e-02 -6.0000e+00 8.0925e-02 9.8482e-02 2.0915e-02 3.1260e-03 -6.0000e+00 2.0662e-02 9.0721e-06 -2.0666e-03 5.7451e-03 7.5413e-05 -6.0000e+00 5.9743e-03 -3.1713e-02 1.2364e-04 12 8 8 10 0 0 -528.56 21.52 4.32 -0.03171 -0.04605 8 2 1 4 0 4000.000 26.62 20.00 21.52 4524 -1898 -931 -11232 -844 -4052 -846 6962 -733 1335 -2197 -3153 -336 -5182 7097 1806 1730 4858 4586 -2106 7594 916 -1398 -7171 1646 -10032 860 8314 52 3116 4586 3309 8509 -254 -5511 -3861 -989 1344 -1095 -2337 -2287 66 -2450 4694 5643 429 -7758 8080 4743 4714 -1245 1142 -3341 4594 7335 136 -3274 116 2429 3736 2478 468 155 6908 7888 -6180 -11718 4338 5531 4953 -4197 415 -3757 -6844 1783 4342 10889 2694 -2063 1815 -9670 -4090 -7656 5764 -372 -4542 -2735 -5172 1319 -552 -2111 6127 7213 -8809 -6219 844 4283 1900 -2266 984 2239 -2085 2433 2269 691 -3677 901 1005 13153 -3151 6768 4197 -2834 3773 1386 4597 4585 -2351 3238 -4334 -2541 6668 1024 -4793 -5963 482 204 14636 -8245 2274 -1102 -2793 3439 -9839 2383 11007 -4079 6188 1362 -3196 19081 -2780 2140 1109 2053 -4761 -3604 -2979 2023 -9578 3972 -1784 -886 -12235 -854 -4341 -895 6891 -785 1391 -2342 -3344 -341 -5459 6563 1763 1708 4735 4577 -2282 7527 974 -1525 -8103 1711 -11756 902 8217 53 3026 4305 3138 7771 -260 -6101 -4265 -1062 1400 -1158 -2486 -2433 69 -2660 4806 5784 466 -9123 8032 4798 4667 -1276 1118 -3384 4319 6847 140 -3482 121 2488 3783 2544 492 164 6832 7677 -6842 -13511 4198 5222 4651 -4288 405 -3848 -7298 1753 4145 9610 2540 -2016 1695 -10121 -4066 -7943 5276 -365 -4682 -2773 -5359 1277 -544 -2127 5737 6726 -9368 -6335 780 3803 1679 -2041 846 1903 -1838 2120 2058 656 -3699 866 960 11089 -3145 6192 3990 -2919 3665 1387 4488 4517 -2497 3245 -4631 -2624 6185 997 -4950 -6108 476 203 12583 -8683 2148 -1066 -2714 3106 -10103 2176 9348 -4102 5712 1339 -3329 16061 -2932 2158 1130 2064 -5074 -3737 -3018 1928 -10254 SO 20190721T032909.1Z 7141.145244 204 1 32.20 2 88.97 64.47 54.92 213.26 0.00 1 0.00 1 0 15 3.264e-02 3.271e-02 3.285e-02 3.265e-02 3.990387e+03 2.236057e+03 2.026239e+02 -6.000000e+00 1.939705e+03 290.63 -2.00 20.00 -2.00 505.33 0.00e+00 1.349863e-03 9.371736e-04 7.616879e-05 -6.000000e+00 9.489717e-04 290.63 -2.00 20.00 -2.00 500.40 0.00e+00 2.687051e+00 6.627551e-01 4.343355e-02 -6.000000e+00 6.602437e-01 232.38 -2.00 3.45 -2.00 502.01 0.00e+00 18.400 0.106 489.00 513.00 1 8.9500e+00 5.1079e-02 3.0324e-02 -6.0000e+00 5.0869e-02 5.4000e-02 1.2772e-02 1.8466e-03 -6.0000e+00 1.3019e-02 1.5200e-05 2.4670e-03 3.6193e-03 3.0382e-05 -6.0000e+00 3.7510e-03 4.0449e-02 -4.5541e-04 12 8 8 10 0 0 -60.87 21.52 3.29 0.04045 0.05756 8 2 1 4 0 4000.000 26.62 20.00 21.52 -6271 8718 -6278 2482 2527 519 880 -337 -4699 -2269 3338 1259 -631 -1144 -2402 2765 103 3926 -7781 -2716 631 2454 9579 -206 -835 483 510 -397 611 2592 -2529 4463 2325 -1555 -1368 -1524 853 5227 1652 2633 1115 -459 -10 -7890 5537 -265 -1660 -2177 -2475 1409 -5762 -724 2849 422 7429 4759 -4298 -522 1426 1666 4795 40 -2625 -4356 -1216 -3470 1081 4161 -2002 -411 -85 -963 4787 1379 -502 2360 -888 2430 299 2766 -1137 -4220 51 -1771 428 -1412 2931 409 937 -7602 1059 -2441 3556 2428 114 -883 -1549 -3254 5849 803 -307 1893 853 -8771 1949 -3566 358 3873 -2648 3087 -3165 3015 -1525 4688 -578 2494 955 3520 1349 1143 902 -586 -2423 3931 666 -6718 -2280 2273 693 3965 2295 5386 -3093 1333 751 -2083 205 -5861 5243 -2419 2479 -2927 3982 -38 -2254 -1082 2359 -6282 1219 1239 -6198 7478 -6252 2398 2450 526 906 -356 -5183 -2427 3335 1267 -639 -1152 -2435 2672 104 3881 -8839 -2978 675 2584 9421 -224 -919 525 551 -428 640 2598 -2624 4319 2338 -1629 -1466 -1655 903 5255 1704 2672 1149 -483 -10 -9130 5650 -287 -1817 -2368 -2653 1418 -6074 -710 2668 407 6826 4609 -4653 -551 1480 1725 4816 42 -2853 -4690 -1259 -3628 1090 4010 -1976 -405 -81 -925 4373 1316 -491 2228 -854 2228 277 2490 -1066 -4106 48 -1709 408 -1379 2749 393 897 -7954 1024 -2470 3419 2361 112 -862 -1487 -3103 4983 710 -275 1684 789 -8998 1833 -3563 342 3540 -2573 2850 -3151 2864 -1535 4481 -587 2472 966 3471 1351 1134 885 -578 -2425 3704 651 -7097 -2308 2199 680 3756 2194 4931 -3048 1251 712 -2015 197 -6118 4973 -2507 2467 -3096 3954 -40 -2385 -1120 2322 -6622 1179 1200 SO 20190721T033323.0Z 7141.148183 208 1 32.01 2 88.21 65.11 55.37 214.38 0.00 1 0.00 1 0 22 1.291e-02 1.278e-02 1.211e-02 1.206e-02 1.233743e+04 9.165472e+02 7.978917e+02 -6.000000e+00 7.671582e+02 290.63 -2.00 20.00 -2.00 505.40 0.00e+00 2.676187e-03 3.462586e-04 1.347327e-04 -6.000000e+00 3.752345e-04 290.63 -2.00 20.00 -2.00 500.64 0.00e+00 1.505704e+00 2.422936e-01 7.925692e-02 -6.000000e+00 2.608143e-01 232.38 -2.00 3.45 -2.00 502.22 0.00e+00 16.493 0.077 489.00 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