File name: Pandora119s1_Athens-NOA_20190722_L2Fit_fwvt1c3d20181127p1-8.txt File generation date: 20250610T165253.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Stelios Kazadsis Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 119 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora119_of_v6d20180103.txt Instrument calibration file used: Pandora119s1_CF_v3d20181127.txt Level 1 file used: Pandora119s1_Athens-NOA_20190722_L1_smca1c3d20181127p1-8.txt Full location name: National Observatory of Athens, Thiseio Short location name: Athens-NOA Country of location: Greece Location latitude [deg]: 37.9878 Location longitude [deg]: 23.7750 Location altitude [m]: 130 Local noon date: 20190722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1641 1790 Nominal wavelengths inside fitting window [nm]: 492.0355 492.1570 492.2785 492.4000 492.5214 492.6428 492.7642 492.8856 493.0070 493.1283 493.2497 493.3710 493.4923 493.6136 493.7348 493.8561 493.9773 494.0986 494.2198 494.3409 494.4621 494.5833 494.7044 494.8255 494.9466 495.0677 495.1888 495.3098 495.4309 495.5519 495.6729 495.7939 495.9149 496.0358 496.1567 496.2777 496.3986 496.5194 496.6403 496.7612 496.8820 497.0028 497.1236 497.2444 497.3652 497.4859 497.6067 497.7274 497.8481 497.9688 498.0894 498.2101 498.3307 498.4513 498.5719 498.6925 498.8131 498.9336 499.0541 499.1747 499.2952 499.4156 499.5361 499.6566 499.7770 499.8974 500.0178 500.1382 500.2585 500.3789 500.4992 500.6195 500.7398 500.8601 500.9804 501.1006 501.2208 501.3410 501.4612 501.5814 501.7016 501.8217 501.9418 502.0619 502.1820 502.3021 502.4222 502.5422 502.6622 502.7822 502.9022 503.0222 503.1422 503.2621 503.3820 503.5019 503.6218 503.7417 503.8615 503.9814 504.1012 504.2210 504.3408 504.4605 504.5803 504.7000 504.8197 504.9394 505.0591 505.1788 505.2984 505.4181 505.5377 505.6573 505.7769 505.8964 506.0160 506.1355 506.2550 506.3745 506.4940 506.6134 506.7329 506.8523 506.9717 507.0911 507.2105 507.3299 507.4492 507.5685 507.6878 507.8071 507.9264 508.0456 508.1649 508.2841 508.4033 508.5225 508.6417 508.7608 508.8800 508.9991 509.1182 509.2373 509.3563 509.4754 509.5944 509.7134 509.8324 509.9514 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190722T032534.0Z 7142.142755 204 1 32.01 2 89.74 64.06 46.86 202.04 0.00 1 0.00 1 0 29 7.513e-02 7.337e-02 7.739e-02 7.611e-02 1.722437e+04 6.281016e+03 1.426262e+03 -6.000000e+00 4.465008e+03 290.65 -2.00 20.00 -2.00 505.36 0.00e+00 2.582066e-04 2.198592e-03 7.644336e-05 -6.000000e+00 2.184394e-03 290.65 -2.00 20.00 -2.00 500.23 0.00e+00 1.367525e+00 1.555838e+00 2.198731e-02 -6.000000e+00 1.518856e+00 232.35 -2.00 3.45 -2.00 501.87 0.00e+00 19.883 0.134 489.00 513.00 1 9.7080e+00 1.1984e-01 3.4091e-02 -6.0000e+00 1.1704e-01 8.7532e-02 2.9442e-02 2.3612e-03 -6.0000e+00 2.9932e-02 6.2923e-06 1.0938e-02 7.5811e-03 1.2606e-04 -6.0000e+00 8.6371e-03 4.5355e-02 -4.3305e-04 12 8 8 10 0 0 40.35 21.81 8.36 0.04535 0.12123 8 2 1 4 0 4000.000 26.83 20.00 21.81 -13752 3340 -613 8535 3745 -3615 -2991 2437 2734 -4329 -5808 -7672 -195 3333 -4690 10864 -2689 -944 5121 7771 10432 3391 5152 -1040 10371 3842 1372 -7790 159 -306 -3687 -12055 -2301 641 2084 3378 -3102 -1095 9265 318 5612 -1549 5852 -6292 -7567 -3383 -91 -6300 3977 2176 -6853 -5748 -1716 -1564 20775 -3998 -5369 -11549 1604 7850 18790 19298 4749 10084 -3533 6973 -14774 9416 3723 -1047 -4090 -1455 5607 -4377 2514 9921 1081 3652 63 -10006 -5603 -1788 -1347 13098 3142 -4653 13930 1658 8960 1426 2409 -4564 3025 1555 11763 -9576 -2379 11465 9518 9691 -1354 -18062 5448 -49 -10150 -5087 6436 5931 7814 -11427 -2648 11026 -3587 7297 2968 12305 11921 -18566 6945 -10324 -1279 -1902 -9896 12627 8573 -2677 7311 7570 -996 -3201 -3064 -6567 46 -8892 15141 -2122 -8059 1880 1968 4953 -10078 10032 -2734 2106 10942 -4036 10999 -6901 -2467 2864 -14883 3103 -611 7998 3781 -3909 -3263 2603 2904 -4757 -6394 -8491 -198 3238 -4933 10137 -2849 -1006 5235 7823 10277 3593 5378 -1159 10339 4078 1481 -9065 167 -315 -3907 -14028 -2488 691 2258 3625 -3531 -1209 9145 342 5737 -1670 6074 -7254 -8883 -3803 -99 -7119 3970 2155 -7246 -5913 -1693 -1564 17041 -4304 -5954 -13713 1672 7684 16526 16936 4822 9660 -3837 6720 -17429 8605 3559 -1041 -4184 -1458 5285 -4594 2461 8915 1044 3387 60 -10241 -5505 -1747 -1291 11269 2940 -4727 12038 1574 7884 1356 2281 -4654 2843 1452 9605 -9337 -2089 8549 7133 7244 -1151 -18822 4702 -47 -10955 -5263 5915 5451 7050 -12283 -2629 9846 -3627 6801 2834 11080 10624 -22523 6480 -11266 -1252 -1848 -10367 10587 7515 -2634 6515 6719 -960 -3132 -2959 -6498 43 -9008 12227 -2077 -8530 1833 1947 4820 -11237 9433 -2859 2144 10130 -4185 9902 -7168 -2444 2710 SO 20190722T032957.0Z 7142.145799 208 1 32.01 2 88.96 64.73 47.17 203.44 0.00 1 0.00 1 0 15 4.317e-02 4.225e-02 4.439e-02 4.398e-02 4.891353e+03 3.148024e+03 3.202652e+02 -6.000000e+00 2.566264e+03 290.65 -2.00 20.00 -2.00 505.41 0.00e+00 1.866279e-03 1.274287e-03 5.976913e-05 -6.000000e+00 1.255570e-03 290.65 -2.00 20.00 -2.00 500.40 0.00e+00 4.332450e+00 8.941298e-01 4.445054e-02 -6.000000e+00 8.735602e-01 232.35 -2.00 3.45 -2.00 502.03 0.00e+00 18.382 0.106 489.00 513.00 1 9.1312e+00 6.9189e-02 3.0278e-02 -6.0000e+00 6.7302e-02 1.1417e-02 1.6926e-02 1.9057e-03 -6.0000e+00 1.7229e-02 1.1140e-05 9.0262e-03 4.8380e-03 2.4091e-05 -6.0000e+00 4.9603e-03 1.9710e-02 -3.4930e-04 12 8 8 10 0 0 -29.44 21.80 6.28 0.01971 0.08232 8 2 1 4 0 4000.000 26.83 20.00 21.80 -9578 -7466 1838 -11007 5665 8487 83 2710 -1550 384 -4808 -1399 156 4953 887 -1654 2265 313 7653 -1073 -1676 2224 3009 6511 -5812 1417 -391 414 1207 -1192 -1445 2860 -3101 -6810 -2623 -300 -28 -910 -4826 1083 -569 2951 -2748 -1965 4461 2245 5324 -3139 -3726 5505 4786 3703 5188 1696 4635 842 1054 106 5022 2003 -6316 -1712 3079 -1272 -743 -2387 3063 1838 -1675 789 2573 6730 -2010 531 -357 -5378 -1982 9496 9591 -4105 4359 -2587 -2625 5917 1922 -323 -11271 3157 -2300 3369 161 333 1327 -628 -2325 -2732 -16 2649 6835 11041 -9826 8665 6460 -71 -322 7324 9114 284 3224 -2993 -1954 3443 -7373 1756 3069 751 -7073 -519 3309 -1256 -5215 1859 272 -157 6497 -8286 -4316 2178 -4350 -1941 -7048 1654 -6086 -1348 -488 2009 -300 632 4423 3347 2443 -2618 1738 5846 999 3427 -7546 449 -655 -2409 -9537 -7391 1707 -12008 5383 8027 86 2787 -1663 401 -5218 -1448 157 4712 877 -1690 2263 318 7374 -1143 -1807 2315 3119 6547 -6641 1506 -421 436 1233 -1220 -1465 2797 -3289 -7713 -2910 -327 -30 -986 -5391 1136 -608 3069 -3057 -2193 4703 2421 5530 -3413 -3994 5383 4595 3527 4844 1618 4395 850 1081 110 4999 2054 -7050 -1830 3138 -1349 -775 -2497 2987 1788 -1666 758 2415 6076 -1996 518 -352 -5522 -1937 8154 8152 -3990 3902 -2497 -2554 5330 1816 -306 -11918 2887 -2222 3088 154 320 1272 -612 -2268 -2618 -14 2291 5561 8530 -9409 7049 5547 -67 -309 6536 7932 268 2955 -2948 -1933 3275 -7724 1737 3019 743 -7613 -523 3185 -1250 -5335 1758 261 -152 5933 -8808 -4419 2092 -4459 -1936 -7333 1560 -6151 -1299 -471 1925 -301 639 4371 3382 2514 -2856 1826 5908 1056 3496 -8251 457 -670 -2465 SO 20190722T033411.0Z 7142.148738 212 1 32.01 2 88.20 65.37 47.49 204.78 0.00 1 0.00 1 0 15 1.685e-02 1.662e-02 1.587e-02 1.581e-02 1.152373e+04 1.197721e+03 6.782114e+02 -6.000000e+00 1.001473e+03 290.65 -2.00 20.00 -2.00 505.42 0.00e+00 3.401529e-03 4.550609e-04 1.731283e-04 -6.000000e+00 4.898142e-04 290.65 -2.00 20.00 -2.00 500.71 0.00e+00 1.862908e+00 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